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Problems in Imaging the Decomposition of Liquid and Solid Solutions in the Ag–Cu–Ni and Ag–Cu–Pb Systems

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

Three-dimensional (3D) computer models of Ag–Cu–Ni and Ag–Cu–Pb isobaric phase diagrams, designed based on 23 and 31 base points, respectively, assembled from 14 and 32 surfaces, 9 and 15 phase fields, respectively, and intended to digitize information on these diagrams, are used to verify the adequacy of interpretation of published isothermal and polythermal sections, both calculated and experimentally studied ones. The geometric features of the phase diagram regions that relate to liquid–liquid miscibility gaps and solid solution decomposition are refined in the 3D models. Mistakes arising from an incorrect imaging of the decay of copper–nickel solid solutions and from discrepancies in the values of the Ag–Cu–Pb ternary eutectic temperature are shown on polythermal sections.

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Funding

This study was fulfilled within the Government assignment to the Physical Materials Science Institute of Siberian Branch of the Russian Academy of Sciences for 2021–2023 (project No. 0270-2021-0002).

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Authors and Affiliations

  1. Physical Materials Science Institute, Siberian Branch, Russian Academy of Sciences, 670047, Ulan-Ude, Russia

    V. P. Vorob’eva, V. I. Lutsyk & M. D. Parfenova

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  1. V. P. Vorob’eva
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  2. V. I. Lutsyk
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  3. M. D. Parfenova
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Correspondence to V. P. Vorob’eva.

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Translated by O. Fedorova

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Vorob’eva, V.P., Lutsyk, V.I. & Parfenova, M.D. Problems in Imaging the Decomposition of Liquid and Solid Solutions in the Ag–Cu–Ni and Ag–Cu–Pb Systems. Russ. J. Inorg. Chem. 68, 69–77 (2023). https://doi.org/10.1134/S0036023622601921

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  • DOI: https://doi.org/10.1134/S0036023622601921

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