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Dynamic Polarizability of a Negatively Charged Hydrogen Ion

  • SPECTROSCOPY AND PHYSICS OF ATOMS AND MOLECULES
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Abstract

The dynamic polarizability of a negatively charged hydrogen ion is calculated using a correlation-consistent basis set with high diffuseness. The obtained results are close to the results obtained by the method of summation over pseudostates. It is also shown that the density functional theory calculations do not allow one to achieve highly accurate results because of the large size of negative ions compared to both positive ions and neutral atoms (molecules).

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ACKNOWLEDGMENTS

We are grateful to Voronezh State University for providing computing resources of the High-Performance Computer Center of Parallel Computing to perform calculations.

Funding

This work was supported by the Russian Science Foundation (grant no. 19-12-00095) in the part of CCSD calculations by the Ministry of Science and Higher Education of the Russian Federation (project no. FZGU-2020-0035) in the part of density functional theory calculations.

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Authors and Affiliations

  1. Voronezh State University, 394018, Voronezh, Russia

    A. S. Kornev, V. E. Chernov & B. A. Zon

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  1. A. S. Kornev
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  2. V. E. Chernov
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  3. B. A. Zon
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Correspondence to A. S. Kornev.

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Translated by O. Kadkin

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Kornev, A.S., Chernov, V.E. & Zon, B.A. Dynamic Polarizability of a Negatively Charged Hydrogen Ion. Opt. Spectrosc. 129, 18–22 (2021). https://doi.org/10.1134/S0030400X21010100

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