Skip to main content
SpringerLink
Log in

Study of the Phase Composition of a Ceramic Sample Based on Ferrodust and Clay at Different Annealing Temperatures

  • TECHNOLOGY OF INORGANIC SUBSTANCES AND MATERIALS
  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

A ceramic sample obtained from the wastes of oil shale (intershale clay) and iron industry (ferrodust from the self-decaying cinder slag of low-carbon ferrochromium) without using any conventional natural materials has been studied. Ferrodust from self-decaying slags is the most representative waste of iron industry with an increased content of calcium oxide (CaO > 40%). The phase transformations were studied on the samples with a composition of 70% intershale clay and 30% ferrodust. The study showed that at an annealing temperature of the samples of 950°C, the carbonates CaCO3 experienced the thermal decomposition, forming hematite, wollastonite, and diopside, and a liquid phase appeared. When the annealing temperature increased to 1000°C, cristobalite and anorthite formed in the samples, and the content of the liquid phase (glass phase) increased. At an annealing temperature of 1050°C, there were no significant changes except an increase in the cristobalite and anorthite contents. Further increase in the annealing temperature to 1100°C led to higher glass content, which improves the physicomechanical properties of the samples. At 1100°C the contents of anorthite, diopside, and cristobalite increased, while the hematite content decreased, and field spar disappeared, probably transforming into glass.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Gordina, N.E., Prokof’ev, V.Yu., Shamaeva, N.V., Borislva, T.N., Konstantinova, E.M., and Voinova, V.V., Thermal behavior of mixtures based on metakaolin and sodium hydroxide, Steklo Keram., 2020, no. 1, pp. 10–16.

  2. Gaishun, A.S., Gaishun, E.S., Kovaleristova, E.V., and Yavruyan, Kh.S., Ceramic materials based on technical raw materials of the coal series, Vestn. Dagest. Gos. Tekh. Univ. Tekh Nauki, 2019, vol. 46, no. 1, pp. 152–159.

    Article  Google Scholar 

  3. Kotlyar, V.D. and Yavruyan, Kh.S., Wall ceramic products based on finely divided products of spoil tip processing, Stroit. Mater., 2017, no. 4, pp. 38–41.

  4. Abdrakhimova, E.S. and Abdrakhimov, V.Z., Interrelation of the phase and chemical compositions with the durability of the ceramic material more than 800 years old from the Girona city walls (Spain), Khim. Tekhnol., 2020, vol. 21, no. 3, pp. 98–104.

    Google Scholar 

  5. Abdrakhimov, V.Z. and Abdrakhimova, E.S., Study of the distribution of iron oxides in intershale clay and oil sludge porous aggregate with Mössbauer spectroscopy, Theor. Found. Chem. Eng., 2019, vol. 53, no. 4, pp. 703–707.

    Article  CAS  Google Scholar 

  6. Abdrakhimova, E.S. and Abdrakhimov, V.Z., Formation of glaze coatings of clinker bricks based on raw kaolin and aluminum-containing nanotechnogenic raw materials, Inorg. Mater. Appl. Res., 2018, vol. 9, no. 4, pp. 588–594.

    Article  Google Scholar 

  7. Kairakbaev, A.K., Abdrakhimova, E.S., and Abdrakhimov, V.Z., Use of nonferrous metallurgy waste: Clayey portion of the zircon–ilmenite ore gravity tailings and pyrite cinders in tile-making, Mater. Sci. Forum, 2020, vol. 989, pp. 47–53.

    Article  Google Scholar 

  8. Kairakbaev, A.K., Abdrakhimova, E.S., and Abdrakhimov, V.Z., Innovative approaches to using Kazakhstan’s industrial ferrous and nonferrous tailings in the production of ceramic materials, Mater. Sci. Forum, 2020, vol. 989, pp. 54–61.

    Article  Google Scholar 

  9. Abdrakhimova, E.S. and Abdrakhimov, V.Z., Study of the effect of nanotechnogenic raw materials and chamotte on the structural and rheological properties of ceramic masses and physicomechanical properties of acid-resistant materials, Khim. Tekhnol., 2018, vol. 19, no. 12, pp. 548–557.

    Google Scholar 

  10. Abdrakhimov, V.Z. and Abdrakhimova, E.S., Oxidative processes in calcination of a porous aggregate based on oil production wastes and intershale clay, Khim. Tekhnol., 2018, vol. 19, no. 8, pp. 352–358.

    Google Scholar 

  11. Abdrakhimov, V.Z. and Abdrakhimova, E.S., Mössbauer spectroscopy study of the distribution of iron oxides in a porous filer based on intershale clay and oil sludge, Khim. Tekhnol., 2018, vol. 19, no. 1, pp. 41–46.

    Google Scholar 

  12. Abdrakhimov, V.Z., Phase composition of clinker bricks based on nonferrous metallurgy waste from East Kazakhstan, Khim. Tekhnol., 2019, vol. 20, no. 9, pp. 406–413.

    Google Scholar 

  13. Abdrakhimov, V.Z. and Abdrakhimova, E.S., Structure of the porosity of a porous aggregate based on burnt rock, burnt clay, and liquid glass mixtures, Khim. Tekhnol., 2019, vol. 20, no. 8, pp. 354–360.

    Google Scholar 

  14. Belyakov, A.V., Zo E Mo U, Popova N.A., and Ie Aung Min, Effect of porcelain additive on the properties of porous ceramics based on electrofused corundum, Nov. Ogneupory, 2016, no. 11, pp. 43–47.

  15. Kairakbaev, A.K., Abdrakhimova, E.S., and Abdrakhimov, V.Z., Use of enrichment wastes of nonferrous and ferrous metallurgy of Kazakhstan in the production of ceramic materials, Ekol. Prom. Ross., 2019, vol. 23, no. 6, pp. 12–16.

    Article  Google Scholar 

  16. Kairakbaev, A.K. and Abdrakhimov, V.Z., The use of slag and dust waste from the production of ferrochrome to obtain a porous aggregate contributes to environmental protection, Ekol. Khim., 2018, vol. 27, no. 6, pp. 340–348.

    Google Scholar 

  17. Kairakbaev, A.K. and Abdrakhimov, V.Z., Study of the technical properties of ferrous metallurgy waste—ferrodust from self-decaying low-carbon ferrochrome slags, Vestn. Aktyubinsk. Univ. im. S. Baisheva, 2019, no. 1, pp. 139–144.

  18. Abdrakhimova, E.S., Abdrakhimov, V.Z., and Kairakbaev, A.K., Patent 2602623. S1 S04V 14/24, Mixture to produce porous aggregate, Applied October 6, 2015; Published November 20, 2016. Byul. No. 32.

  19. Abdrakhimov, V.Z., Reduction of environmental damage to ecosystems by using intershale clay and ash–slag material in the production of bricks and porous aggregate, Ugol, 2018, no. 10, pp. 76–83.

  20. Abdrakhimov, V.Z., Study of the heat- and mass-transfer processes during firing of ceramic materials based on intershale clay and oil sludge, Buren. Neft, 2019, no. 3, pp. 52–55.

  21. Litvinova, G.I. and Pirozhkova, M.I., Petrography of Nonmetallic Inclusions, Moscow: Metallurgiya, 1972.

    Google Scholar 

  22. Petrov, V.P., Belyankina, E.D., and Kozyrev, V.V., Wollastonite, Moscow: Nauka, 1982.

    Google Scholar 

  23. Abdrakhimova, E.S. and Abdrakhimov, V.Z., Using wollastonite in producing ceramic wares, Materialovedenie, 2004, no. 10, pp. 47–52.

  24. Abdrakhimov, V.Z., Wollastonite in ceramic materials, Ogneupory Tekh. Keram., 2006, no. 7, pp. 41–44.

  25. Safronova, T.V., Vereshchagin, V.I., and Bayandina, E.V., Structural ceramics based on mixtures of low- and medium-plastic clay and diopside raw materials, Vestn. Tomsk. Gos. Arkhit.-Stroit. Univ., 2012, no. 2, pp. 154–162.

  26. Suleimenov, S.T., Physicochemical Processes of Structure Formation in Building Materials and Industrial Mineral Waste, Moscow: Manuskript, 1996.

    Google Scholar 

  27. Saibulatov, S.Zh., Study of the effect of the composition of ashes on the phase transformations in ash ceramics, Kompleksn. Ispol’z. Miner. Syr’ya, 1985, no. 11, pp. 78–81.

  28. Kukolev, G.V., Chemistry of Silicon and Physical Chemistry of Silicates, Moscow: Vysshaya shkola, 1966.

  29. Pashchenko, A.A., Myasnikov, A.A., Myasnikova, U.A., Starchevskaya, E.A., Gumen, V.S., Kruglitskaya, V.Ya., Shevchenko, L.A., Gorodov, V.S., Alekseenko, N.V., and Serbin, V.P., Physical Chemistry of Silicates, Moscow: Vysshaya shkola, 1986.

Download references

Author information

Authors and Affiliations

  1. Samara State University, 443086, Samara, Russia

    E. S. Abdrakhimova

  2. Samara State Economical University, 443090, Samara, Russia

    V. Z. Abdrakhimov

Authors
  1. E. S. Abdrakhimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Z. Abdrakhimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. Z. Abdrakhimov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by L. Smolina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abdrakhimova, E.S., Abdrakhimov, V.Z. Study of the Phase Composition of a Ceramic Sample Based on Ferrodust and Clay at Different Annealing Temperatures. Theor Found Chem Eng 56, 513–519 (2022). https://doi.org/10.1134/S0040579522040029

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579522040029

Search

Navigation