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Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether

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Abstract

A reaction between palladium(II) acetate and aqueous cerium(III) acetate in acetic acid with subsequent boiling in benzene with excess pivalic acid is found to yield the complex Pd(μ-OOCBut)4Ce(OOCBut)(HOOCBut)3 (1). The liquid-phase thermolysis of complex 1 in dibenzyl ether (190°C) leads to the formation of the tetranuclear complex [Pd(μ-OOCBut)4Ce(HOOCBut)]2(μ-OOCBut)(μ-OH2) (2). The structure of the synthesized complexes is established by X-ray diffraction.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    S. E. Nefedov, M. A. Uvarova, M. A. Golubnichaya, N. Yu. Kozitsyna, M. N. Vargaftik & I. I. Moiseev

  2. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfskaya doroga 86, Odessa, 65080, Ukraine

    D. G. Chikhichin & L. G. Kamalov

Authors
  1. S. E. Nefedov
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  2. M. A. Uvarova
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  3. M. A. Golubnichaya
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  4. N. Yu. Kozitsyna
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  5. D. G. Chikhichin
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  6. L. G. Kamalov
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  7. M. N. Vargaftik
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  8. I. I. Moiseev
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Corresponding author

Correspondence to S. E. Nefedov.

Additional information

Original Russian Text © S.E. Nefedov, M.A. Uvarova, M.A. Golubnichaya, N.Yu. Kozitsyna, D.G. Chikhichin, L.G. Kamalov, M.N. Vargaftik, I.I. Moiseev, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 7, pp. 947–951.

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Nefedov, S.E., Uvarova, M.A., Golubnichaya, M.A. et al. Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether. Russ. J. Inorg. Chem. 59, 733–737 (2014). https://doi.org/10.1134/S0036023614070171

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  • DOI: https://doi.org/10.1134/S0036023614070171

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