Abstract
Poly(vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) blended with poly (methyl methacrylate) grafted natural rubber (MG49) and lithium tetrafluoroborate (LiBF4) as charge carriers based polymer electrolyte was prepared by solution casting technique. The effect of propylene carbonate (PC) and ethylene carbonate (EC) plasticizers on the properties of the polymer electrolyte films was investigated. Electrochemical impedance spectroscopy (EIS) showed that ionic conductivity increases as the concentration of plasticizer increases and the highest room temperature conductivities obtained are 1.51 × 10−3 S cm−1 and 7.39 × 10−4 S cm−1 at 80 wt % PC and 40 wt % EC, respectively. The addition of PC resulted in ionic conductivity enhancement in contrast with EC plasticizer. The temperature dependence conductivity for 80 wt % PC reached 6.52 × 10−2 S cm−1 at 373 K. Scanning electron microscopy (SEM) indicated the compatibility of PC with (PVDF-HFP)-MG49-LiBF4 whereas EC shows immiscibility with (PVDF-HFP)-MG49-LiBF4 complex. X-Ray Diffraction (XRD) studies show high degree of amorphous nature of the plasticized polymer electrolytes as indicated by reduction in the intensity of crystalline peaks. Thermogravimetric analysis (TGA) illustrates that the addition of plasticizer decreases the thermal stability of polymer electrolyte. However, linear sweep voltammetry (LSV) shows the electrochemical stability is up to 4 V.
Similar content being viewed by others
References
Bernardo, J.J. and Burell, H., Plasticization, North Holland Publishing Company, 1972.
Gray, F.M., Polymer Electrolytes, Cambridge: Royal Society of Chemistry, 1997.
Kim, K.M., Park, N.G., Ryu, K.S., and Chang, S.H., Characteristics of PVDFHFP/TiO2 composite membrane electrolytes prepared by phase inversion and conventionalcasting methods, Electrochimiaca Acta, 2006, vol. 51, pp. 5636–5644.
Xie, H., Tang, Z., Li, Z., He, Y., Liu, Y., and Wang, H., PVDF-HFP composite polymer electrolyte with excellent electrochemical properties for Li-ion batteries, J. Solid State Electrochem, 2008, vol. 12, pp. 1497–1502.
Deka, M., Nath, A.K., and Kumar, A., Effect of dedoped (insulating) polyaniline nanofibers on the ionic transport and interfacial stability of poly(vinylidene fluoride-hexafluoropropylene) based composite polymer electrolyte membranes, J. Membr. Sci., 2009, vol. 327, pp. 188–194.
Ramesh, S. and Ong Poh Ling, Effect of ethylene carbonate on the ionic conduction in poly(vinylidenefluoride-hexafluoropropylene) based solid polymer electrolytes, Polym. Chem, 2010, vol. 1, pp. 702–707.
Wang, Z.l. and Tang, Z.Y., A novel polymer electrolyte based on PMAML/PVDF-HFP blend, Electrochimica Acta, 2004, vol. 49, pp. 1063–1068.
Jiang, Z., Caroll, B., and Abraham, K.M., Studies of some poly(vinylidene fluoride) electrolytes, Electrochimica Acta, 1997, vol. 42, pp. 2667–2677.
Song, J.Y., Wang, Y.Y., and Wan, C.C., Review of geltype polymer electrolyte for lithium ion batteries, J. Power Sources, 1999, vol. 77, pp. 183–197.
Murata, K., Izuchi, S., and Yoshihisa, Y., An overview of the research and development of solid polymer electrolyte batteries, Electrochim. Acta, 2000, vol. 45, pp. 1501–1508.
Magistris, A., Mustarelli, P., Parazzoli, F., Quartarone, E., Piaggio, P., and Bottino, A., Structure, porosity and conductivity of PVDF films for polymer electrolytes, J. Power Sources, 2001, vols. 97–98, pp. 657–660.
Ataollahi, N., Ahmad, A., Hamzah, H., Rahman, M.Y.A., and Mohamed, N.S., Preparation and Characterization of PVDF-HFP/MG49 Based Polymer Blend Electrolyte, Int. J. Electrochem. Sci., 2012, vol. 7, pp. 6693–6703.
Kumar, P.P. and Yashonath, S., Ionic conduction in the solid state, Chem. Sci., 2006, vol. 118, p. 135154.
Boor Singh, L., Yamada, K., Hundal, M.S., Park, J.S., Park, G.G., Lee, W.Y., Kim, C.S., and Sekhon, S.S., Physicochemical studies of PVdF-HFP-based polymer ionic liquid composite electrolytes, Appl. Phys. A, 2009, vol. 96, pp. 661–670.
Mahendran, O., Chen, S.Y., Chen-Yang, Y.W., Lee, J.Y., and Rajendran, S., Investigation on PMMA-PVdF polymer blend electrolyte with esters of dibenzoic acid as plasticizer, Ionics, 2005, vol. 11, pp. 251–258.
Manuel Stephan, A., Gopu Kumar, S., Renganathan, N.G., and Anbu Kulandainathan, M., Characterization of poly (vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) electrolytes complexed with different lithium salts, European Polymer J., 2005, vol. 41, pp. 15–21.
Aurelien, D.P., Tao, Z., Glenn, G.A., and Antoni, S.G., Microstructure effects inplasticized electrodes based on PVDF-HFP for plastic Li-ion batteries, J. Power Sources., 2001, vol. 97, pp. 58–761.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Published in Russian in Elektrokhimiya, 2015, Vol. 51, No. 3, pp. 270–279.
The article is published in the original.
Rights and permissions
About this article
Cite this article
Ataollahi, N., Ahmad, A., Hamzah, H. et al. Comparative study of the properties of plasticized (PVDF-HFP)-MG49-LiBF4 blend polymer electrolytes. Russ J Electrochem 51, 227–235 (2015). https://doi.org/10.1134/S1023193515030039
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193515030039