Abstract
The chemical interaction of uncompacted monocarbide NbC and WC powders, which were taken at mass carbide ratios NbC: WC = 10: 1, 3: 1, 1: 1, and 1: 3 and a total carbide content of 20 wt %, in molten copper is studied at 1300°C. The primary and secondary phase transformations that result in the appearance and decomposition of an (Nb,W)C solid solution are analyzed. The activating role of low-frequency vibration is shown.
Similar content being viewed by others
References
L. E. Bodrova, E. A. Popova, E. A. Pastukhov, A. V. Dolmatov, and E. Yu. Goida, “Synthesis of niobium carbides in copper melts,” Russian Metallurgy (Metally), No. 9, 810–814 (2010).
L. E. Bodrova and E. A. Pastukhov, “Interaction between vanadium carbide and aluminum and copper melts,” Russian Metallurgy (Metally), No. 2, 112–114 (2013).
L. E. Bodrova, E. Yu. Goida, E. A. Pastukhov, L. A. Marshuk, and E. A. Popova, “Interaction of tungsten with tungsten carbide in a copper melt,” Russian Metallurgy (Metally), No. 7, 491–496 (2013).
E. Ignat’ev, E. Pastukhov, and L. Bodrova, Method to Obtain Alloys of Low Frequency Processing of Their Melts (LAP LAMBERT Akad. Publ., Saarbrucken, 2013).
A. P. Savitskii, Liquid-Phase Sintering of Systems with Interacting Components (Nauka, Novosibirsk, 1991).
V. N. Antsiferov, G. V. Bobrov, L. K. Druzhinin, et al., Powder Metallurgy and Sprayed Coatings: A Textbook (Metallurgiya, Moscow, 1987).
E. A. Popova, L. E. Bodrova, V. P. Chentsov, et al., “Wetting of titanium, niobium, and chromium carbides by molten copper,” Rasplavy, No. 2, 3–9 (2009).
L. E. Bodrova, A. B. Shubin, E. Yu. Goida, S. A. Petrova, and O. M. Fedorova, “Effect of mechanical activation on the synthesis of complex carbide (Nb,W)C in molten copper,” in Proceedings of 14 Russian Conference on the Structure and Properties of Metallic and Slag Melts (Izd. UrO RAN, Yekaterinburg, 2015), pp. 178–179.
L. E. Bodrova, E. A. Pastukhov, and E. Yu. Goida, “Effect of mechanical activation on the self-fragmentation of the carbide phases in Cu–W–Nb–C alloys,” Rasplavy, No. 6, 11–15 (2015).
G. V. Samsonov and Ya. S. Umanskii, Hard Compounds of Refractory Metals (Metallurgizdat, Moscow, 1957).
H. Hollek, Binary and Ternary Carbide and Nitride Systems of Transition Metals: A Handbook, Ed. by Yu. V. Levinskii (Metallurgiya, Moscow, 1988).
K. I. Chebotarev et al., X-ray Diffraction Tabulated Process (RTP) Program (VNII Neorg. Mater., Moscow, 2002).
A. I. Gusev, Physical Chemistry of Nonstoichiometric Refractory Compounds (Nauka, Moscow, 19991).
H. Nowotny and R. Kieffer, “Roentgenographisehe untersuchungvon karbidsystemen,” Z. Metallkd. 38, 257 (1947).
A. A. Rempel’ and A. I. Gusev, “Formation and estimation of the homogeneity of strongly nonstoichiometric disordered and ordered carbides,” FTT 42 (7), 1243–1249 (2000).
G. V. Samsonov, G. Sh. Upadkhaya, and V. S. Neshpor, Physical Metallurgy of Carbides (Nauk. Dumka, Kiev, 1974).
E. G. Gutsalenko, “Forecast of tungsten semicarbide in tungsten ceramic hot-pressed composites with electronsolidation of powders on a monocarbide base,” in Vestn. Natsion. Tekhn. Univ. KhPI (KhPI, Khar’kov, 2010), pp. 52–64.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.E. Bodrova, O.M. Fedorova, A.B. Shubin, E.A. Pastukhov, 2017, published in Metally, 2017, No. 2, pp. 52–56.
Rights and permissions
About this article
Cite this article
Bodrova, L.E., Fedorova, O.M., Shubin, A.B. et al. Interaction of niobium and tungsten monocarbides in molten copper. Russ. Metall. 2017, 204–208 (2017). https://doi.org/10.1134/S003602951703003X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S003602951703003X