Abstract
Physicochemical transformations that occur during the low-temperature synthesis of zirconium carbonitride via the reduction of zirconia with magnesium in the presence of sodium carbonate in a nitrogen atmosphere are studied. Both reactions leading to the formation of Zr2CN and side processes occurring in the charge are studied by means of differential scanning calorimetry. Based in the results, it is concluded that zirconium carbonitride can be synthesized in the temperature range of 600–675°C. It is shown that using graphite does not lead to the formation of zirconium carbide or zirconium carbonitride in the investigated range of temperatures, while the use of urea has hardly any effect on the final product.
Similar content being viewed by others
REFERENCES
M. Jalaly, F. J. Gotor, and M. J. Sayagues, J. Solid State Chem. 267, 106 (2018).
L. E. Toth, Transition Metal Carbides and Nitrides (Academic, London, 1971).
S. T. Oyama, The Chemistry of Transition Carbides and Nitrides (Hartnolls, Cornwall, 1996).
S. E. Potts, C. J. Carmalt, C. S. Blackman, et al., Organometalics 28, 1838 (2009).
C. J. Carmalt, A. C. Newport, S. A. O’Neil, et al., Inorg. Chem. 44, 615 (2005).
T. Zhang, S. F. Zheng, and G. Wen, Mater. Lett. 132, 277 (2014).
F. L. Huang, C. B. Cao, X. Xiang, et al., Diamond Relat. Mater. 13, 1757 (2004).
D. Chen, Y. Huang, X. Hu, et al., Materials 11, 387 (2018).
G. Puyoo, F. Teyssandier, R. Pailler, et al., Carbon 122, 19 (2017).
Sh. A. Faziev, M. S. Paizullakhanov, and Sh. R. Nurmatov, Heliotech. Mater. Sci. 46, 53 (2010).
J. Sun, B. Liang, Y. Huang, et al., Catal. Today 274, 123 (2016).
M. Jalay, F. J. Gotor, and M. J. Sayagues, J. Alloys Compd. 763, 18 (2018).
L. Wang, Y. Su, and Y. Q. Zhu, Int. J. Refract. Met. Hard Mater. 38, 134 (2013).
S. A. Rasaki, B. Zhang, K. Anbalgam, et al., Prog. Solid State Chem. 50, 1 (2018).
L. Wang, W. Xi, T. Mei, et al., J. Ceram. Soc. Jpn. 125, 789 (2017).
J. Ma and Y. Du, J. Alloys Compd. 448, 215 (2008).
J. Ma, M. Wu, Y. Du, et al., Mater. Sci. Eng. B 153, 96 (2008).
J. Ma, M. Wu, Y. Du, et al., Mater. Lett. 63, 905 (2009).
P. M. Schaber, J. Colson, S. Higgins, et al., Thermochim. Acta 424, 131 (2004).
ACKNOWLEDGMENTS
This work was performed as part of the Federal Target Program “Research and Development in Priority Fields of Science and Engineering in Russia, 2014–2020” (agreement no. 14.578.21.0200, unique identifier PNIER RFMEFI57816X0200).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by M. Timoshinina
Rights and permissions
About this article
Cite this article
Shishkin, R.A., Kudyakova, V.S. Low-Temperature Synthesis of Zirconium Carbonitrode via the Reduction of Zirconia with Magnesium in the Presence of Sodium Carbonate in a Nitrogen Atmosphere. Russ. J. Phys. Chem. 93, 1455–1459 (2019). https://doi.org/10.1134/S0036024419080272
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024419080272