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F 3 molecular ions in fluoride crystals

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Abstract

The UV absorption spectra of F 3 molecular ions in LaF3, SrF2, CaF2, and BaF2 crystals doped with rare-earth elements are studied. Comparison of radiation-colored and additively colored crystals reveals the absorption bands of F 3 hole centers in the region near 6 eV. Nonempirical calculations of optical transitions agree well with experimental results.

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Correspondence to E. A. Radzhabov.

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Original Russian Text © E.A. Radzhabov, 2016, published in Optika i Spektroskopiya, 2016, Vol. 120, No. 2, pp. 307–312.

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Radzhabov, E.A. F 3 molecular ions in fluoride crystals. Opt. Spectrosc. 120, 294–299 (2016). https://doi.org/10.1134/S0030400X16010173

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