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Effect of the Granulometric Composition of Natural Graphite and the Means of Synthesis on the Pore Structure of Thermally Expanded Graphite

  • PHYSICAL CHEMISTRY OF DISPERSED SYSTEMS AND SURFACE PHENOMENA
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Abstract

A 2D-NLDFT-HS study is performed of the effect the state of oxidation of the graphite matrix has on the parameters of micro-, meso-, and macropore structures of thermally expanded graphite (TEG). A wide range of the stage numbers of graphite intercalation compounds synthesized from natural flake graphite of the same grade is considered, along with the intercalant that is used and the particle size of the original graphite. The 2D-NLDFT-HS model provides a more accurate description of low-temperature nitrogen adsorption/desorption isotherms than other means.

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Funding

This work was supported by the RF Ministry of Science and Higher Education as part of project no. АААА-А16-116053110012-5 and the development program of the interfaculty scientific and educational school “The Future of the Planet and Global Environmental Changes.”

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. V. Kravtsov, O. N. Shornikova, A. I. Bulygina & V. V. Avdeev

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. B. Solopov

Authors
  1. A. V. Kravtsov
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  2. O. N. Shornikova
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  3. A. I. Bulygina
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  4. A. B. Solopov
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  5. V. V. Avdeev
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Corresponding author

Correspondence to A. V. Kravtsov.

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The authors declare they have no conflicts of interest.

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Translated by M. Timoshinina

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Kravtsov, A.V., Shornikova, O.N., Bulygina, A.I. et al. Effect of the Granulometric Composition of Natural Graphite and the Means of Synthesis on the Pore Structure of Thermally Expanded Graphite. Russ. J. Phys. Chem. 96, 2729–2736 (2022). https://doi.org/10.1134/S0036024422120172

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  • DOI: https://doi.org/10.1134/S0036024422120172

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