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Cobalt(III) tetrabenzoporphyrin: Synthesis, spectral and coordination properties

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Abstract

Comparison of tetrabenzoporphyrin complexation reactions and transmetalation of cadmium(II) tetrabenzoporphyrinate with cobalt(II) acetate and chloride in dimethylformamide (DMF) has been carried out Cobalt(III) tetrabenzoporphyrinate has been prepared and identified. Acido ligands displacement in Co(III) tetrabenzoporphyrinate by pyridine, imidazole, and quinuclidine molecules has been studied.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    G. M. Mamardashvili, N. V. Chizhova, E. Yu. Kaigorodova & N. Zh. Mamardashvili

Authors
  1. G. M. Mamardashvili
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  2. N. V. Chizhova
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  3. E. Yu. Kaigorodova
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  4. N. Zh. Mamardashvili
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Correspondence to N. V. Chizhova.

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Original Russian Text © G.M. Mamardashvili, N.V. Chizhova, E.Yu. Kaigorodova, N.Zh. Mamardashvili, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 3, pp. 296–304.

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Mamardashvili, G.M., Chizhova, N.V., Kaigorodova, E.Y. et al. Cobalt(III) tetrabenzoporphyrin: Synthesis, spectral and coordination properties. Russ. J. Inorg. Chem. 62, 301–308 (2017). https://doi.org/10.1134/S0036023617030123

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  • DOI: https://doi.org/10.1134/S0036023617030123

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