Abstract
The textural and structural characteristics of phosphorites from the Polpinsky deposit have been determined. These raw materials are shown to be of siliceous polymineral type and consist mostly of α-quartz, hydroxycarbonate apatite, montmorillonite, and bonschtedtite. The modification dynamics of chemical composition and the textural characteristics (specific surface, pore volume, and pore diameter) of the solid upon the acid decomposition of a phosphorite sample from Polpinsky deposit have been studied. The α-quartz in phosphorites is shown to not experience crystal-structural alterations upon acid decomposition; its pore size does not inhibit the extraction of acid-soluble components, including calcium and phosphorus, from the bulk.
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S. V. Dobrydnev, V. S. Beskov, I. A. Pochitalkina, and V. V. Bogach, Teor. Osnovy Khim. Tekhnol. 35 (4), 310 (2001).
S. V. Dobrydnev, V. V. Bogatch, I. A. Pochitalkina, and V. S. Beskov, Hem. Ind. 54 (7–8), 319 (2000).
I. A. Petropavlovskii, I. A. Pochitalkina, V. G. Kiselev, et al., Khim. Prom. Segodnya, No. 4, 5 (2012).
I. A. Pochitalkina, I. A. Petropavlovskii, I. A. Filenko, and D. F. Kondakov, Khim. Tekhnol. 16 (3), 136 (2015).
The Technology of Phosphorus and Complex Fertilizers, Ed. by S. D. Evenchik and A. A. Brodskii (Khimiya, Moscow, 1987) [in Russian].
M. E. Pozin, The Technology of Mineral Salts (Fertilizers, Pesticides, Industrial Salts, Acid Oxides) (Khimiya, Leningrad, 1558), Part II [in Russian].
A. Yu. Tsivadze, A. I. Rusanov, A. A. Fomkin, et al., The Physical Chemistry of Adsorption Phenomena (Granitsa, Moscow, 2011) [in Russian].
L. V. Adamova and A. P. Safronov, The Sorption Method to Study Pore Structure in Nanomaterials and Specific Surface in Nanosized Systems. Tutorial (Yekaterinburg, 2008) [in Russian].
The Chemical Encyclopedia (Sovetskaya Entsiklopediya, Moscow, 1990), Vol. 2 [in Russian].
R. K. Iler, The Chemistry of Silica (Wiley, 1979; Moscow, 1982).
G. A. Yurgenson, Typomorphism and Mineralization of Quartz Veins (Nedra, Moscow, 1984) [in Russian].
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Original Russian Text © I.A. Pochitalkina, D.F. Kondakov, O.A. Artamonova, O.V. Vinokurova, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 11, pp. 1503–1506.
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Pochitalkina, I.A., Kondakov, D.F., Artamonova, O.A. et al. Textural and structural characteristics of phosphorites from the Polpinsky deposit. Russ. J. Inorg. Chem. 62, 1495–1498 (2017). https://doi.org/10.1134/S0036023617110146
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DOI: https://doi.org/10.1134/S0036023617110146