Skip to main content
Log in

Volume and Surface Properties of Antimony-Containing Nickel Melts

  • Published:
Russian Metallurgy (Metally) Aims and scope

Abstract

A decrease in the detrimental effect of an antimony impurity in nickel is considered using structure-sensitive parameters, namely, density and surface tension. Samples of experimental heats containing 0.01–0.05 wt % Sb are prepared from a preliminarily cast master alloy. Antimony additions are found to increase the density of the nickel melt substantially. A negative density hysteresis appears in the temperature dependences recorded upon cooling. Antimony in the nickel melt is found to have a high surface activity and to decrease its surface tension strongly. When the melt is heated, its surface tension increases, which is accompanied by the passage of antimony into the volume and by changes in the volume and surface solution compositions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. I. R. Kryanin, I. L. Mirkin, and L. P. Trusov, “Kinetics of structural transformations and the fracture of high-temperature alloys during long-term tests,” Metalloved. Term. Obrab. Met., No. 8, 8–19 (1967).

  2. A. V. Ryabov and E. A. Trofimov, “Improvement of the technique of experimental study of the bismuth solubility in nickel,” Vestn. Yuzh.-Ural. Gos Univer., Ser. Metallurgiya, No. 34, 32–34 (2010).

    Google Scholar 

  3. V. V. Averin, G. A. Lopukhov, and S. I. Popel, Theory of Metallurgical Processes (Metallurgiya, Moscow, 1978).

    Google Scholar 

  4. Phase Diagrams of Binary Metallic Systems: A Handbook, Ed. by N. P. Lyakishev (Mashinostroenie, Moscow, 2001), Vol. 3.

    Google Scholar 

  5. A. P, Lyubchenko, High-Strength Cast Iron (Metallurgiya, Moscow, 1982).

  6. K. S. Filippov and V. V. Molokanov, “Density and surface tension of the melt of an amorphous alloy as a function of the structure of the initial sample,” Russ. Metall. (Metally), No. 3, 187–191 (2013).

  7. M. V. Pridantsev and T. V. Ostapenko, “Effect of rare-earth metal on the structure and properties of Kh18N10T, Kh17N13M2T, and 00Kh17N11 steels,” Izv. Akad. Nauk SSSR, Ser. Met., No. 3, 136–140 (1974).

  8. V. V. Loza, D. P. Dolinin, and T. M. Voronina, “Effect of crown on the quality of vacuum arc remelting ingots,” in Physicochemical Fundamentals of Vacuum Processes in Ferrous Metallurgy (Nauka, Moscow, 1984), pp. 142–146.

    Google Scholar 

  9. V. A. Boyarshinov, A. G. Shalimov, A. I. Shcherbakov, et al., Refining Remelting of Steel and Alloys in Vacuum (Metallurgiya, Moscow, 1979).

    Google Scholar 

  10. B. G. Chernov, “On the kinetics of evaporation of impurities from the iron and nickel melt in vacuum,” Izv. Akad. Nauk SSSR, Ser. Met., No. 3, 76–80 (1972).

  11. Ya. E. Gol’dshtein and V. G. Mizin, Modification and Microalloying of Cast Iron and Steel (Metallurgiya, Moscow, 1986).

    Google Scholar 

  12. K. S. Filippov, “Density and surface tension of the melt of a high-temperature alloy as a function of the structure of the initial sample,” in Proceedings of XV International Conference on Modern Problems of Electrometallurgy of Steel (Izdat. Tsentr YuzhUrGU, Chelyabinsk, 2013), Vol. 1, pp. 83–88.

  13. Yu. V. Naidich and V. M. Eremenko, “Sessile drop method for determination of the surface tension and the density of liquid metals at high temperatures,” Fiz. Met. Metalloved. 11 (6) 883–885 (1961).

    CAS  Google Scholar 

  14. K. S. Filippov, “Density and surface tension of the melts of iron, nickel, and Fe–Ni–Cr alloys produced from metals with different initial structures,” Fiz. Khim. Obrab. Met., No. 1, 94–97 (2011).

  15. K. S. Filippov, V. I. Kashin, and E. B. Mel’nikova, “Change in the internal energy of a nickel-based melt during a temperature hysteresis of density and surface tension,” in Proceedings of X All-USSR Conference on Physicochemical Fundamentals of Metallurgical Processes (Chermetinformatsiya, Moscow, 1991), Vol. 3.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. S. Filippov.

Additional information

Translated by K. Shakhlevich

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Filippov, K.S. Volume and Surface Properties of Antimony-Containing Nickel Melts. Russ. Metall. 2018, 677–684 (2018). https://doi.org/10.1134/S0036029518070042

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036029518070042

Navigation