Skip to main content
SpringerLink
Log in

Aerobic Liquid-Phase Oxidation of Para-tert-Butylcumene to Hydroperoxide

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The reaction of aerobic liquid-phase oxidation of para-tert-butylcumene (PTBC) in the presence of N-hydroxyphthalimide has been studied. It has been found that the selectivity for the tertiary hydroperoxide of PTBC is over 95–98% up to a hydrocarbon conversion of 35–50%. The reasonability of the use of this reaction in the process of joint production of PTBC and acetone is shown. The mechanism of the process is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. E. A. Kurganova, V. N. Sapunov, G. N. Koshel’, and A. S. Frolov, Izv. Akad. Nauk, Ser. Khim., No. 2, 2115 (2016).

  2. S. A. Apostolov, S. E. Babash, E. I. Belkina, and A. D. Berents, New Chemist’s and Chemical Engineer’s Handbook: Raw Materials and Products of Industrial Organic and Inorganic Chemistry (ANO MPO Professional, St. Petersburg, 2002) [in Russian].

    Google Scholar 

  3. M. Saha, M. K. Hossain, M. Ashaduzzama, et al., Bangladesh J. Sci. Ind. Res. 44, 131 (2009).

    Article  CAS  Google Scholar 

  4. A. S. Frolov, E. A. Kurganova, G. N. Koshel’, and T. N. Nesterova, Eur. J. Anal. Appl. Chem. 1, 16 (2015).

    Article  Google Scholar 

  5. Y. Ishii, S. Sakaguchi, and T. Iwahama, Adv. Synth. Catal. 343, 393 (2001).

    Article  CAS  Google Scholar 

  6. K. Kasperczyk, B. Orlińska, and J. Zawadiak, Cent. Eur. J. Chem. 12, 1176 (2014).

    Article  CAS  Google Scholar 

  7. O. Fukuda, S. Sakaguchi, and Y. Ishii, Adv. Synth. Catal. 343, 809 (2001).

    Article  CAS  Google Scholar 

  8. L. Melone, S. Prosperini, G. Ercole, et al., J. Chem. Technol. Biotechnol. 89, 1370 (2014).

    Article  CAS  Google Scholar 

  9. E. A. Kurganova, A. S. Frolov, G. N. Koshel’, et al., Pet. Chem. 58, 451 (2018).

    Article  CAS  Google Scholar 

  10. B. Orlińska and J. Zawadiak, Reac. Kinet. Mech. Catal. 110, 15 (2013).

    Article  Google Scholar 

  11. E. Boring, Y. V. Geletii, and C. L. Hill, J. Mol. Catal., A 176, 49 (2001).

Download references

Author information

Authors and Affiliations

  1. Yaroslavl State Technical University, 150000, Yaroslavl, Russia

    E. M. Yarkina, E. A. Kurganova, A. S. Frolov, N. V. Lebedeva & G. N. Koshel’

Authors
  1. E. M. Yarkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Kurganova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Frolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. V. Lebedeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. N. Koshel’
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. N. Koshel’.

Ethics declarations

The authors declare no conflict of interest requiring the disclosure in this publication.

Additional information

Translated by E. Boltukhina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yarkina, E.M., Kurganova, E.A., Frolov, A.S. et al. Aerobic Liquid-Phase Oxidation of Para-tert-Butylcumene to Hydroperoxide. Pet. Chem. 59, 1245–1248 (2019). https://doi.org/10.1134/S0965544119110161

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544119110161

Keywords:

Search

Navigation