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Properties of Hydrogen Bonds in Water and Monohydric Alcohols

  • STRUCTURE OF MATTER AND QUANTUM CHEMISTRY
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Abstract

The average number of hydrogen bonds formed by water, methanol, and ethanol molecules is studied, depending on temperature. An analysis of the specific volume and heat of vaporization, depending on temperature in the range from the triple point to the critical point, is used. It is shown with good accuracy that the changes in these thermodynamic quantities are of an argon-like nature, while small deviations are associated with the formation of hydrogen bonds. The average number of hydrogen bonds formed by water, methanol, and ethanol molecules is thus determined along with the effective diameter of these molecules, and they are compared to the literature data.

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REFERENCES

  1. D. S. Eisenberg and W. Kauzmann, The Structure and Properties of Water (Oxford Univ. Press, Oxford, 2005).

    Book  Google Scholar 

  2. V. Ya. Antonchenko, A. S. Davydov, and V. V. Il’in, Principles of the Physics of Water (Naukova Dumka, Kiev, 1991) [in Russian].

    Google Scholar 

  3. Water. A Comprehensive Treatise, Ed. by F. Franks (Plenum, New York, 1972).

    Google Scholar 

  4. M. F. Chaplin, Water Structure and Behavior. http://www.lsbu.ac.uk/water/index.html.

  5. L. Pauling, General Chemistry (Freeman, San Francisco, 1970).

    Google Scholar 

  6. G. C. Pimentel and A. L. McClellan, The Chemical Bond (W. H. Freeman, San Francisco, 1960).

    Google Scholar 

  7. N. D. Sokolov, Usp. Fiz. Nauk 57, 205 (1955).

    Article  CAS  Google Scholar 

  8. M. Dolgushin, ITPh Preprint No. 77-83 (Inst. Theor. Phys., Kiev, 1977).

  9. P. Barnes, in Progress in Liquid Physics, Ed. by C. A. Croxton (Wiley, New York, 1978).

    Google Scholar 

  10. H. C. Berendsen and G. A. Velde, in CECAM Report of Workshop on Molecular Dynamics and Monte Carlo Calculations on Water, June 19–Aug. 11, 1972, p. 63.

  11. R. L. Fulton and P. Perhaes, J. Phys. Chem. A 102, 9001 (1998).

    Article  CAS  Google Scholar 

  12. P. V. Makhlaichuk, N. P. Malomuzh, and I. V. Zhyganiuk, Ukr. J. Phys. 57, 113 (2012).

    CAS  Google Scholar 

  13. N. P. Malomuzh, M. V. Timofeev, and I. V. Zhyganiuk, J. Mol. Liq. 242, 175 (2017).

    Article  CAS  Google Scholar 

  14. T. V. Lokotosh, N. P. Malomuzh, and V. L. Zakharchenko, J. Struct. Chem. 44, 1001 (2003).

    Article  CAS  Google Scholar 

  15. N. P. Malomuzh and A. V. Oleinik, J. Struct. Chem. 49, 1055 (2008).

    Article  CAS  Google Scholar 

  16. A. I. Fisenko, N. P. Malomuzh, and A. V. Oleynik, Chem. Phys. Lett. 450, 297 (2008).

    Article  CAS  Google Scholar 

  17. S. V. Lishchuk, N. P. Malomuzh, and P. V. Makhlaichuk, Phys. Lett. A 374, 2084 (2010).

    Article  CAS  Google Scholar 

  18. L. A. Bulavin, N. P. Malomuzh, and K. S. Shakun, Ukr. J. Phys. 50, 653 (2005).

    CAS  Google Scholar 

  19. A. I. Fisenko, N. P. Malomuzh, and A. V. Oleynik, Chem. Phys. Lett. 450, 297 (2008).

    Article  CAS  Google Scholar 

  20. Ch. Tegeler, R. Span, and W. Wagner, J. Phys. Chem. Ref. Data 28, 779 (1999).

    Article  CAS  Google Scholar 

  21. A. Saul and W. Wagner, J. Phys. Chem. Ref. Data 16, 893 (1987).

    Article  CAS  Google Scholar 

  22. R. D. Goodwin, J. Phys. Chem. Ref. Data 16, 799 (1987).

    Article  CAS  Google Scholar 

  23. H. E. Dillon and S. G. Penoncello, Int. J. Thermophys. 25, 321 (2004).

    Article  CAS  Google Scholar 

  24. NIST Database. http://webbook.nist.gov/chemistry/fluid/.

  25. S. L. Rivkin and A. A. Aleksandrov, Thermophysical Properties of Water and Water Vapor (Energiya, Moscow, 1980) [in Russian].

    Google Scholar 

  26. A. Z. Patashinskii and V. L. Pokrovskii, Fluctuation Theory of Phase Transitions (Nauka, Moscow, 1982) [in Russian].

    Google Scholar 

  27. V. L. Kulinskii and N. P. Malomuzh, Phys. Rev. E 67, 011501 (2003).

    Article  CAS  Google Scholar 

  28. V. L. Kulinskii, N. P. Malomuzh, and I. O. Matvejchuk, Phys. A (Amsterdam, Neth.) 388, 4560 (2009).

  29. P. V. Makhlaichuk, V. N. Makhlaichuk, and N. P. Malomuzh, J. Mol. Liq. 225, 577 (2017).

    Article  CAS  Google Scholar 

  30. G. Malenkov, Condens. Matter 21, 283101 (2009).

    Article  CAS  Google Scholar 

  31. Yu. I. Naberukhin and V. P. Voloshin, Z. Phys. Chem. 223, 1119 (2009).

    Article  CAS  Google Scholar 

  32. V. P. Voloshin, Yu. I. Naberukhin, and G. G. Malenkov, Strukt. Dinam. Mol. Sist., No. 10, 12 (2011).

  33. R. H. Henchman and Sh. J. Irudayam, J. Phys. Chem. B 114, 1792 (2010).

    Article  CAS  Google Scholar 

  34. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 5: Statistical Physics, Part 1 (Nauka, Moscow, 1995; Pergamon, Oxford, 1980).

  35. V. Yu. Bardik and V. M. Sysoev, Low Temp. Phys. 24, 602 (1998).

    Article  CAS  Google Scholar 

  36. V. Yu. Bardic, N. P. Malomuzh, and V. M. Sysoev, J. Mol. Liq. 120, 27 (2005).

    Article  CAS  Google Scholar 

  37. V. Yu. Bardic, N. P. Malomuzh, K. S. Shakun, and V. M. Sysoev, J. Mol. Liq. 127, 96 (2006).

    Article  CAS  Google Scholar 

  38. L. A. Bulavin, V. L. Kulinskii, and N. P. Malomuzh, J. Mol. Liq. 161, 19 (2011).

    Article  CAS  Google Scholar 

  39. The Chemist’s Handbook, Ed. by B. P. Nikol’skii (Khimiya, Moscow, 1966), Vol. 1 [in Russian].

    Google Scholar 

  40. L. A. Bulavin, T. V. Lokotosh, and N. P. Malomuzh, J. Mol. Liq. 137, 1 (2008).

    Article  CAS  Google Scholar 

  41. M. G. Kiselev, Doctoral (Chem.) Dissertation (Inst. Solution Chem., Ivanovo, 2003).

  42. A. Idrissi, R. D. Oparin, S. P. Krishtal, et al., Faraday Discuss. 167, 551 (2013).

    Article  CAS  PubMed  Google Scholar 

  43. J.-C. Soetens and P. A. Bopp, J. Phys. Chem. B 119, 8593 (2015).

    Article  CAS  PubMed  Google Scholar 

  44. R. Jedlovszky and J. Richardi, J. Chem. Phys. 110, 8019 (1999).

    Article  CAS  Google Scholar 

  45. P. G. Kusalik and I. M. Svishchev, Science (Washington, D.C., U. S.) 265, 1219 (1994).

    Article  CAS  Google Scholar 

  46. H. J. C. Berendsen, J. R. Grigera, and T. P. Straatsma, J. Phys. Chem. 91, 6269 (1987).

    Article  CAS  Google Scholar 

  47. W. L. Jorgensen, J. Am. Chem. Soc. 103, 335 (1981).

    Article  CAS  Google Scholar 

  48. M.-L. Tan, J. T. Fischer, A. Chandra, et al., Chem. Phys. Lett. 376, 646 (2003).

    Article  CAS  Google Scholar 

  49. P. Ren and J. W. Ponder, J. Phys. Chem. B 107, 5933 (2003).

    Article  CAS  Google Scholar 

  50. H. L. Pi, J. L. Aragones, C. Vega, et al., Mol. Phys. 107, 365 (2009).

    Article  CAS  Google Scholar 

  51. H. W. Horn, W. C. Swope, and J. W. Pitera, et al., J. Chem. Phys. 120, 9665 (2004).

    Article  CAS  PubMed  Google Scholar 

  52. A. Rahman, F. H. Stillinger, and H. L. Lemberg, J. Chem. Phys. 63, 5223 (1975).

    Article  CAS  Google Scholar 

  53. N. P. Malomuzh, V. N. Makhlaichuk, P. V. Makhlaichuk, and K. N. Pankratov, J. Struct. Chem. 54, 205 (2013).

    Article  CAS  Google Scholar 

  54. K. Okada, M. Yao, Y. Hiejima, H. Kohno, Y. Kojihara, J. Chem. Phys. 110, 3026 (1999).

    Article  CAS  Google Scholar 

  55. H. R. Pruppacher, J. Chem. Phys. 56, 101 (1972).

    Article  CAS  Google Scholar 

  56. K. Simpson and M. Karr, Phys. Rev. 17, 342 (1958).

    Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to G.G. Malenkov for his support, acquainting us with M.G. Kiselev’s works on methane, and discussing our results. We also thank L.A. Bulavin and Yu.I. Naberukhin for their many useful observations.

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Authors and Affiliations

  1. Mechnikov Odessa National University, 65082, Odessa, Ukraine

    V. Ya. Gotsul’skii, N. P. Malomuzh & V. E. Chechko

  2. Institute of Physics, Mechnikov Odessa National University, 65082, Odessa, Ukraine

    V. E. Chechko

Authors
  1. V. Ya. Gotsul’skii
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  2. N. P. Malomuzh
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  3. V. E. Chechko
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Correspondence to V. Ya. Gotsul’skii.

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Translated by O. Polyakov

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Gotsul’skii, V.Y., Malomuzh, N.P. & Chechko, V.E. Properties of Hydrogen Bonds in Water and Monohydric Alcohols. Russ. J. Phys. Chem. 92, 1516–1522 (2018). https://doi.org/10.1134/S0036024418080149

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  • DOI: https://doi.org/10.1134/S0036024418080149

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