Abstract
The study of the method of the phase isotopic exchange (PIE) for the purification of gas flows containing deuterium and tritium is carried out. The experimental data obtained for a column with a diameter of 32 mm on a Sulzer copper oxidized packing showed that the mass transfer characteristics do not depend on the deuterium concentration. Based on these results, a mathematical model for separating three-isotope mixtures, which makes it possible to calculate the column parameters under different initial conditions, is developed.
Similar content being viewed by others
References
Perevezentsev, A.N., Rozenkevich, M.B., Pak, Yu.S., Marunich, S.A., and Bukin, A.N., Phase isotope exchange of water as a gas detritiation method, Theor. Found. Chem. Eng., 2013, vol. 47, no. 1, pp. 47–54. doi 10.1134/S0040579513010053
Sumchenko, A.S., Bukin, A.N., Marunich, S.A., Pak, Yu.S., Rozenkevich, M.B., Selivanenko, I.L., and Aung, T.M., Influence of packing columns starting modes on effectiveness of processes of water rectification and detritiation of gases by the method of phase isotopic exchange, Theor. Found. Chem. Eng., 2015, vol. 49, no. 3, pp. 252–260. doi 10.1134/S0040579515030136
Rozenkevich, M., Pak, Yu., Marunich, S., Bukin, A., Ivanova, A., Perevezentsev, A., and Lepetit, L., Main features of the technology for air detritiation in scrubber column, Fusion Sci. Technol., 2017, vol. 70, no. 3, p. 435.
Rozenkevich, M.B., Pak, Yu.S., Bukin, A.N., Marunich, S.A., Ivanova, A.S., and Perevezentsev, A.N., Purification of gas streams from the vapors of tritiated water: A comparison between adsorption and phase isotope exchange methods, V Mezhdunarodnaya konferentsiya-shkola po khimicheskoi tekhnologii KhT’16: sbornik tezisov dokladov satellitnoi konferentsii XX Mendeleevskogo s"ezda po obshchei i prikladnoi khimii: v 3 tomakh (V International School and Conference on Chemical Engineering CE’16: A Satellite Conference of XX Mendeleev Congress on General and Applied Chemistry: Abstracts of Papers in Three Volumes) (Volgograd, 2016), Volgograd: Volgogr. Gos. Tekh. Univ., 2016, vol. 2, p. 461.
Kel’tsev, N.A., Osnovy adsorbtsionnoi tekhniki (Fundamentals of Adsorption Techniques), Moscow: Khimiya, 1984.
GOST (State Standard) R 8.811–2012: State System for Ensuring the Uniformity of Measurements. Psychrometric Tables. Construction, Content, and Computational Relationships, 2014.
Andreev, B.M., Zel’venskii, Ya.D., and Katal’nikov, S.G., Tyazhelye izotopy vodoroda v yadernoi tekhnike (Heavy Hydrogen Isotopes in Nuclear Engineering), Moscow: IzdAT, 2000.
Sanitary Regulations and Standards SanPiN 2.6.1.2523-09: Radiation Safety Standards, Moscow: Fed. Tsentr Gig. Epidemiol. Rospotrebnadzora, 2009.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.N. Bukin, V.S. Moseeva, M.B. Rozenkevich, 2018, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2018, Vol. 52, No. 4, pp. 384–390.
Rights and permissions
About this article
Cite this article
Bukin, A.N., Moseeva, V.S. & Rozenkevich, M.B. Isotope Purification of Gases Containing Deuterium and Tritium by the Method of the Phase Isotopic Exchange of Water. Theor Found Chem Eng 52, 488–494 (2018). https://doi.org/10.1134/S0040579518040371
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0040579518040371