Skip to main content
Log in

Controlled synthesis of low-hydrated niobium and tantalum hydroxides: Phase composition and bulk properties of their thermolysis products

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Physicochemical properties of low-hydrated niobium and tantalum hydroxides MO0.5–2.0(OH)4−1 · mH2O (M = Nb or Ta), which are precursors for the synthesis of niobium and tantalum based oxide phases, were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. S. Korotkov and V. V. Atuchin, J. Solid State Chem. 179, 1177 (2006).

    Article  CAS  Google Scholar 

  2. G. Zhu, M. Bahoura, M. A. Noginov, et al., Laser Phys. 17, 818 (2007).

    Article  CAS  Google Scholar 

  3. P. Yu, Y. Tang, and H. Luo, J. Electroceram. 24(1), 1 (2010).

    Article  CAS  Google Scholar 

  4. Y. Yamashita and Y. Hosono, in Piezoelectricity: Evolution and Future of the Technology, Ed. by W. Heywang, K. Lubitz, and W. Wersing (Springer, Berlin, 2008), Vol. 114, pp. 223–244.

    Article  CAS  Google Scholar 

  5. K. Tanabe, Catal. Today 78, 65 (2003).

    Article  CAS  Google Scholar 

  6. E. E. Nikishina, D. V. Drobot, and E. N. Lebedeva, The Chemistry and Technology of Niobium and Tantalum. Simple and Complex Oxides (Izd-vo MITKhT, Moscow, 2013) [in Russian].

    Google Scholar 

  7. Ion Exchanges in Chemical Technology, Ed. by B. P. Nikol’skii and P. G. Romankov (Khimiya, Leningrad, 1982) [in Russian].

    Google Scholar 

  8. V. V. Vol’khin, Yu. V. Egorov, F. A. Belinskaya, et al. in Ion Exchange, Ed. by M. M. Senyavin (Nauka, Moscow, 1981), p. 25 [in Russian].

  9. Ju. V. Egorov and V. D. Puzako, Radiochem. 13, 747 (1971).

    CAS  Google Scholar 

  10. V. A. Klimova, Basic Organic Microanalysis (Mir, Moscow, 1975) [in Russian].

    Google Scholar 

  11. M. P. Shaskol’skaya, Crystallography (Vysshaya Shkola, Moscow, 1984) [in Russian].

    Google Scholar 

  12. S. Brunauer, P. H. Emmett, and E. Teller, J. Am. Chem. Soc. 60, 309 (1938).

    Article  CAS  Google Scholar 

  13. R. V. Zagrafskaja, A. P. Karnauchov, and V. B. Fenelonov, Kinet. Catal. 17, 730 (1976).

    Google Scholar 

  14. A. A. Fomkin and A. V. Shkolin, Dokl. Phys. Chem. 423, 292 (2008).

    Article  CAS  Google Scholar 

  15. A. A. Fomkin, Protect. Met. Phys. Chem. Surf. 45(2), 121 (2009).

    Article  CAS  Google Scholar 

  16. A. V. Zhilkina, A. A. Gordienko, N. A. Prokudina, et al., Russ. J. Phys. Chem. A 87, 674 (2013).

    Article  CAS  Google Scholar 

  17. M. M. Dubinin, in Topics of Physical Adsorption Theory, Ed. by M. M. Dubinin and V. V. Serpinskii (Nauka, Moscow, 1970), p. 251 [in Russian].

  18. ISO 15901-2:2006. Pore Size Distribution and Porosity of Solid Materials by Mercury Porosimetry and Gas Adsorption, Part 2: Analysis of Mesopores and Macropores by Gas Adsorption (ISO, Geneva, 2007).

    Google Scholar 

  19. ISO 15901-3:2007. Pore Size Distribution and Porosity of Solid Materials by Mercury Porosimetry and Gas Adsorption, Part 3: Analysis of Micropores by Gas Adsorption (ISO, Geneva, 2007).

    Google Scholar 

  20. S. Gregg and K. Sing, Adsorption, Surface Area and Porosity (Academic Press, New York, 1982).

    Google Scholar 

  21. V. A. Dzis’ko, A. P. Karnaukhov, and D. V. Tarasova, Physicochemical Fundamentals for the Synthesis of Oxide Catalysts (Nauka, Novosibirsk, 1978) [in Russian].

    Google Scholar 

  22. ISO 8130-3:1992. Coating Powders. Part 3: Determination of Density by Liquid Displacement Pycnometer (ISO, Geneva, 1992).

  23. D. V. Drobot, E. N. Lebedeva, S. S. Korovin, and E. E. Nikishina, Patent RU 21555160, Byull. Izobret., No. 7 (2000).

    Google Scholar 

  24. E. E. Nikishina, E. N. Lebedeva, and D. V. Drobot, Patent RU 2314258, Byull. Izobret., No. 1 (2008).

    Google Scholar 

  25. K. S. W. Sing, D. H. Everett, R. A. W. Haul, et al., Pure Appl. Chem. 57, 603 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. E. Nikishina.

Additional information

Original Russian Text © E.E. Nikishina, E.N. Lebedeva, N.A. Prokudina, D.V. Drobot, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 4, pp. 487–465.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nikishina, E.E., Lebedeva, E.N., Prokudina, N.A. et al. Controlled synthesis of low-hydrated niobium and tantalum hydroxides: Phase composition and bulk properties of their thermolysis products. Russ. J. Inorg. Chem. 60, 428–436 (2015). https://doi.org/10.1134/S0036023615040178

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023615040178

Keywords

Navigation