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Synthesis and Luminescence of Europium-Containing Compositions Based on Yttrium Oxide and Oxyfluorides

  • Synthesis and Properties of Inorganic Compounds
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Abstract

By heating the products isolated from an ethyl acetate medium, luminescent europium-containing compositions based on yttrium oxyfluorides and oxide have been synthesized. The concentration of Eu3+ ions in the compositions was from 0.10 to 10 at % of the yttrium content. It has been shown that the (EuхY1–х)nOn–1Fn + 2, (EuхY1–х)OF, (EuхY1–х)2O3, and (EuхY1–х)5O4F7 phases are formed during the synthesis. The luminescence of the compositions is related to the 5D0 → 7Fj electron transitions of Eu3+ ions. It depends on the synthesis conditions, the type of matrix, the position of the Eu3+ ions in the crystal lattice, the excitation wavelength, and other factors.

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Authors and Affiliations

  1. Altai State University, Barnaul, 656049, Russia

    V. P. Smagin & A. P. Khudykov

  2. Tomsk State University, Tomsk, 634050, Russia

    N. S. Eremina

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  1. V. P. Smagin
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  2. A. P. Khudykov
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  3. N. S. Eremina
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Correspondence to V. P. Smagin.

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Original Russian Text © V.P. Smagin, A.P. Khudykov, N.S. Eremina, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 11, pp. 1404–1413.

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Smagin, V.P., Khudykov, A.P. & Eremina, N.S. Synthesis and Luminescence of Europium-Containing Compositions Based on Yttrium Oxide and Oxyfluorides. Russ. J. Inorg. Chem. 63, 1427–1435 (2018). https://doi.org/10.1134/S0036023618110190

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  • DOI: https://doi.org/10.1134/S0036023618110190

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