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Formation of Niobium Diboride Nanoparticles by the Reaction of Niobium Pentachloride with Sodium Borohydride in Ionic Melts of Alkali Metal Halides

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Abstract

Near-spherical niobium diboride nanoparticles with an average diameter of ~17 nm, crystallizing in the hexagonal system and belonging to the space group P6/mmm, were obtained by reacting NbCl5 with NaBH4 in ionic melts of alkali metal halides at 1073 K under an argon pressure of 4 MPa for 15 h in an autoclave.

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Funding

This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the State Assignment (state registration no. АААА-А19-119061890019-5) using the equipment of the Analytical Center for Collective Use, Institute of Problems of Chemical Physics, Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. A. Vinokurov, N. N. Dremova, S. E. Nadkhina, A. V. Ivanov & S. P. Shilkin

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  1. A. A. Vinokurov
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  2. N. N. Dremova
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  3. S. E. Nadkhina
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  4. A. V. Ivanov
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  5. S. P. Shilkin
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Correspondence to S. P. Shilkin.

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Vinokurov, A.A., Dremova, N.N., Nadkhina, S.E. et al. Formation of Niobium Diboride Nanoparticles by the Reaction of Niobium Pentachloride with Sodium Borohydride in Ionic Melts of Alkali Metal Halides. Russ J Gen Chem 92, 272–275 (2022). https://doi.org/10.1134/S1070363222020189

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