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Coefficient of ozone mass transfer during its interaction with an aqueous solution of formic acid in a bubble column reactor

  • Physical Chemistry of Solutions
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Abstract

A way of determining the coefficient of ozone mass transfer between the gas phase and liquid aqueous phase using a test compound (formic acid) is described. The values of ozone mass transfer coefficient (in aqueous solutions of 0.1–0.55 М HClO4 and 0–1 М НСООН, and in 0.75 М H2SO4, 0.125 М KHSO4, and 0–2 М НСООН) are determined along with the rate constants of the reaction of О3 with undissociated НСООН molecules and formate ions at 21 ± 1°С.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. V. Levanov, O. Ya. Isaikina, R. B. Gasanova & V. V. Lunin

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    O. Ya. Isaikina & V. V. Lunin

Authors
  1. A. V. Levanov
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  2. O. Ya. Isaikina
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  3. R. B. Gasanova
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  4. V. V. Lunin
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Correspondence to A. V. Levanov.

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Original Russian Text © A.V. Levanov, O.Ya. Isaikina, R.B. Gasanova, V.V. Lunin, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 8, pp. 1307–1312.

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Levanov, A.V., Isaikina, O.Y., Gasanova, R.B. et al. Coefficient of ozone mass transfer during its interaction with an aqueous solution of formic acid in a bubble column reactor. Russ. J. Phys. Chem. 91, 1427–1431 (2017). https://doi.org/10.1134/S0036024417080167

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  • DOI: https://doi.org/10.1134/S0036024417080167

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