Skip to main content
SpringerLink
Log in

Interaction between Co2P4O12 and alkali metal nitrate (chloride) melts

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Reactions between Co2P4O12 and alkali metal nitrate (chloride) melts was studied in the temperature range 350–400°C (800–850°C) at different phosphate/melt ratios. The effect of the nature of an alkali metal and the ratio between the components in the Co2P4O12-MINO3 (MICl) system on composition of the reaction products was established. The resulting crystalline phases (NaCoPO4, Na4Co3(PO4)2P2O7, Na9Co3(PO4)5 and KCoPO4) were studied by X-ray powder diffraction, IR and electron spectroscopy, and scanning electron microscopy. The features of transformation of the Co2P4O12 framework into KCoPO4 under the effect of excessive alkali metal ions in the melt are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Feng, X. Bu, S. H. Tolbert, and G. D. Stucky, J. Am. Chem. Soc. 119, 2497 (1997).

    Article  CAS  Google Scholar 

  2. Y. Zhang, C. Zhao, X. Dai, et al., J. Power Sources 243, 908 (2013).

    Article  CAS  Google Scholar 

  3. M. Nose, H. Nakayama, K. Nobuhara, et al., J. Power Sources 234, 175 (2013).

    Article  CAS  Google Scholar 

  4. The Atlas of Infrared Spectra of Phosphates, Ed. by I. V. Tatanaev (Nauka, Moscow, 1990) [in Russian].

    Google Scholar 

  5. A. Olbertz, D. Stachel, I. Svoboda, and H. Fuess, Z. Krist.-New Cryst. Struct. 213, 241 (1998).

    CAS  Google Scholar 

  6. B. Boonchom, J. Optoelectron. Biomed. Mater. 1(1), 103 (2009).

    Google Scholar 

  7. V. Ramakrishnan and G. Aruldhas, Infrared Phys. 25, 665 (1985).

    Article  CAS  Google Scholar 

  8. A. Levér, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, 1984).

    Google Scholar 

  9. M. Lujan, F. Kubel, and H. Schmid, Z. Naturforsch. 49 1256, (1994).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

    N. Yu. Strutynska, O. V. Livitska, I. V. Zatovsky & N. S. Slobodyanik

Authors
  1. N. Yu. Strutynska
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Livitska
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Zatovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. S. Slobodyanik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. Yu. Strutynska.

Additional information

Original Russian Text © N.Yu. Strutynska, O.V. Livitska, I.V. Zatovsky, N.S. Slobodyanik, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 9, pp. 1148–1152.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Strutynska, N.Y., Livitska, O.V., Zatovsky, I.V. et al. Interaction between Co2P4O12 and alkali metal nitrate (chloride) melts. Russ. J. Inorg. Chem. 59, 918–921 (2014). https://doi.org/10.1134/S0036023614090241

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023614090241

Keywords

Search

Navigation