Abstract
Highly dispersed 1.9 wt % Pt/Ce0.75Zr0.25O2 – x and 5 wt % Pt/Ce0.75Zr0.25O2 – x catalysts with an average particle size of 0.9 nm were prepared by sorption-hydrolytic precipitation. It was shown that the catalysts are active in the water gas shift reaction in a mixture simulating synthesis gas produced by steam reforming of natural gas. At an initial CO concentration of 10 vol % and a flow rate of 30000 ncm3 \({\text{g}}_{{{\text{cat}}}}^{{ - 1}}\) h–1, outlet CO and CH4 concentrations reach 2.5 and 0.01 vol %, respectively, over 1.9 wt % Pt/Ce0.75Zr0.25O2 – x at 325°C and 1.5 and 0.075 vol %, respectively, over 5 wt % Pt/Ce0.75Zr0.25O2 – x at 300°С. The observed reaction orders for CO and H2O over 5 wt % Pt/Ce0.75Zr0.25O2 – x were found to be close to zero, and the apparent activation energy for both catalysts was 86 kJ/mol. Transmission electron microscopy of the catalysts showed that the narrow size distribution and high dispersion of the supported particles are retained during the reaction. However, some coarsening of Pt particles occurs, the average size increases to 1.4 and 1.6 nm for 1.9 wt % Pt/Ce0.75Zr0.25O2 – x and 5 wt % Pt/Ce0.75Zr0.25O2 – x, respectively. For the catalysts after the reaction, the metallic Pt surface area values, measured by CO chemisorption and transmission electron microscopy, differ significantly. Most likely, it is caused by the presence of some of the surface Pt atoms in the oxidized state. It was shown that the temperature dependences of the turnover frequency in the water gas shift reaction per the length unit of the metal-support interface, coincide for catalysts 1.9 wt % Pt/Ce0.75Zr0.25O2 – x and 5 wt % Pt/Ce0.75Zr0.25O2 – x. Based on this, an assumption was made about the leading role of the Pt–Ce0.75Zr0.25O2 – x boundary in the catalysis of the water gas shift reaction.
Similar content being viewed by others
REFERENCES
Sharaf, O.Z. and Orhan, M.F., Renewable Sustainable Energy Rev., 2014, vol. 32, p. 810.
Park, E.D., Lee, D., and Lee, H.C., Catal. Today, 2009, vol. 139, no. 4, p. 280.
Kerzhentsev, M.A., Matus, E.V., Rundau, I.A., Kuznetsov, V.V., Ismagilov, I.Z., Ushakov, V.A., Yashnik, S.A., and Ismagilov, Z.R. Kinet. Catal., 2017, vol. 58, no. 5, p. 601.
Choudhary, T.V. and Goodman, D.W., Catal. Today, 2002, vol. 77, nos. 1–2, p. 65.
Baronskaya, N.A., Minyukova, T.P., Khassin, A.A., Yurieva, T.M., and Parmon, V.N., Russ. Chem. Rev., 2010, vol. 79, no. 11, p. 1027.
Potemkin, D.I., Konishcheva, M.V., Zadesenets, A.V., Snytnikov, P.V., Filatov, E.Yu., Korenev, S.V., and Sobyanin, V.A., Kinet. Catal., 2018, vol. 59, no. 4, p. 514.
Il’ichev, A.N., Bykhovsky, M.Ya., Fattakhova, Z.T., Shashkin, D.P., Fedorova, Yu.E., Matyshak, V.A., and Korchak, V.N., Kinet. Catal., 2019, vol. 60, no. 5, p. 661.
Takenaka, S., Shimizu, T., and Otsuka, K., Int. J. Hydrogen Energy, 2004, vol. 29, no. 10, p. 1065.
Palma, V., Ruocco, C., Cortese, M., Renda, S., Meloni, E., Festa, G., and Martino, M., Metals, 2020, vol. 10, no. 7, p. 1.
Voitic, G., Pichler, B., Basile, A., Iulianelli, A., Malli, K., Bock, S., and Hacker, V., Fuel Cells and Hydrogen: From Fundamentals to Applied Research, Amsterdam: Elsevier, 2018, p. 215.
Ivanova, S., Laguna, O.H., Centeno, M.Á., Eleta, A., Montes, M., and Odriozola, J.A., Renewable Hydrogen Technologies: Production, Purification, Storage, Applications and Safety, Amsterdam: Elsevier, 2013, Ch. 10, p. 225.
Chen, W.H. and Chen, C.Y., Appl. Energy, 2020, vol. 258, p. 114078.
Li, Y., Kottwitz, M., Vincent, J.L., Enright, M.J., Liu, Z., Zhang, L., Huang, J., Senanayake, S.D., Yang, W.C.D., Crozier, P.A., Nuzzo, R.G., and Frenkel, A.I., Nat. Commun., 2021, vol. 12, no. 1, p. 1.
Efstathioum, A.M., Catalysis, Cambridge: The Royal Society of Chemistry, 2016, vol. 28, Ch. 7, p. 175.
Shekhar, M., Wang, J., Lee, W.-S., Damion Williams, W., Min Kim, S., Stach, A.E., Miller, T.J., Nicholas Delgass, W., and Ribeiro, H.F., J. Am. Chem. Soc., 2012, vol. 134, no. 10, p. 4700.
Chen, Y., Lin, J., Li, L., Qiao, B., Liu, J., Su, Y., and Wang, X., ACS Catal., 2018, vol. 8, no. 2, p. 859.
Simonov, P.A., Shoinkhorova, T.B., Snytnikov, P.V., Potemkin, D.I., and Belyaev, V.D., RF Patent No. 2653360 (2017).
Shoynkhorova, T.B., Simonov, P.A., Potemkin, D.I., Snytnikov, P.V., Belyaev, V.D., Ishchenko, A.V., Svintsitskiy, D.A., and Sobyanin, V.A., Appl. Catal., B, 2018, vol. 237, p. 237.
Bergeret, G. and Gallezot, P., Handbook of Heterogeneous Catalysis, New York: Wiley, 2008, p. 738.
Pastor-Pérez, L., Ramos-Fernández, E.V., and Sepúlveda-Escribano, A., Int. J. Hydrogen Energy, 2019, vol. 44, no. 39, p. 21837.
Gonzalez Castaño, M., Reina, T.R., Ivanova, S., Centeno, M.A., and Odriozola, J.A., J. Catal., 2014, vol. 314, p. 1.
Reddy, G.K. and Smirniotis, P.G., Water Gas Shift Reaction, Amsterdam: Elsevier, 2015, p. 225.
Boronin, A.I., Slavinskaya, E.M., Figueroba, A., Stadnichenko, A.I., Kardash, T.Y., Stonkus, O.A., Fedorova, E.A., Muravev, V.V., Svetlichnyi, V.A., Bruix, A., and Neyman, K.M., Appl. Catal., B, 2021, vol. 286, p. 119931.
Kalamaras, C.M., Gonzalez, I.D., Navarro, R.M., Fierro, J.L.G., and Efstathiou, A.M., J. Phys. Chem. C, 2011, vol. 115, no. 23, p. 11595.
ACKNOWLEDGMENTS
The TEM studies were carried out using facilities of the shared research center “National center of investigation of catalysts” at Boreskov Institute of Catalysis.
Funding
The work was supported by the Russian Science Foundation under the project no. 21-73-20075 (A.M. Gorlova, O.A. Stonkus, V.P. Pakharukova).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Abbreviations and notation: PEMFC, proton exchange membrane fuel cell; WGSR, water gas shift reaction; TEM, transmission electron microscopy; DRIFTS, diffuse reflectance infrared Fourier-transformed spectroscopy; XPS, X-ray photoelectron spectroscopy; TOF, turnover frequency.
Rights and permissions
About this article
Cite this article
Gorlova, A.M., Simonov, P.A., Stonkus, O.A. et al. Pt/Ce0.75Zr0.25O2 – x Catalysts for Water Gas Shift Reaction: Morphology and Catalytic Properties. Kinet Catal 62, 812–819 (2021). https://doi.org/10.1134/S0023158421060057
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158421060057