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Solidification of the eutectic Ga–Sn alloy

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Abstract

Cyclic thermal analysis is used to study the effect of overheating of the eutectic Ga–8.5 mol % Sn melt on the presolidification supercooling. It is found that, when the liquid eutectic is overheated above the eutectic temperature (T e = 293.5 K) and is subsequently cooled, the dependence of the presolidification supercooling on the overheating temperature exhibits monotonic ascending behavior. The maximum supercooling after heating of the melt to 339 K is 26 K. The kinetic and thermodynamic parameters of eutectic solidification are calculated using the thermal analysis curves measured during melting.

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References

  1. L. I. Glushkova and S. G. Konnikov, “Interaction of components in paste Ga-based solders,” in Forming of Metals and Welding (Leningrad Polytech. Institute, Leningrad, 1969), Vol. 308, pp. 205–208.

    Google Scholar 

  2. V. S. Kazakov, “Development of gallium past solders for low-temperature soldering of copper and titanium alloys with ceramics”, Extended Abstract of Candidate’s Dissertation in Engineering, Krasnoyarsk, 2007.

    Google Scholar 

  3. V. I. Krayukhin, “Composition of materials for preparation of strengthening pasts,” RF Patent 2345865, 2009.

    Google Scholar 

  4. S. P. Yatsenko, Gallium. Interaction with Metals (Nauka, Moscow, 1974), pp. 26–28.

    Google Scholar 

  5. V. P. Chentsov, V. G. Shevchenko, A. G. Mozgovoi, and M. A. Pokrasin, “Density and surface tension of heavy liquid-metal coolants,” Perspektivnye Materially, No. 3, 46–52 (2011).

    Google Scholar 

  6. G. P. Brekharya, “Effect of cooling rate on the supercooling of metals and alloys and structure-formation,” Candidate’s Dissertation in Engineering (Dnepropetrovsk, 1976).

    Google Scholar 

  7. J. Y. Perepechko, Mater. Sci. Eng, 65 (1), 125–135 (1984).

    Article  Google Scholar 

  8. V. D. Aleksandrov and S. A. Frolova, “Effect of the overheating of the gallium melt on its supercooling during solidification,” Russian Metallurgy, No. 1, 16–21 (2014).

    Google Scholar 

  9. V. D. Aleksndrov and S. A. Frolova, “Effect of time–temperature treatment of liquid on the solidification of Sn–Bi alloys,” Rasplavy, No. 3, 14–21 (2003).

    Google Scholar 

  10. Phase Diagrams of Binary Metallic Alloys: Handbook, Ed. by N. P. Lyakishev (Mashinostroenie, Moscow, 1996, 1997, 2000).

  11. V. D. Aleksandrov, V. A. Postnikov, S. A. Frolova, and S. V. Prokof’ev, Ukraine Patent 83721, Byull. Izobret., No. 15, (2008).

  12. V. M. Glazov, Foundations of Physical Chemistry: Tutorial for Institution of Higher Education (Vyssh. Shkola, Moscow, 1981).

    Google Scholar 

  13. Properties of Elements, Ed. by. E. M. Drits (Metallurgiya, Moscow, 1985).

  14. A. N. Krestovnikov and V. N. Vigdorovich, Chemical Thermodynamics (Metallurgiya, Moscow, 1974).

    Google Scholar 

  15. A. D. Drozdin, M. V. Dudorov, V. E. Roshchin, L. A. Gamov, and L. D. Menikhes, “Mathematic model of formation of crystal nuclei in an supercooled melt,” Vestn. Yuzhno-Ural. Gos. Univ., No. 11, 66–73 (2012).

    Google Scholar 

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Correspondence to V. D. Aleksandrov.

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Original Russian Text © V.D. Aleksandrov, S.A. Frolova, Sh.K. Amerkhanova, 2016, published in Metally, 2016, No. 3, pp. 47–52.

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Aleksandrov, V.D., Frolova, S.A. & Amerkhanova, S.K. Solidification of the eutectic Ga–Sn alloy. Russ. Metall. 2016, 437–442 (2016). https://doi.org/10.1134/S0036029516050025

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  • DOI: https://doi.org/10.1134/S0036029516050025

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