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Synthesis of Monetite from Calcium Hydroxyapatite and Monocalcium Phosphate Monohydrate under Mechanical Activation Conditions

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Abstract

A powder of monetite СаНРО4 with a particle size of 100–300 nm was synthesized from monocalcium phosphate monohydrate Ca(H2PO4)2 ⋅ H2O and calcium hydroxyapatite Ca10(PO4)6(OH)2 in an acetone medium upon mechanical activation in a planetary mill. According to X-ray powder diffraction data, after heat treatment in the range 900–1100°С, the phase composition of the samples was represented by calcium β-pyrophosphate β-Ca2P2O7. The synthesized powder can be used for producing resorbable calcium phosphate ceramic materials.

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ACKNOWLEDGMENTS

The work was accomplished using equipment purchased at the expense of the Moscow State University Development Program.

Funding

The study was supported by the Russian Foundation for Basic Research (project nos. 16-08-01172, 18-29-11079, and 18-53-00034).

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Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    T. V. Safronova, I. S. Sadilov, K. V. Chaikun, T. B. Shatalova & Ya. Yu. Filippov

Authors
  1. T. V. Safronova
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  2. I. S. Sadilov
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  3. K. V. Chaikun
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  4. T. B. Shatalova
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  5. Ya. Yu. Filippov
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Contributions

T.V. Safronova formulated a goal, designed the experiment, and wrote the paper; I.S. Sadilov and K.V. Chaikun synthesized samples and interpreted the XRD data; T.B. Shatalova performed thermal analysis (TA, MS) and interpreted the results; Ya.Yu. Filippov conducted electron microscopic studies of the synthesized powders and samples of ceramic materials. All authors participated in the discussion of the results.

Corresponding author

Correspondence to T. V. Safronova.

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The authors declare no conflict of interests.

Additional information

Translated by G. Kirakosyan

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Safronova, T.V., Sadilov, I.S., Chaikun, K.V. et al. Synthesis of Monetite from Calcium Hydroxyapatite and Monocalcium Phosphate Monohydrate under Mechanical Activation Conditions. Russ. J. Inorg. Chem. 64, 1088–1094 (2019). https://doi.org/10.1134/S0036023619090171

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  • DOI: https://doi.org/10.1134/S0036023619090171

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