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Glass Formation in the Al2(SO4)3–(CH3)2SO–H2O System

  • Physicochemical Analysis of Inorganic Systems
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Abstract

The glass formation in the Al2(SO4)3–(CH3)2SO–H2O system was found for the first time. The competitive ability of ligands, dimethyl sulfoxide and water (which are strong donors), for entering the first coordination sphere of aluminum is considered. The possibility of mixed coordination of (CH3)2SO (via sulfur and oxygen atoms) in the first coordination sphere of aluminum with retention of the glass-forming ability of the sample was suggested on the basis of IR spectral study.

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References

  1. I. A. Kirilenko, Wate–Electrolyte Glass-Forming Systems (Krasand, Moscow, 2016) [in Russian].

    Google Scholar 

  2. A. A. Kostyaev, A. K. Martusevich, and A. A. Andreev, Nauchn. Obozrenie. Med. Nauki, No. 6, 54 (2016).

    Google Scholar 

  3. Yu. N. Kukushkin, Sorosovskii Obrazovat. Zh., No. 9, 54 (1997).

    Google Scholar 

  4. V. P. Belousov and M. Yu. Panov, Thermodynamics of Aqueous Solutions of Nonelectrolytes (Khimiya, Leningrad, 1983) [in Russian].

    Google Scholar 

  5. D. H. Rasmuussen and A. P. Mackenzie, Nature 220, 1315 (1968).

    Article  Google Scholar 

  6. V. P. Belousov and A. G. Morachevskii, Heats of Mixing for Liquids (Khimiya, Leningrad, 1970) [in Russian].

    Google Scholar 

  7. G. V. Rashkovskii, Z. A. Ovchinnikova, and N. V. Penkina, Zh. Prikl. Khim. 55, 1858 (1982).

    Google Scholar 

  8. U. Koatze, M. Brai, F.-D. Sholle, and R. Pottel, J. Mol. Liq. 44, 197 (1990).

    Article  Google Scholar 

  9. M. N. Rodnikova, Yu. A. Zakharova, I. A. Solonina, and D. A. Sirotin, Zh. Fiz. Khim. 86, 993 (2012).

    Google Scholar 

  10. I. A. Kirilenko, Russ. J. Inorg. Chem. 62, 1819 (2017). doi 10.1134/S0036023617140042

    Article  CAS  Google Scholar 

  11. T. Fischer and B. Eisenmann, Z. Kristallogr. 211, 475 (1996).

    CAS  Google Scholar 

  12. V. F. Kablov, N. U. Bykadorov, O. K. Zhokhova, et al., Vestn. Kazansk. Tekhnol. Univ. 16 (1), 61 (2013).

    CAS  Google Scholar 

  13. C. A. Angell and E. J. Sare, J. Chem. Phys. 52, 1058 (1970).

    Article  CAS  Google Scholar 

  14. G. V. Yukhnevich and E. G. Kokhanov, Zh. Prikl. Spectrosk. 39, 617 (1983).

    CAS  Google Scholar 

  15. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Interscience, New York, 1986).

    Google Scholar 

  16. F. A. Cotton, R. Francis, and W. D. Horrocks, J. Phys. Chem. 64, 1534 (1960).

    Article  CAS  Google Scholar 

  17. B. B. Wayland and R. F. Shramm, Inorg. Chem. 8, 971 (1969).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    I. A. Kirilenko

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 199071, Russia

    L. I. Demina

Authors
  1. I. A. Kirilenko
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  2. L. I. Demina
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Correspondence to I. A. Kirilenko.

Additional information

Original Russian Text © I.A. Kirilenko, L.I. Demina, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 10, pp. 1349–1352.

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Kirilenko, I.A., Demina, L.I. Glass Formation in the Al2(SO4)3–(CH3)2SO–H2O System. Russ. J. Inorg. Chem. 63, 1368–1371 (2018). https://doi.org/10.1134/S0036023618100108

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  • DOI: https://doi.org/10.1134/S0036023618100108

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