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Physical Chemistry of Water Fluids As a Basis for Technological Processes with Their Participation

  • IN COMMEMORATION OF ACADEMICIAN V.V. LUNIN: SELECTED CONTRIBUTIONS FROM HIS STUDENTS AND COLLEAGUES
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Abstract

Some physicochemical properties of water fluids (WFs) that underlie their applications and criteria for determining the parameter domains with qualitative differences in their physical state were considered. The qualitative relationship between the type and intensity of intermolecular interactions in various substances and their macroscopic characteristics (normal boiling temperatures and critical points) was analyzed. Special attention was paid to the density as a macroscopic parameter that reflects the influence of intermolecular interactions in the WF. Despite the technological importance of isobaric dependences, for understanding the mechanisms of various effects on the properties of fluids, it is necessary to consider isochoric and isothermal dependences, especially when analyzing the dielectric properties of water and its dissociation into counterions.

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ACKNOWLEDGMENTS

With deep gratitude I keep memory of the years when I had good fortune to communicate with Academician Lunin and work with him both on various projects in the “supercritical” community and in the editorial boards of the journals headed by Valery Vasil’evich. With gratitude and sorrow I also recall my first superior and close acquaintance who also recently passed away—Aleksandr Zakharovich Shabutov, with whom I studied a complex problem, namely, the solubility of chlorine and hydrogen chloride in various media and worked on apparatus design and high-pressure experimental techniques.

Funding

This study was financially supported by the Russian Foundation for Basic Research (project no. 18-29-06055).

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  1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    M. Yu. Sinev

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Correspondence to M. Yu. Sinev.

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Translated by L. Smolina

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Sinev, M.Y. Physical Chemistry of Water Fluids As a Basis for Technological Processes with Their Participation. Russ. J. Phys. Chem. 95, 418–428 (2021). https://doi.org/10.1134/S0036024421030195

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