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Kinetic characteristics of gas–liquid ozone reactions

  • Chemical Kinetics and Catalysis
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Abstract

An experimental chemical method for determining the kinetic characteristics (volumetric mass transfer coefficient and rate constant of a second-order reaction) of gas–liquid ozone reactions in a bubble column reactor is described. The calculation formulas are substantiated, and the ranges of values of the experimental factors that determine the method’s limits of applicability are found. The conditions under which the boundary-value problem of a gas–liquid ozone reaction of the second order can be reduced to a problem of a pseudo-first order reaction allowing an analytical solution are revealed.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. V. Levanov, O. Ya. Isaikina & V. V. Lunin

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    O. Ya. Isaikina & V. V. Lunin

Authors
  1. A. V. Levanov
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  2. O. Ya. Isaikina
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  3. V. V. Lunin
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Correspondence to A. V. Levanov.

Additional information

Original Russian Text © A.V. Levanov, O.Ya. Isaikina, V.V. Lunin, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 10, pp. 1641–1647.

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Levanov, A.V., Isaikina, O.Y. & Lunin, V.V. Kinetic characteristics of gas–liquid ozone reactions. Russ. J. Phys. Chem. 91, 1845–1850 (2017). https://doi.org/10.1134/S0036024417100235

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  • DOI: https://doi.org/10.1134/S0036024417100235

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