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Mononuclear Zn(II) 3,5-Diiodosalicylate Complex with 3-Chloropyridine: Synthesis and Features of Non-Covalent Interactions in the Solid State

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Abstract

The reaction of zinc(II) nitrate with 3,5-diiodosalicylic acid in the presence of 3-chloropyridine gave the heteroligand complex [(3-ClPy)2ZnDISA2] (1), which was studied by X-ray diffraction. The crystal structure of 1 includes non-covalent I···O interactions (halogen bonds), the energies of which were estimated by quantum chemical calculations.

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Funding

The study was supported by the Russian Foundation for Basic Research (project no. 20-33-70010 “Stabilnost”).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. A. Bondarenko & S. A. Adonin

  2. Saint Petersburg State University, 199034, St. Petersburg, Russia

    A. S. Novikov

  3. South Ural State University, 454080, Chelyabinsk, Russia

    S. A. Adonin

Authors
  1. M. A. Bondarenko
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  2. A. S. Novikov
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  3. S. A. Adonin
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Correspondence to S. A. Adonin.

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Translated by Z. Svitanko

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Bondarenko, M.A., Novikov, A.S. & Adonin, S.A. Mononuclear Zn(II) 3,5-Diiodosalicylate Complex with 3-Chloropyridine: Synthesis and Features of Non-Covalent Interactions in the Solid State. Russ. J. Inorg. Chem. 66, 814–819 (2021). https://doi.org/10.1134/S0036023621060061

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  • DOI: https://doi.org/10.1134/S0036023621060061

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