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Synthesis and Properties of Polymer Composites Based on Magnesium-Substituted Hydroxyapatite

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Magnesium-substituted hydroxyapatite Ca10 – xMgx(PO4)6(OH)2 (Mg-HA) has been synthesized from an aqueous solution of magnesium, calcium, diammonium phosphate, and ammonia salts in the presence of a polymer matrix of chitosan and chitin. The results of a study of the physicochemical properties of the synthesized composites are presented. The results of determining the composition, morphological, thermal, and bioactive characteristics of the obtained composites are presented. It has been found that all samples have a similar phase composition and morphology, which is characteristic of magnesium-substituted hydroxyapatite. It has been shown that the crystallite size of composites with chitosan decreases with an increase in the polymer content, while for composites with chitin there is an inverse relationship. It has been found that upon dissolution of samples in an isotonic solution, the rates of formation of calcium ions in the liquid phase increase with the content of chitosan and chitin in the synthesized composites.

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Authors and Affiliations

  1. Omsk State University, 644077, Omsk, Russia

    A. I. Nikitina & O. A. Golovanova

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  1. A. I. Nikitina
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  2. O. A. Golovanova
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Correspondence to O. A. Golovanova.

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Translated by V. Avdeeva

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Nikitina, A.I., Golovanova, O.A. Synthesis and Properties of Polymer Composites Based on Magnesium-Substituted Hydroxyapatite. Russ. J. Inorg. Chem. 67, 131–138 (2022). https://doi.org/10.1134/S0036023622020115

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  • DOI: https://doi.org/10.1134/S0036023622020115

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