Skip to main content
Log in

Nonequilibrium Fluctuations of Light Scattering Intensity in the Neighborhood of the Phase Transition Temperature

  • PHYSICAL OPTICS
  • Published:
Optics and Spectroscopy Aims and scope Submit manuscript

Abstract

Light scattering in a 3% aqueous solution of hydroxypropyl methylcellulose (metolose) is studied under nonequilibrium conditions within a temperature range of 303–353 K, i.e., in the neighborhood of the phase transition temperature (336 K). It is established that the light scattering intensity undergoes considerable fluctuations in this temperature interval. It is shown that they are caused by quasi-periodic motions (density fluctuations) appearing in the strongly nonequilibrium state of the solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. L. D. Landau and E. M. Lifshits, Course of Theoretical Physics, Vol. 5: Statistical Physics (Pergamon, Oxford, 1980; Fizmatlit, Moscow, 2002).

  2. A. Z. Patashinskii and V. L. Pokrovskii, Fluctuation Theory of Phase Transitions (Nauka, Moscow, 1982) [in Russian].

    Google Scholar 

  3. H. E. Stanley, Introduction to Phase Transitions and Critical Phenomena (Oxford Univ. Press, Oxford, 1987).

    Google Scholar 

  4. V. V. Brazhkin, S. V. Buldyrev, V. N. Ryzhov, and H. E. Stanley, New Kinds of Phase Transitions: Transformations in Disordered Substances (Springer, New York, 2002).

    Book  Google Scholar 

  5. X. Chen, J. Shu, and Q. Chen, Sci. Rep. 7, 46680 (2017). https://doi.org/10.1038/srep46680

    Article  ADS  Google Scholar 

  6. G. Sun, L. Xu, and N. Giovambattista, Phys. Rev. Lett. 120, 035701 (2018). https://doi.org/10.1103/PhysRevLett.120.035701

    Article  ADS  Google Scholar 

  7. U. C. Täuber, Ann. Rev. Condens. Matter Phys. 8, 185 (2017). https://doi.org/10.1146/annurev-conmatphys-031016-025444

    Article  ADS  Google Scholar 

  8. U. C. Täuber, Critical Dynamics: A Field Theory Approach to Equilibrium and Non-Equilibrium Scaling Behavior (Cambridge Univ. Press, Cambridge, 2014).

    Google Scholar 

  9. A. Subedi, A. Cavalleri, and A. Georges, Phys. Rev. B 89, 220301R (2014). https://doi.org/10.1103/PhysRevB.89.220301

    Article  ADS  Google Scholar 

  10. L. M. Sieberer, M. Buchhold, and S. Diehl, Rep. Prog. Phys. 79, 096001 (2016). https://doi.org/10.1088/0034-4885/79/9/096001

    Article  ADS  Google Scholar 

  11. M. Jo, J. Um, and B. Kahng, Phys. Rev. E 99, 032131 (2019). https://doi.org/10.1103/PhysRevE.99.032131

    Article  ADS  Google Scholar 

  12. K. Gowrishankar and M. Rao, Soft Matter 12, 2040 (2016). https://doi.org/10.1039/c5sm02527c

    Article  ADS  Google Scholar 

  13. P. Kratochvil, Classical Light Scattering from Polymer Solutions (Elsevier, Amsterdam, 1987).

    Google Scholar 

  14. W. Schärtl, Light Scattering from Polymer Solutions and Nanoparticle Dispersions (Springer, Berlin, Heidelberg, 2007).

    Google Scholar 

  15. Encyclopedia of Polymeric Nanomaterials, Ed. by S. Kobayashi and K. Müllen (Springer Reference, Heidelberg, 2015).

    Google Scholar 

  16. Light Scattering Near Phase Transitions, Ed. by H. Z. Cummins and A. P. Levanyuk (Elsevier, Amsterdam, 1983).

    Google Scholar 

  17. Theory of Light Scattering in Condensed Matter: Proceedings of the 1st Joint USA–USSR Symposium, Ed. by B. Bendow, and J. L. Birman, and V. M. Agranovich (Springer, 2011).

    Google Scholar 

  18. Metolose, Shin-Etsu Chemical Co., Japan. http://www.metolose.jp/en/industrial/metolose.html.

  19. O. M. Alekseev, Yu. F. Zabashta, V. I. Kovalchuk, M. M. Lazarenko, and L. A. Bulavin, Ukr. J. Phys. 64, 238 (2019). https://doi.org/10.15407/ujpe64.3.238

    Article  Google Scholar 

  20. V. F. Barkovskii, T. B. Gorodentseva, and N. B. Toporova, Fundamentals of Physico-Chemical Methods of Analysis (Vysshaya Shkola, Moscow, 1983) [in Russian].

    Google Scholar 

  21. G. Nicolis and I. Prigogine, Self-Organization in Nonequilibrium Systems: From Dissipative Structures to Order through Fluctuations (Wiley, New York, 1977).

    MATH  Google Scholar 

  22. Yu. L. Klimontovich, Statistical Physics (Harwood Academic, New York, 1986; Nauka, Moscow, 1982).

  23. L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 6: Fluid Mechanics (Nauka, Moscow, 1986; Pergamon, New York, 1987).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. N. Alekseev.

Ethics declarations

The authors declare that they have no conflict of interest.

Additional information

Translated by A. Nikol’skii

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Alekseev, A.N., Vergun, L.Y., Zabashta, Y.F. et al. Nonequilibrium Fluctuations of Light Scattering Intensity in the Neighborhood of the Phase Transition Temperature. Opt. Spectrosc. 128, 74–77 (2020). https://doi.org/10.1134/S0030400X20010038

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0030400X20010038

Keywords:

Navigation