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Effect of polyoxomolybdate nanocluster doping on the dielectric characteristics of polyvinyl alcohol nanocomposite films

  • Physical Methods of Investigation
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Abstract

Electrophysical parameters of polyvinyl alcohol (PVA) films comprising nanocluster molybdenum-based polyoxometalates (POMs), namely electrical conductivity, dielectric loss tangent, and dielectric permittivity, have been studied. Frequency and concentration curves have been plotted for these properties, which characterize the relaxation parameters of polymeric macromolecules and interactions of the polymer with spheroidal Keplerate POMs (Mo132 and Mo72Fe30) and toroidal POMs (Mo138).

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References

  1. Yu. A. Mikhailin, Special Polymeric Composites (Plast-INFO, Moscow, 2009) [in Russian].

    Google Scholar 

  2. S. Yu, P. Hing, and X. Hu, J. Appl. Phys. 88, 398 (2000).

    Article  CAS  Google Scholar 

  3. C. U. Devi, A. K. Sharma, and V. V. R. N. Rao, Mater. Lett. 56, 16 (2002).

    Article  Google Scholar 

  4. O. Gh. Abdullah and D. S. Muhammad, Int. J. Mater. Sci. 5, 537 (2010).

    Google Scholar 

  5. A. K. Lyashchenko, A. S. Lileev, T. A. Palitskaya, and A. A. Ostroushko, Russ. J. Phys. Chem. 75, 202 (2001).

    Google Scholar 

  6. A. S. Lileev, A. K. Lyashchenko, and A. A. Ostroushko, Russ. J. Inorg. Chem. 48, 1262 (2003).

    Google Scholar 

  7. A. S. Lileev, A. K. Lyashchenko, A. A. Ostroushko, and M. Yu. Sennikov, Russ. J. Inorg. Chem. 51, 656 (2006).

    Article  Google Scholar 

  8. A. A. Ostroushko, M. Yu. Sennikov and E. L. Gerasimova, Russ. J. Inorg. Chem. 50, 428 (2005).

    Google Scholar 

  9. A. A. Ostroushko and M. Yu. Sennikov, Russ. J. Inorg. Chem. 54, 115 (2009).

    Article  Google Scholar 

  10. A. Müller, E. Krickemeyer, H. Bögge, et al., Angew. Chem., Int. Ed. Eng. 37, 3360 (1998).

    Google Scholar 

  11. A. Müller, R. Maiti, M. Schmidtmann, et al., Chem. Commun., 2126 (2001).

    Google Scholar 

  12. A. Müller, S. Sarkar, S. Q. N. Shah, et al., Angew. Chem. Int. Ed. Eng. 38, 3238 (1999).

    Article  Google Scholar 

  13. S. Kurosaki and T. Furumaya, J. Polym. Sci. 43, 137 (1960).

    Article  CAS  Google Scholar 

  14. S. De, A. De, A. Das, and S. K. De, Mater. Chem. Phys. 91, 477 (2005).

    Article  CAS  Google Scholar 

  15. T. Liu, B. Imber, E. Diemann, et al., J. Am. Chem. Soc. 128, 15914 (2006).

    Article  CAS  Google Scholar 

  16. A. A. Ostroushko, M. Yu. Sennikov, and M. O. Tonkushina, Russ. J. Inorg. Chem. 54, 611 (2009).

    Article  Google Scholar 

  17. A. A. Ostroushko, M. O. Tonkushina, A. P. Safronov, and A. E. Udilov, Russ. J. Inorg. Chem. 55, 1260 (2010).

    Article  CAS  Google Scholar 

  18. M. H. Harun, E. Saion, A. Kassim, et al., Malaysian Polym. J. 13 (2), 24 (2008).

    Google Scholar 

  19. H. W. Wang, K. C. Chang, H. C. Chu, et al., J. Appl. Polym. Sci. 92, 2402 (2004).

    Article  CAS  Google Scholar 

  20. H. W. Wang, C. F. Shieh, K. C. Chang, and H. C. Chu, J. Appl. Polym. Sci. 97, 2175 (2005).

    Article  CAS  Google Scholar 

  21. A. A. Ostroushko and K. V. Grzhegorzhevskii, Russ. J. Phys. Chem. 88, 1008 (2014).

    Article  CAS  Google Scholar 

  22. R. J. Sengwa and S. Choudhary, Expr. Polym. Lett. 4, 559 (2010).

    Article  CAS  Google Scholar 

  23. A. Roy, A. Parveen, R. Deshpande, et al., J. Nanopart. Res., No. 15, 1337 (2013).

    Article  Google Scholar 

  24. A. A. Ostroushko, Russ. J. Inorg. Chem. 60, 387 (2015).

    Article  CAS  Google Scholar 

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Correspondence to M. O. Tonkushina.

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Original Russian Text © M.O. Tonkushina, A.S. Kraev, O.V. Alekseeva, A.A. Ostroushko, A.V. Agafonov, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 4, pp. 498–503.

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Tonkushina, M.O., Kraev, A.S., Alekseeva, O.V. et al. Effect of polyoxomolybdate nanocluster doping on the dielectric characteristics of polyvinyl alcohol nanocomposite films. Russ. J. Inorg. Chem. 61, 477–481 (2016). https://doi.org/10.1134/S0036023616040215

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  • DOI: https://doi.org/10.1134/S0036023616040215

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