Abstract
The preparation of nanosized Group IV metal diborides by reacting powdery titanium, zirconium, and hafnium with fine-grained boron in Na2B4O7 ionic melts in the temperature range 600–850°C has been studied. Nanosized titanium, zirconium, and hafnium diborides are formed at temperatures of at least 750°C.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
T. I. Serebryakova, V. A. Neronov, and P. D. Peshev, High-Temperature Borides (Metallurgiya, Chelyabinsk, 1991) [in Russian].
R. A. Andrievskii, Fundamentals of Nanostructural Materials Science. Potentials and Topics (BINOM. Laboratoriya znanii, Moscow, 2012), p. 252 [in Russian].
S. Carenco, D. Portehault, C. Boissiere, et al., Chem. Rev. 113, 7981 (2013).
J. A. Jensen, J. E. Gozum, D. M. Pollina, and G. S. Girolami, J. Am. Chem. Soc. 110, 1643 (1988).
G. W. Rice and R. L. Woodin, J. Am. Chem. Soc. 71, 181 (1988).
A. L. Wayda, L. F. Schneemeyer, and R. L. Opila, Appl. Phys. Lett. 53, 361 (1988).
R. A. Andrievski, S. E. Kravchenko, and S. P. Shilkin, Jpn. J. Appl. Phys. 10, 198 (1994).
R. A. Andrievskii, S. E. Kravchenko, and S. P. Shilkin, Neorg. Mater. 31, 1048 (1995).
S. E. Kravchenko, V. I. Torbov, and S. P. Shilkin, Russ. J. Inorg. Chem. 56, 506 (2011).
Y. L. Gu, Y. T. Qian, L. Y. Chen, and F. Zhou, J. Alloys Compd. 352, 325 (2003).
J. W. Kim, J. H. Shim, J. P. Ahn, et al., Mater. Lett. 62, 2461 (2008).
L. Chen, Y. Qian, L. Chi, et al., Mater. Res. Bull. 39, 609 (2004).
S. E. Kravchenko, V. I. Torbov, and S. P. Shilkin, Neorg. Mater. 46, 691 (2010).
L. Chen, Y. Gu, Y. Qian, et al., Solid State Commun. 130, 231 (2004).
S. Venugopal, A. Paul, B. Vaidhyanathan, et al., Eur. Ceram. Soc. 34, 1471 (2014).
H. Wang, S.-H. Lee, and H.-D. Kim, J. Am. Ceram. Soc. 95, 1493 (2012).
L. Chen, Y. Gu, L. Chi, et al., J. Alloys Compd. 368 (1–2), 353 (2004).
D. Portehault, S. Devi, P. Beaunier, et al., Angew. Chem. 123, 3320 (2011).
L. S. Volkova, S. E. Kravchenko, I. I. Korobov, et al., Neorg. Mater. 49, 1173 (2013).
L. S. Volkova, A. G. Burlakova, S. E. Kravchenko, and S. P. Shilkin, Neorg. Mater. 49, 1285 (2013).
L. S. Volkova, Yu. M. Shul’ga, and S. P. Shilkin, Zh. Obshch. Khim. 82, 709 (2012).
E. G. Avakumov, Mechanical Activation of Chemical Processes (Nauka, SO RAN, Novosibirsk, 1989) [in Russian].
O. L. Khasanov, I. A. Shulepov, V. V. Polisadova, et al., Izv. Tomsk. Politekhn. Univ. 318 (2), 131 (2011).
S. A. Kuznetsov, A. L. Glagolevskaya, A. T. Belyaevskii, et al., Zh. Prikl. Khim. 70, 1646 (1997).
I. V. Zarutskii, V. V. Malyshev, and V. I. Shapoval, Zh. Prikl. Khim. 70, 1475 (1997).
V. N. Fokin, S. P. Shilkin, E. E. Fokina, and N. G. Mozgina, Zh. Obshch. Khim. 67, 705 (1997).
Experimental Methods in Adsorption and Molecular Chromatography, Ed. by A. V. Kiselev and V. P. Dreving (Moscow Univ. Press, Moscow, 1973) [in Russian].
Phase Diagrams of Binary Metal Systems: A Handbook, Ed. by N. P. Lyakishev (Mashinostroenie, Moscow, 1996) [in Russian].
V. G. Aleshin, A. N. Kharlamov, and M. G. Chudinov, Izv. Akad. Nauk SSSR, Neorg. Mater. 15, 672 (1979).
N. G. Ilyushchenko, A. I. Anfinogenov, and N. I. Shurov, Interaction of Metals in Ionic Melts (Nauka, Moscow, 1991) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.E. Kravchenko, A.G. Burlakova, I.I. Korobov, G.V. Kalinnikov, I.A. Domashnev, S.P. Shilkin, R.A. Andrievskii, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 4, pp. 450–454.
Rights and permissions
About this article
Cite this article
Kravchenko, S.E., Burlakova, A.G., Korobov, I.I. et al. Synthesis of nanosized group IV borides in ionic melts of anhydrous sodium tetraborate. Russ. J. Inorg. Chem. 61, 429–433 (2016). https://doi.org/10.1134/S0036023616040112
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023616040112