Skip to main content
Log in

Specific Features of the Atomic Structure of the Ti50Ni25Cu25 Alloy Amorphized during Rapid Quenching from a Melt

  • STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION
  • Published:
Physics of Metals and Metallography Aims and scope Submit manuscript

Abstract

This paper presents results of the structural study of the Ti50Ni25Cu25 alloy formed under rapid quenching from a melt. The studies were performed using neutron and X-ray diffraction and transmission and scanning electron microscopy. It has been revealed that this alloy has an amorphous nanocrystalline structure, which contains В2, L21, and L12 ensembles of nanocrystals with sizes to several nanometers in an amorphous matrix alongside with microspherolites, which have sustained the thermoelastic В2–В19 martensitic transition. It has also been shown for the first time that topological and compositional short-range atomic order is formed in the amorphous matrix of the Ti50N25Cu25 alloy in the form of localized nanodomains by the same three types of superstructures (В2, L21, L12).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Rapidly Quenched Alloys, Ed. by S. Shteeb and H. Warlimont (North-Holland, Amsterdam, 1985; Metallurgiya, Moscow, 1989).

  2. A. M. Glezer and I. E. Permyakova, Nanocrystals Quenched from Melt (Fizmatlit, Moscow, 2012) [in Russian].

    Google Scholar 

  3. A. M. Glezer, I. E. Permyakova, V. V. Gromov, and V. V. Kovalenko, Mechanical Behavior of Amorphous Alloys (Izd. SibGIU, Novokuznetsk, 2006) [in Russian]

  4. V. G. Pushin, S. B. Volkova, and N. M. Matveeva, “Structural and phase transformations in quasi-binary TiNi–TiCu alloys rapidly quenched from the melt: I. High-copper amorphous alloys,” Phys. Met. Metallogr. 83, 275–282 (1997).

    Google Scholar 

  5. V. G. Pushin, S. B. Volkova, and N. M. Matveeva, “Structural and phase transformations in quasi-binary TiNi–TiCu alloys rapidly quenched from the melt: II. Alloys with mixed amorphous–crystalline structure,” Phys. Met. Metallogr. 83, 283–288 (1997).

    Google Scholar 

  6. V. G. Pushin, S. B. Volkova, and N. M. Matveeva, “Structural and phase transformations in quasi-binary TiNi–TiCu alloys rapidly quenched from the melt: III. Mechanisms of crystallization,” Phys. Met. Metallogr. 83, 435–443 (1997).

    Google Scholar 

  7. A. V. Pushin, N. I. Kourov, A. A. Popov, and V. G. Pushin, “Structure, phase transformations, and properties of Ti2NiCu rapidly quenched alloys,” Materialovedenie 187, 24–32 (2012).

    Google Scholar 

  8. A. V. Pushin, A. A. Popov, and V. G. Pushin, “Effect of the deviation of the chemical composition from the stoichiometric composition on the structural and phase transformations and properties of rapidly quenched Ti50 + xNi25 – xCu25 alloys,” Phys. Met. Metallogr. 113, 283–294 (2012).

    Article  Google Scholar 

  9. A. V. Pushin, A. A. Popov, and V. G. Pushin, “ Effect of deviations of composition from the quasi-binary section TiNi–TiCu on structural and phase transformations in rapidly quenched alloys,” Phys. Met. Metallogr. 114, 692–702 (2013).

    Article  Google Scholar 

  10. A. V. Pushin, A. A. Popov, and V. G. Pushin, “Structure, phase transformation and properties of rapidly quenched Ti2NiCu alloys,” Mater. Sci. Forum 738–739, 321–325 (2013).

    Article  Google Scholar 

  11. S. F. Dubinin, V. D. Parkhomenko, V. G. Pushin, and S. G. Teploukhov, “ X-ray, electron, and neutron diffraction studies of the structure of TiNi-based alloys in the amorphous state obtained by rapid quenching or irradiation with fast neutrons,” Phys. Met. Metallogr. 89, 63–67 (2000).

    Google Scholar 

  12. V. D. Parkhomenko, S. F. Dubinin, V. G. Pushin, and S. G. Teploukhov, “Diffraction studies of the structure of nickel–titanium alloys amorphized by quenching and fast neutrons,” Vopr. At. Nauki Tekh., No. 4, 28–33 (2001)

  13. B. A. Aleksashin, V. V. Kondrat’ev, A. V. Korolev, A. V. Pushin, V. G. Pushin, A. V. Soloninin, and A. P. Tankeyev,” 63Cu, NMR spectra, magnetic susceptibility, and transmission electron microscopy of the rapidly quenched alloy Ti50Ni25Cu25,” Phys. Met. Metallogr. 110, 582–587 (2010).

    Article  Google Scholar 

  14. A. V. Pushin, V. G. Pushin, N. N. Kuranova, N. I. Kourov, T. E. Kuntsevich, V. V. Makarov and A. N. Uksusnikov, “Structure and phase transformations in copper-alloyed rapidly melt-quenched Ni50Ti32Hf18-based alloys with high-temperature shape memory effect,” Phys. Met. Metallogr. 118, 997–1005 (2017).

    Article  Google Scholar 

  15. V. G. Pushin, N. N. Kuranova, and A. V. Pushin, “Development of high-strength fine- and ultra-fine-grained shape memory alloys,” Phys. Met. Metallogr. 118 (13), 72–80 (2018).

    Google Scholar 

  16. V. G. Pushin, V. V. Stolyarov, R. Z. Valiev, N. I. Kourov, N. N. Kuranova, E. A. Prokofiev, and L. I. Yurchenko, “Features of structure and phase transformations in shape memory TiNi-based alloys after severe plastic deformation,” Ann. Chim. (Cachan, Fr.) 27, 77–88 (2002).

  17. V. G. Pushin, N. I. Kourov, T. E. Kuntsevich, N. N. Kuranova, N. M. Matveeva, and L. I. Yurchenko, “Nanocrystalline TiNi-based shape memory materials produced by ultrarapid quenching from melt,” Phys. Met. Metallogr. 94, Suppl. 1, S107–S118 (2002).

    Google Scholar 

  18. Heusler Alloys: Properties, Growth, Applications, Ed. by C. Felser (Springer International Publishing, Switzerland, 2016).

    Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was performed within the framework of state task “Structure”, grant no. AAAA-A18-118020190116-6 and the cooperative laboratory of the Ural Federal University n.a. the First President of Russia B.N. Yeltsin and the Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. G. Pushin.

Additional information

Translated by E. Glushachenkova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pushin, V.G., Pushin, A.V. & Kuranova, N.N. Specific Features of the Atomic Structure of the Ti50Ni25Cu25 Alloy Amorphized during Rapid Quenching from a Melt. Phys. Metals Metallogr. 120, 164–170 (2019). https://doi.org/10.1134/S0031918X19020157

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0031918X19020157

Keywords:

Navigation