Abstract
The thermal stability of the blends based on polylactide and low-density polyethylene of various compositions is studied. A decrease in the degradation temperature is observed with an increase in the polylactide content in samples (from 414°C for 100% polyethylene to 364°C for 100% polylactide). The influence of aged polyethylene on the thermooxidative degradation of the blends containing 30 wt % polylactide is studied. The third component (aged polyethylene) is determined to accelerate the initial oxidation stage.
Similar content being viewed by others
REFERENCES
Aging and Stabilization of Polymers, Ed. by A. S. Kuz’minskii (Khimiya, Moscow, 1966).
N. M. Emanuel’ and A. L. Buchachenko, Chemical Physics of Molecular Degradation and Stabilization of Polymers (Nauka, Moscow, 1988).
Sh. Lv, Y. Zhang, and H. Tan, “Thermal and thermooxidative degradation kinetics and characteristics of poly(lactic acid) and its composites,” Waste Managem. 87, 335–344 (2019).
Y. V. Tertyshnaya, L. S. Shibryaeva, and A. A. Ol’khov, “Thermal oxidation and degradation of poly-3-hydroxybutyrate nonwoven materials,” Rus. J. Phys. Chem. B 9 (3), 498–503 (2015).
Yu. V. Tertyshnaya, L. S. Shibryaeva, and A. A. Popov, “Thermooxidative degradation of blends based on poly(3-hydroxybutyrate). Specifics of the process,” Rus. J. Phys. Chem. B 6 (1), 38–41 (2012).
F.-D. Kopinke and K. Mackenzie, “Mechanistic aspects of the thermal degradation of poly(lactic acid) and poly(β-hydroxybutyric acid),” J. Anal. Appl. Pyrol. 40, 43–53 (1997).
F.-D. Kopinke, M. Remmler, and K. Mackenzie, “Thermal decomposition of biodegradable polyesters. I. Poly(β-hydroxybutyric acid),” Polym. Degrad. Stabil. 52, 25–38 (1996).
Yu. V. Tertyshnaya and M. V. Podzorova, “Composite materials based on polylactide and poly-3-hydroxybutyrate “green” polymers,” Rus. J. Appl. Chem. 91 (3), 417–423 (2018).
Y. F. Kim, C. N. Choi, Y. D. Kim, K. Y. Lee, and M. S. Lee, “Compatibilization of immiscible poly(L-lactide) and low density polyethylene blend,” Fib. Polym. 5, 270–274 (2004).
L. As’habi, S. H. Jafari, H. A. Khonakdar, B. Kretzschmar, U. Wagenknecht, and G. Heinrich, “Effect of clay type and polymer matrix on microstructure and tensile properties of PLA/LLDPE/Clay nanocomposites,” J. Appl. Polym. Sci. 130, 749–758 (2013).
H. Ebadi-Dehaghani, H. A. Khonakdar, M. Barikani, and S. H. Jafari, “Experimental and theoretical analyses of mechanical properties of PP/PLA/Clay nanocomposites,” Composites: Part B 69, 133–144 (2015).
Yu. V. Tertyshnaya, M. V. Podzorova, and T. V. Monakhova, “Solid-phase thermal oxidation of polyethylene–polylactide blends,” Rus. J. Phys. Chem. B 13 (2), 354–361 (2019).
M. V. Podzorova, Yu. V. Tertyshnaya, T. V. Monakhova, and A. A. Popov, “Thermal oxidation and structure of polylactide–polyethylene blends,” Rus. J. Phys. Chem. B 10 (5), 825–829 (2016).
L.-T. Lim, R. Auras, and M. Rubino, “Processing technologies for poly(lactic acid),” Progr. Polym. Sci. 33, 820 (2008).
ACKNOWLEDGMENTS
This work was carried out using the equipment of the Centers for Collective Use “Novel Materials and Technologies” at the Emanuel Institute of Biochemical Physics (Russian Academy of Sciences) and “Scientific Equipment” at the Plekhanov Russian University of Economics.
Funding
This work was carried out in terms of state assignment no. 1201253305 for the Emanuel Institute of Biochemical Physics (Russian Academy of Sciences), theme 44.3 “Polymer Materials Science: Kinetics and Mechanism of Chemical and Physical Processes in Polymers, Composites, and Biological Systems.”
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by E. Yablonskaya
Rights and permissions
About this article
Cite this article
Podzorova, M.V., Tertyshnaya, Y.V. Thermal and Thermooxidative Degradation of Blends Based on Polylactide and Polyethylene. Russ. Metall. 2020, 1182–1185 (2020). https://doi.org/10.1134/S0036029520100213
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036029520100213