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Hydroconversion of rapeseed oil to hydrocarbons in the presence of MFI/MCM-41 micro–mesoporous materials synthesized by the hydrothermal microwave method

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Abstract

Catalysts containing an MFI zeolite and an MFI/MCM-41 composite synthesized by the hydrothermal microwave method have been first studied in rapeseed oil hydroconversion. Catalysts provide the production of valuable petrochemicals, namely, high-octane components of motor fuels and С2–С4 olefins. Synthesized MFI zeolite mostly catalyzed the formation of aromatic hydrocarbons (ArH); incorporation of this zeolite into the matrix of mesoporous silicate MCM-41 leads to a decrease in the ArH content in the liquid hydrocarbon products owing to an increase in the yield of liquid aliphatic hydrocarbons. Promotion of the MFI zeolite synthesized by the hydrothermal microwave method with zinc ions leads to the formation of a catalyst providing the formation of liquid products consisting of ArH.

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References

  1. A. S. Berenblyum, V. Ya. Danyushevsky, P. S. Kuznetsov, et al., Pet. Chem. 56, 663 (2016).

    Article  CAS  Google Scholar 

  2. V. A. Yakovlev, S. A. Khromova, and V. I. Bukhtiyarov, Russ. Chem. Rev. 80, 911 (2011).

    Article  CAS  Google Scholar 

  3. M. V. Tsodikov, F. A. Yandieva, A. V. Chistyakov, et al., Dokl. Chem. 447, 306 (2012).

    Article  CAS  Google Scholar 

  4. J. A. Botas, D. P. Serrano, A. Garcia, and R. Ramos, Appl. Catal., B 145, 205 (2014).

    Article  CAS  Google Scholar 

  5. X. Dupain, D. J. Costa, C. J. Schaverien, et al., Appl. Catal., B 72, 44 (2007).

    Article  CAS  Google Scholar 

  6. M. V. Tsodikov, A. V. Chistyakov, M. A. Gubanov, et al., Pet. Chem. 53, 46 (2013).

    Article  CAS  Google Scholar 

  7. D. Chen, N. I. Tracy, D. W. Crunkleton, and G. L. Price, Appl. Catal., A 384, 206 (2010).

    Article  CAS  Google Scholar 

  8. F. A. Twaiq, A. R. Mohamad, and S. Bhatia, Fuel Process. Technol. 85, 1283 (2004).

    Article  CAS  Google Scholar 

  9. F. A. Twaiq, A. R. Mohamad, and S. Bhatia, Microporous Mesoporous Mater. 64, 95 (2003).

    Article  CAS  Google Scholar 

  10. Y. -S. Ooi, R. Zakaria, A. R. Mohamed, and S. Bhatia, Appl. Catal., A 274, 15 (2004).

    Article  CAS  Google Scholar 

  11. A. G. Dedov, A. S. Loktev, A. E. Gekhman, et al., Khim. Tekhnol. 12, 654 (2011).

    CAS  Google Scholar 

  12. A. G. Dedov, T. V. Kosakova, E. A. Isaeva, et al., RU Patent No. 2 470 004; Byull. Izobret., No. 35 (2012).

  13. A. G. Dedov, A. S. Loktev, D. A. Levchenko, et al., Khim. Tekhnol., No. 5, 268 (2014).

    Google Scholar 

  14. A. G. Dedov, A. S. Loktev, A. A. Karavaev, et al., Dokl. Chem. 468, 179 (2016).

    Article  CAS  Google Scholar 

  15. A. G. Dedov, A. S. Loktev, A. A. Karavaev et al., Dokl. Akad. Nauk, 471, 303 (2016).

    Google Scholar 

  16. S. Abello, A. Bonilla, and J. Perez-Ramirez, Appl. Catal., A 364, 191 (2009).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Gubkin State University of Oil and Gas, Moscow, Russia

    A. G. Dedov, A. S. Loktev, E. A. Isaeva, A. A. Karavaev, Yu. N. Kitashov, S. V. Markin & I. I. Moiseev

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    A. E. Baranchikov & V. K. Ivanov

Authors
  1. A. G. Dedov
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  2. A. S. Loktev
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  3. E. A. Isaeva
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  4. A. A. Karavaev
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  5. Yu. N. Kitashov
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  6. S. V. Markin
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  7. A. E. Baranchikov
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  8. V. K. Ivanov
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  9. I. I. Moiseev
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Corresponding author

Correspondence to A. S. Loktev.

Additional information

Original Russian Text © A.G. Dedov, A.S. Loktev, E.A. Isaeva, A.A. Karavaev, Yu.N. Kitashov, S.V. Markin, A.E. Baranchikov, V.K. Ivanov, I.I. Moiseev, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 4, pp. 415–422.

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Dedov, A.G., Loktev, A.S., Isaeva, E.A. et al. Hydroconversion of rapeseed oil to hydrocarbons in the presence of MFI/MCM-41 micro–mesoporous materials synthesized by the hydrothermal microwave method. Pet. Chem. 57, 678–685 (2017). https://doi.org/10.1134/S0965544117080035

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  • DOI: https://doi.org/10.1134/S0965544117080035

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