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Effect of Composition of Cobalt-Molybdenum-Containing Sulfonium Thiosalts on the Hydrogenation Activity of Nanosized Catalysts In Situ Synthesized on Their Basis

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Abstract

Cobalt-molybdenum-containing thiosalts with different composition of the sulfonium cation are prepared. The activities of sulfide catalysts in situ synthesized on their basis in the hydrogenation of substituted naphthalenes are compared. It is shown that the sulfonium cation composition affects the morphology of the sulfide particles and the phase composition of the catalyst. It is demonstrated that the conversion of model alkyl-substituted bicyclic aromatic hydrocarbons is higher in the presence of the catalyst prepared from the phenylsulfonium thiosalt.

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Funding

This work was carried out within the framework of State Task for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    M. I. Knyazeva, D. I. Panyukova, T. S. Kuchinskaya, A. B. Kulikov & A. L. Maximov

  2. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. L. Maximov

Authors
  1. M. I. Knyazeva
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  2. D. I. Panyukova
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  3. T. S. Kuchinskaya
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Correspondence to M. I. Knyazeva.

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CONFLICT OF INTEREST

A.L. Maximov is the editor-in-chief of the journal Petroleum Chemistry. Other authors declare that there is conflict of interest.

ADDITIONAL INFORMATION

M.I. Knyazeva, ORCID: https://orcid.org/0000-0001-9054-0905

D.I. Panyukova, ORCID: https://orcid.org/0000-0001-6847-0162

T.S. Kuchinskaya, ORCID: https://orcid.org/0000-0002-2908-0353

A.B. Kulikov, ORCID: https://orcid.org/0000-0003-1756-282X.

A.L. Maximov, ORCID: https://orcid.org/0000-0001-9297-4950

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Translated by T. Soboleva

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Knyazeva, M.I., Panyukova, D.I., Kuchinskaya, T.S. et al. Effect of Composition of Cobalt-Molybdenum-Containing Sulfonium Thiosalts on the Hydrogenation Activity of Nanosized Catalysts In Situ Synthesized on Their Basis. Pet. Chem. 59, 1285–1292 (2019). https://doi.org/10.1134/S0965544119120065

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