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Gold(I) complexes in sulfite-thiosulfate aqueous solutions

  • Physical Chemistry of Solutions
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Abstract

Stepwise substitution equilibria of ligands in the system of gold(I) sulfite-thiosulfate complexes in an aqueous solutions, namely Au(SO3)2 3- + S2O3 2-= Au(SO3)(S2O3)3- + (logß1 = -0.35 ± 0.15) and Au(SO3)2 3- + S2O3 2- = Au(S2O3)2 3-(S2O3)3-(logß2 = -0.99 ± 0.05), were studied at 25°C and I = 1 M (NaCl). The UV spectra of these species were recorded. The method of taking into account the systematic effect of sulfite oxidation by air oxygen with the use of independent series of measurements under conditions close to the conditions of main experiments was tested.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    I. V. Mironov & V. Yu. Kharlamova

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    I. V. Mironov & V. Yu. Kharlamova

Authors
  1. I. V. Mironov
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  2. V. Yu. Kharlamova
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Correspondence to I. V. Mironov.

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Original Russian Text © I.V. Mironov, V.Yu. Kharlamova, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 1, pp. 129–134.

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Mironov, I.V., Kharlamova, V.Y. Gold(I) complexes in sulfite-thiosulfate aqueous solutions. Russ. J. Inorg. Chem. 61, 123–128 (2016). https://doi.org/10.1134/S0036023616010174

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