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Absolute molecular mass determination of sodium salt of styrene/methacrylic acid copolymer by gel permeation chromatography coupled with multi angle laser light scattering

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Abstract

Sodium salt of styrene/methacrylic acid copolymer was synthesized via radical polymerization, and its absolute molecular mass and polydispersity index were measured by aqueous-based GPC coupled with MALLS in a mixed solvent containing 75/25, v/v%, methanol/water, 38.6 mM NaCl and 10.0 mM NaH2PO4 buffer, pH 6.0. Dynamic light scattering verified the absence of aggregation of copolymer in preferred mobile phase compositions.

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Authors and Affiliations

  1. School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Xue Yang, Zequan Liu & Qiang Zhang

  2. Shandong Pesticide Research Institute, Jinan, 250000, China

    Yinping Xie

Authors
  1. Xue Yang
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  2. Zequan Liu
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  3. Yinping Xie
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  4. Qiang Zhang
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Correspondence to Qiang Zhang.

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Yang, X., Liu, Z., Xie, Y. et al. Absolute molecular mass determination of sodium salt of styrene/methacrylic acid copolymer by gel permeation chromatography coupled with multi angle laser light scattering. Polym. Sci. Ser. A 57, 383–388 (2015). https://doi.org/10.1134/S0965545X1504015X

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  • DOI: https://doi.org/10.1134/S0965545X1504015X

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