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Synthesis of Highly Dispersed Zirconium Carbide

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The reduction of zirconium oxide with nanofibrous carbon to obtain highly dispersed zirconium carbide was studied. The optimum reduction conditions were determined. The reaction products were identified using modern physicochemical methods (scanning electron microscopy, low-temperature nitrogen adsorption, sedimentation analysis, differential scanning calorimetry). The product obtained appeared to be single-phase zirconium carbide containing no more than 2 wt % impurities. The powder particles are aggregated (mean diameter 14.9–15.0 μm, specific surface area 1.5–1.7 m2 g–1). The oxidation of zirconium carbide starts at 480°С and is complete at 800°С.

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Authors and Affiliations

  1. Novosibirsk State Technical University, ul. Karla Marksa 20, Novosibirsk, 630073, Russia

    Yu. L. Krutskii, M. V. Popov, N. Yu. Cherkasova, T. S. Kvashina, V. I. Chushenkov, A. I. Smirnov, A. V. Felof’yanova & A. I. Aparnev

  2. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. A. Maksimovskii

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    E. A. Maksimovskii & O. V. Netskina

  4. Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    O. V. Netskina

Authors
  1. Yu. L. Krutskii
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  2. E. A. Maksimovskii
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  3. M. V. Popov
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  4. O. V. Netskina
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  5. N. Yu. Cherkasova
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  6. T. S. Kvashina
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  7. V. I. Chushenkov
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  8. A. I. Smirnov
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  9. A. V. Felof’yanova
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  10. A. I. Aparnev
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Correspondence to Yu. L. Krutskii.

Additional information

Original Russian Text © Yu.L. Krutskii, E.A. Maksimovskii, M.V. Popov, O.V. Netskina, N.Yu. Cherkasova, T.S. Kvashina, V.I. Chushenkov, A.I. Smirnov, A.V. Felof’yanova, A.I. Aparnev, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 3, pp. 389−396.

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Krutskii, Y.L., Maksimovskii, E.A., Popov, M.V. et al. Synthesis of Highly Dispersed Zirconium Carbide. Russ J Appl Chem 91, 428–435 (2018). https://doi.org/10.1134/S107042721803014X

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  • DOI: https://doi.org/10.1134/S107042721803014X

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