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Partial molar volumes of isoniazid solutions in aqueous-ethanol mixtures at 298.15 K

  • Physical Chemistry of Solutions
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Abstract

Densities (ρ) of antitubercular drug isoniazid solutions in water, aqueous-ethanol (20–80 vol % EtOH) and in pure ethanol at 298.15 K with different molar concentrations (0.01–0.16 mol dm−3) were measured. Experimental density data were used to calculate apparent molar volumes (φ v ) of isoniazid in different media. The φ v data were fitted to Massons relation and partial molar volumes (φ 0 v ) of drug for infinitely dilute solution were determined for each solution. Experimental and derived properties were interpreted in terms of drug-solvent molecular interactions and structural fittings in studied systems.

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Authors and Affiliations

  1. School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, MS, India

    S. D. Deosarkar, R. T. Sawale & P. D. Tawde

  2. School of Pharmacy, Swami Ramanand Teerth Marathwada University, Nanded, MS, India

    T. M. Kalyankar

Authors
  1. S. D. Deosarkar
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  2. R. T. Sawale
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  3. P. D. Tawde
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  4. T. M. Kalyankar
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Correspondence to S. D. Deosarkar.

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Deosarkar, S.D., Sawale, R.T., Tawde, P.D. et al. Partial molar volumes of isoniazid solutions in aqueous-ethanol mixtures at 298.15 K. Russ. J. Phys. Chem. 89, 232–235 (2015). https://doi.org/10.1134/S0036024415020077

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  • DOI: https://doi.org/10.1134/S0036024415020077

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