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An XPS Study of the Interaction of a Palladium Foil with NO2

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Abstract

The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO2 pressures of 10–6, 10–5, and 10–4 mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3d5/2, Pd 3p3/2, and O 1s binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness d was estimated based on the weakening of the Pd 3d line of metallic palladium. As the interaction temperature was increased, d initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state.

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation (project no. 14-23-00146).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. Yu. Smirnov, I. O. Klembovskii, A. V. Kalinkin & V. I. Bukhtiyarov

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    I. O. Klembovskii & V. I. Bukhtiyarov

Authors
  1. M. Yu. Smirnov
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  2. I. O. Klembovskii
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  3. A. V. Kalinkin
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  4. V. I. Bukhtiyarov
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Correspondence to M. Yu. Smirnov.

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Translated by V. Makhlyarchuk

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Smirnov, M.Y., Klembovskii, I.O., Kalinkin, A.V. et al. An XPS Study of the Interaction of a Palladium Foil with NO2. Kinet Catal 59, 786–791 (2018). https://doi.org/10.1134/S0023158418060150

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