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Influence of DETA on the Tin Promotion of Mesoporous Sn–Ti Catalysts for Cyclohexanone Oxidation by Molecular Oxygen

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

A series of Sn–Ti(n)–DETA catalysts were prepared by a simple EISA method assisted by post-treatment of diethylenetriamine (DETA) solution, and several characterization techniques, including XRD, N2 sorption, Raman, ICP, UV–Vis DRS, pyridine-adsorbed IR, SEM, and TEM, were adopted to investigate their physical and chemical properties. The influence of DETA on the tin incorporation promotion of mesoporous Sn–Ti catalysts and their catalytic performance in the B–V oxidation of cyclohexanone by molecular oxygen were also studied. The mesopores with higher surface area and larger pore volume can be kept well when the weight percent of tetrahedrally incorporated tin species would be promoted up to 21% owing to the stronger alkalinity and more primary amine of the DETA molecule resulting in higher Lewis acidity. The cyclohexanone conversion of 95.5% and caprolactone selectivity of 96.8%, respectively, over Sn–Ti(21)–DETA catalyst were obtained, and it shows good catalytic stability even after reused for 5 times.

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Authors and Affiliations

  1. College of Chemical Engineering, Nanjing Tech University, 210009, Nanjing, P. R. China

    Fanqing Li, Zhiwei Zhou, Zhirui Liu, Chuanfa Liu, Hao Huang, Guang Liu & Wenliang Wu

  2. Technology and Finance Service Center of Jiangsu Province, Productivity Center of Jiangsu Province, 210042, Nanjing, P. R. China

    Juan Qin

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  1. Fanqing Li
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  2. Zhiwei Zhou
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  3. Juan Qin
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  4. Zhirui Liu
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  5. Chuanfa Liu
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  7. Guang Liu
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Fanqing Li, Zhou, Z., Qin, J. et al. Influence of DETA on the Tin Promotion of Mesoporous Sn–Ti Catalysts for Cyclohexanone Oxidation by Molecular Oxygen. Russ. J. Phys. Chem. 94, 2226–2232 (2020). https://doi.org/10.1134/S0036024420110230

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  • DOI: https://doi.org/10.1134/S0036024420110230

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