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Development of Small-Angle X-Ray Scattering Methods for Analysis of Supported Catalysts and Nanocomposites

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Abstract

A method of selective dissolution of support or matrix (STS) for studying supported metal catalysts and nanocomposites by small angle X-ray scattering has been proposed. Due to this technique, the strong parasitic scattering from the porous structure of support/matrix or their particles disappears. The efficiency of the STS technique was demonstrated on different samples. The transmission electron microscopy data of the initial supported catalysts were found to be in good agreement with the small angle X-ray scattering data of sols prepared from them. The main limitations of this technique are selective dissolution of different phases in complex materials and possible particle aggregation in the prepared sols.

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ACKNOWLEDGMENTS

I am grateful to A.V. Ishchenko, D.A. Zyuzin, A.L. Nuzhdin, and L.A. Kovtunova for their assistance in this study and to the “High Technologies and Analysis of Nanosystems” Multiaccess Center of Novosibirsk State University for providing measurement equipment.

Funding

This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation under the government contract at the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. АААА-А21-121011390053-4).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    Yu. V. Larichev

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    Yu. V. Larichev

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  1. Yu. V. Larichev
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Correspondence to Yu. V. Larichev.

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The author declares that he has no conflicts of interest.

Additional information

Translated by L. Smolina

Abbreviations and notation: TEM, transmission electron microscopy, XRD, X-ray diffraction analysis, SAXS, small-angle X-ray scattering, CSR, coherent scattering region.

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Larichev, Y.V. Development of Small-Angle X-Ray Scattering Methods for Analysis of Supported Catalysts and Nanocomposites. Kinet Catal 62, 820–827 (2021). https://doi.org/10.1134/S0023158421060100

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  • DOI: https://doi.org/10.1134/S0023158421060100

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