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Role of Zeolites in Heat and Mass Transfer in Pelletized Multifunctional Cobalt-Based Fischer–Tropsch Catalysts

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Abstract

The role of a zeolite in the H-form in heat and mass transfer in pellets of a composite Co catalyst for Fischer–Tropsch synthesis (FTS) has been studied. It has been shown that the introduction of a heat-conducting additive—metallic aluminum—into the catalyst composition leads to an increase in the thermal stability of the pellets; however, it does not provide high productivity. The introduction of a zeolite into the catalyst contributes to the intensification of mass transfer owing to a decrease in the density and average boiling point of the resulting liquid hydrocarbons. In this case, heat transfer is further improved due to heat removal owing to the heat capacity of the removed products. According to the studies on the conversion of liquid hydrocarbons under FTS conditions, a mechanism of the simultaneous occurrence of these processes in the presence of a cobalt–zeolite catalyst has been proposed.

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ACKNOWLEDGMENTS

This work was performed using the equipment of the Center for collective use of scientific equipment “Studies of Nanostructured, Carbon, and Superhard Materials” of Technological Institute for Superhard and Novel Carbon Materials. The authors thank I.G. Solomonik (Technological Institute for Superhard and Novel Carbon Materials) for conducting studies by temperature-programmed desorption of ammonia.

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of a state task to Technological Institute for Superhard and Novel Carbon Materials and OOO INFRA.

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Authors and Affiliations

  1. Technological Institute for Superhard and Novel Carbon Materials, 108840, Troitsk, Moscow, Russia

    L. V. Sineva, E. O. Nalivaiko, K. O. Gryaznov & V. Z. Mordkovich

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  1. L. V. Sineva
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  2. E. O. Nalivaiko
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  3. K. O. Gryaznov
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  4. V. Z. Mordkovich
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Correspondence to L. V. Sineva.

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The authors declare that they have no conflicts of interest.

Additional information

Translated by M. Timoshinina

ADDITIONAL INFORMATION

The paper is based on the Proceedings of IV Russian Congress on Catalysis “Roskataliz” (September 20–25, 2021, Kazan, Russia).

Abbreviations and notation: FTS, Fischer–Tropsch synthesis; MWD, molecular weight distribution; LHM, liquid hydrocarbon mixture.

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Sineva, L.V., Nalivaiko, E.O., Gryaznov, K.O. et al. Role of Zeolites in Heat and Mass Transfer in Pelletized Multifunctional Cobalt-Based Fischer–Tropsch Catalysts. Kinet Catal 63, 321–329 (2022). https://doi.org/10.1134/S0023158422030089

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  • DOI: https://doi.org/10.1134/S0023158422030089

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