Abstract
The influence of the nitrogen content on the structure and mechanical properties of heat and corrosion resistant 12% Cr martensitic-ferritic steel developed at the Central Research Institute of Structural Materials Prometey has been studied. Steel containing 0.061 wt % nitrogen possesses a high level of mechanical properties. The decrease in the nitrogen content to 0.017 wt % leads to an increase of structurally free ferrite fraction in the steel, a decrease in the density of dislocations, a decrease of structural dispersity and the absence of finely dispersed precipitates of niobium and vanadium nitrides and carbides. As a result, there is a decrease in the strength properties, especially in the heat resistance.
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P. Yvon and F. Carré, “Structural materials challenges for advanced reactor systems,” J. Nucl. Mater. 385, 217–222 (2009).
D. A. Artemieva, G. P. Karzov, A. S. Kudryavtsev, V. G. Markov, S. A. Suvorov, S. I. Brykov, V. V. Denisov, S. Yu. Korolev, and M. S. Metal’nikov, “Selection of a structural material for steam generators using criteria of corrosion resistance under different operating condi-tions of a high-power sodium reactor,” Vopr. At. Nauki Tekh., Ser.: Obespechenie Bezop. AES, No. 34, 53–59 (2014).
R. L. Klueh and A. T. Nelson, “Ferritic/martensitic steels for next-generation reactors,” J. Nucl. Mater. 371, 37–52 (2007).
J. Hald, “Microstructure and long-term creep properties of 9–12% Cr steels,” Int. J. Pressure Vessels Piping 85, 30–37 (2008).
F. Abe, M. Taneike, and K. Sawada, “Alloy design of creep resistant 9Cr steel using a dispersion of nanosized carbonitrides,” Int. J. Pressure Vessels Piping 84, 3–12 (2007).
A. E. Fedoseeva, V. A. Dudko, R. O. Kaibyshev, P. A. Kozlov, V. N. Skorobogatykh, and I. A. Shchenkova, “Microstructural changes in steel 10Kh9V2MFBR during creep for 40000 hours at 600°C,” Phys. Met. Metallogr. 116, 1047–1056 (2015).
J. Hald, “Prospects for martensitic 12% Cr steels for advanced steam power plants,” Trans. Indian Inst. Met. 69, 183–188 (2016).
H. K. Danielsen, P. E. di Nunzio, and J. Hald, “Kinetics of Z-phase precipitation in 9 to 12% Cr steels,” Metall. Mater. Trans. A 44, 2445–2452 (2013).
V. A. Dudko, A. E. Fedoseeva, A. N. Belyakov, and R. O. Kaibyshev, “Influence of the carbon content on the phase composition and mechanical properties of P92-type steel,” Phys. Met. Metallogr. 116, 1165–1174 (2015).
A. S. Kudriavtsev, D. A. Artemieva, and P. Ya. Rayner, “Effect of phase composition on the deformation capacity of 12Cr martensitic steel at high temperatures,” Inorg. Mater.: Appl. Res. 6, 566–570 (2015).
M. I. Gol’dshtein, S. V. Grachev, and Yu. G. Veksler, Special Steels (Moscow Inst. Steel and Alloys Moscow, 1999) [in Russian].
K. A. Lanskaya, High-Chromium Heat-Resistant Steels (Metallirgiya, Moscow, 1976) [in Russian].
R. O. Kaybyshev, V. N. Skorobogatykh, and I. A. Shchenkova, “New martensitic steels for fossil power plant: creep resistance,” Phys. Met. Metallogr. 109, 186–200 (2010).
M. Yoshizawa and M. Igarashi, “Long-term creep deformation characteristics of advanced ferritic steels for USC power plants,” Int. J. Pressure Vessels Piping 84, 37–43 (2007).
A. S. Kudryavtsev, K. A. Okhapkin, M. S. Mikhailov, C. S. Skutin, G. E. Zubova, and B. V. Fedotov, “Analysis of factors responsible for the accelerated creep rupture of 12% Cr martensitic steel weld joints,” Phys. Met. Metallogr. 117, 602–610 (2016).
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Original Russian Text © A.S. Kudryavtsev, D.A. Artem’eva, M.S. Mikhailov, 2017, published in Fizika Metallov i Metallovedenie, 2017, Vol. 118, No. 8, pp. 829–835.
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Kudryavtsev, A.S., Artem’eva, D.A. & Mikhailov, M.S. Nitrogen alloying of the 12% Cr martensitic-ferritic steel. Phys. Metals Metallogr. 118, 788–794 (2017). https://doi.org/10.1134/S0031918X17080087
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DOI: https://doi.org/10.1134/S0031918X17080087