Skip to main content
SpringerLink
Log in

Oxidative coupling of methane: Mechanism and kinetics

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The mechanism of the oxidative coupling of methane (OCM), a reaction discovered in the early 1980s, and the development of approaches to kinetic description of this reaction are analyzed. In addition to being of potential practical significance as a single-step synthetic route from methane to ethylene, a valuable chemical and petrochemical semiproduct, OCM was the first heterogeneous–homogeneous process of this hitherto unknown type. Its distinctive feature is that it is impossible to separately determine the methane conversion via the main pathway (into C2 hydrocarbons) in the homogeneous phase and on the catalyst surface, because reactive intermediates (methyl radicals) result from the interaction of methane molecules with active sites of the surface, while the primary OCM product (ethane) results from the recombination of these radicals in the gas phase. The correlation between the phenomenological regularities of the OCM process and its mechanism, the correlation between the nature of the active sites and the mechanism of activation of methane and oxygen, and the possibility of constructing a self-consistent kinetic model taking into account the specific features of the process—redox nature of the active sites and the free-radical character of the major intermediate compounds—are analyzed in detail.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. US Patent 4205194, 1980.

  2. Fang, T. and Yeh, C., J. Catal., 1981, vol. 69, no. 2, p. 227.

    Article  CAS  Google Scholar 

  3. Keller, G.E. and Bhasin, M.M., J. Catal., 1982, vol. 73, no. 1, p. 9.

    Article  CAS  Google Scholar 

  4. Hinsen, W., Bytyn, W., and Baerns, M., 8th Int. Congr. on Catalysi., West Berlin, 1984, vol. 3, p. 581.

    Google Scholar 

  5. Ito, T. and Lunsford, J.H., Nature, 1985, vol. 314, no. 6013, p. 721.

    Article  CAS  Google Scholar 

  6. Driscoll, D.J., Campbell, K.D., and Lunsford, J.H., Adv. Catal., 1987, vol. 35, p. 139.

    CAS  Google Scholar 

  7. Sinev, M.Yu., Korchak, V.N., and Krylov, O.V., Russ. Chem. Rev., 1989, vol. 58, no. 1, p. 22.

    Article  Google Scholar 

  8. Methane Conversion by Oxidative Processes, Wolf, E., Ed., New York: Van Nostrand Reinhold, 1992.

  9. Voskresenskaya, E.N., Roguleva, V.G., and Anshits, A.G., Catal. Rev. Sci. Eng., 1995, vol. 37, no. 1, p. 101.

    Article  CAS  Google Scholar 

  10. Sinev, M.Yu., Margolis, L.Ya., and Korchak, V.N., Russ. Chem. Rev., 1995, vol. 64, no. 4, p. 349.

    Article  Google Scholar 

  11. Martin, G.A. and Mirodatos, C., Fuel Process. Technol., 1995, vol. 42, p. 179.

    Article  CAS  Google Scholar 

  12. Schuurman, Y. and Mirodatos, C., Appl. Catal., A, 1997, vol. 151, p. 305.

    Article  CAS  Google Scholar 

  13. Krylov, O.V. and Arutyunov, V.S., Okislitel’nye prevrashcheniya metana (Oxidative Conversions of Methane., Moscow: Nauka, 1998.

    Google Scholar 

  14. Centi, G., Cavani, F., and Trifiro, F., Selective Oxidation by Heterogeneous Catalysis, New York: Springer, 2001.

    Book  Google Scholar 

  15. Sinev, M.Yu., J. Catal., 2003, vol. 216, nos. 1–2, p. 468.

    Article  CAS  Google Scholar 

  16. Sinev, M., Arutyunov, V., and Romanets, A., Adv. Chem. Eng, 2007, vol. 32, p. 167.

    Article  CAS  Google Scholar 

  17. Kondratenko, E.V. and Baerns, M., in Handbook of Heterogeneous Catalysis, Ertl, G., Knözinger, H., Schüth, F., and Weitkamp, J., Eds., Weinheim: Wiley–VCH, 2008, p. 3010.

  18. Sinev, M.Yu., Fattakhova, Z.T., Lomonosov, V.I., and Gordienko, Yu.A., J. Nat. Gas Chem., 2009, vol. 18, no. 3, p. 273.

    Article  CAS  Google Scholar 

  19. Schwarz, H., Chem. Phys. Lett., 2015, vol. 629, p. 91.

    Article  CAS  Google Scholar 

  20. Sokolovskii, V.D. and Mamedov, E.A., Catal. Today, 1992, vol. 14, nos. 3–4, p. 415.

    Google Scholar 

  21. Krylov, O.V., Russ. Chem. Rev., 1992, vol. 61, no. 8, p. 851.

    Article  Google Scholar 

  22. Lunsford, J.H., Angew. Chem., Int. Ed. Engl., 1995, vol. 34, no. 9, p. 970.

    Article  CAS  Google Scholar 

  23. Zavyalova, U., Holena, M., Schlögl, R., and Baerns, M., ChemCatChem, 2011, vol. 3, p. 1935.

    Article  CAS  Google Scholar 

  24. Arndt, S., Otremba, T., Simon, U., Yildiz, M., Schubert, H., and Schomäcker, R., Appl. Catal., A, 2012, vols. 425–426, p. 53.

    Article  CAS  Google Scholar 

  25. Mleczko, L., Schweer, D., Durjanova, Z., Andorf, R., and Baerns, M., Stud. Surf. Sci. Catal., 1994, vol. 81, p. 155.

    Article  CAS  Google Scholar 

  26. Usachev, N.Ya., Kharlamov, V.V., Belanova, E.P., Starostina, T.S., and Krukovskii, I.M., Ross. Khim. Zh., 2008, vol. 52, no. 4, p. 22.

    CAS  Google Scholar 

  27. Makhlin, V.A. and Magomedova, M.V., Khim. Promst. Segodnya, 2011, vol. 10, p. 6.

    Google Scholar 

  28. Driscoll, D.J., Martir, W., Wang, J.-X., and Lunsford, J.H., J. Am. Chem. Soc., 1985, vol. 107, no. 1, p. 58.

    Article  CAS  Google Scholar 

  29. Driscoll, D.J. and Lunsford, J.H., J. Phys. Chem., 1985, vol. 89, no. 21, p. 4415.

    Article  CAS  Google Scholar 

  30. Otsuka, K., Jinno, K., and Morikawa, A., Chem. Lett., 1985, vol. 14, no. 4, p. 499.

    Article  Google Scholar 

  31. Lin, C.H., Campbell, K.D., Wang, J.X., and Lunsford, J.H., J. Phys. Chem., 1986, vol. 90, no. 4, p. 534.

    Article  CAS  Google Scholar 

  32. Otsuka, K., Jinno, K., and Morikawa, A., J. Catal., 1986, vol. 100, no. 2, p. 353.

    Article  CAS  Google Scholar 

  33. Choudhary, V.R., Chaudhari, S.T., Rajput, A.M., and Rane, V.H., J. Chem. Soc., Chem. Commun., 1989, vol. 9, p. 555.

    Article  Google Scholar 

  34. Choudhary, V.R., Chaudhari, S.T., Rajput, A.M., and Rane, V.H., Catal. Lett., 1989, vol. 3, no. 1, p. 85.

    Article  CAS  Google Scholar 

  35. Sinev, M.Yu., Tyulenin, Yu.P., and Rozentuller, B.V., Kinet. Catal., 1991, vol. 32, no. 4, p. 807.

    Google Scholar 

  36. Lee, S.H., Jung, D.W., Kim, J.B., and Kim, Y.-R., Appl. Catal., A, 1997, vol. 164, nos. 1–2, p. 159.

    Article  CAS  Google Scholar 

  37. Gayko, G., Wolf, D., Kondratenko, E.V., and Baerns, M., J. Catal., 1998, vol. 178, no. 2, p. 441.

    Article  CAS  Google Scholar 

  38. Papa, F., Gingasu, D., Patron, L., Miyazaki, A., and Balint, I., Appl. Catal., A, 2010, vol. 375, no. 1, p. 172.

    Article  CAS  Google Scholar 

  39. US Patent 4499322, 1984.

  40. Minachev, Kh.M., Usachev, N.Ya., Khodakov, Yu.S., Udut, V.N., and Makarov, P.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1987, no. 9, p. 2124.

    Google Scholar 

  41. Jones, C.A., Leonard, J.J., and Sofranko, J.A., J. Catal., 1987, vol. 103, no. 2, p. 311.

    Article  CAS  Google Scholar 

  42. Sofranko, J.A., Leonard, J.J., Jones, C.A., Gaffney, A.M., and Withers, H.P., Catal. Today, 1988, vol. 3, nos. 2–3, p. 127.

    Article  CAS  Google Scholar 

  43. Minachev, Kh.M., Usachev, N.Ya., Belanova, E.P., and Shirokova, G.A., Catal. Today, 1992, vol. 13, no. 4, p. 565.

    Article  Google Scholar 

  44. Fang, X.P., Li, S.B., Lin, J.Z., and Chu, Y.L., J. Mol. Catal. (China), 1992, vol. 6, p. 255.

    CAS  Google Scholar 

  45. Fang, X.P., Li, S.B., Lin, J.Z., and Chu, Y.L., J. Mol. Catal. (China), 1992, vol. 6, p. 427.

    CAS  Google Scholar 

  46. Sinev, M.Yu., Vorob’eva, G.A., and Korchak, V.N., Kinet. Catal., 1986, vol. 27, no. 5, p. 1007.

    Google Scholar 

  47. Ali Emesh, I.T. and Amenomiya, Y., J. Phys. Chem., 1986, vol. 90, no. 20, p. 4785.

    Article  Google Scholar 

  48. Labinger, J.A. and Ott, K.C., J. Phys. Chem., 1987, vol. 91, no. 11, p. 2682.

    Article  CAS  Google Scholar 

  49. Sinev, M.Yu., Bychkov, V.Yu., Korchak, V.N., and Krylov, O.V., Catal. Today, 1990, vol. 6, no. 4, p. 543.

    Article  CAS  Google Scholar 

  50. Paganini, M.C., Chiesa, M., Martino, P., Giamello, E., and Garrone, E., J. Phys.Chem. B, 2003, vol. 107, no. 11, p. 2575.

    Article  CAS  Google Scholar 

  51. Sinev, M.Yu., Tyulenin, Yu.P., Bychkov, V.Yu., Rozentuller, B.V., and Rajput, A.M., Proc. 9th Soviet–Japanese Seminar on Catalysis., Yuzhno-Sakhalinsk, 1990, p. 75.

    Google Scholar 

  52. Sinev, M.Yu., Doctoral (Chem.) Dissertation., Moscow: Inst. of Chemical Physics, 2011.

    Google Scholar 

  53. Ekstrom, A., Regtop, R., and Bhargava, S., Appl. Catal., 1990, vol. 60, p. 253.

    Article  Google Scholar 

  54. Sinev, M.Yu., Tulenin, Yu.P., Kalashnikova, O.V., Bychkov, V.Yu., and Korchak, V.N., Catal. Today, 1996, vol. 32, nos. 1–4, p. 157.

    Article  CAS  Google Scholar 

  55. Tulenin, Yu.P., Kadushin, A.A., Seleznev, V.A., Shestakov, A.F., and Korchak, V., Catal. Today, 1992, vol. 13, p. 329.

    Article  CAS  Google Scholar 

  56. Tulenin, Yu.P., Kadushin, A.A., Seleznev, V.A., Shestakov, A.F., and Menshikov, V.A., Catal. Today, 1992, vol. 13, p. 523.

    Article  CAS  Google Scholar 

  57. Lomonosov, V.I., Usmanov, T.R., Sinev, M.Yu., and Antonyuk, S.N., Vestn. MITKhT, 2014, vol. 9, no. 6, p. 55.

    CAS  Google Scholar 

  58. Lomonosov, V.I., Usmanov, T.R., Sinev, M.Yu., and Bychkov, V.Yu., Kinet. Catal., 2014, vol. 55, no. 4, p. 474.

    Article  CAS  Google Scholar 

  59. Nersenyan, L.A., Vardanyan, I.A., Kegeyan, E.M., Margolis, L.Ya., and Nalbandyan, A.B., Dokl. Akad. Nauk SSSR, 1975, vol. 220, no. 3, p. 605.

    Google Scholar 

  60. Driscoll, D.J., Campbell, K.D., and Lunsford, J.H., Adv. Catal., 1987, vol. 35, p. 139.

    CAS  Google Scholar 

  61. Sinev, M.Yu., Korchak, V.N., Krylov, O.V., Grigoryan, R.R., and Garibyan, T.A., Kinet. Catal., 1988, vol. 29, no. 5, p. 954.

    Google Scholar 

  62. Feng, Y., Niiranen, J., and Gutman, D., J. Phys. Chem., 1991, vol. 95, no. 17, p. 6558.

    Article  CAS  Google Scholar 

  63. Feng, Y., Niiranen, J., and Gutman, D., J. Phys. Chem., 1991, vol. 95, no. 17, p. 6564.

    Article  CAS  Google Scholar 

  64. Buyevskaya, O.V., Rothaemel, M., Zanthoff, H.W., and Baerns, M., J. Catal., 1994, vol. 146, no. 2, p. 346.

    Article  CAS  Google Scholar 

  65. Gleaves, J.T., Ebner, J.R., and Kuechler, T.C., Catal. Rev. Sci. Eng., 1998, vol. 30, no. 1, p. 49.

    Article  Google Scholar 

  66. Luo, L., Tang, X., Wang, W., Wang, Y., Sun, S., Qi, F., and Huang, W., Sci. Rep., 2013, vol. 3, p. 1.

    Google Scholar 

  67. Ito, T., Wang, J.-X., and Lunsford, J.H., J. Am. Chem. Soc., 1985, vol. 107, no. 18, p. 5062.

    Article  CAS  Google Scholar 

  68. Otsuka, K., Murakami, Y., Wada, Y., Said, A.A., and Morikawa, A., J. Catal., 1990, vol. 121, no. 1, p. 122.

    Article  CAS  Google Scholar 

  69. Sinev, M.Y., Res. Chem. Intermed., 2006, vol. 32, nos 3-4, p. 205.

    Article  CAS  Google Scholar 

  70. Buyevskaya, O.V., Suleimanov, A.I., Aliev, S.M., and Sokolovskii, V.D., React. Kinet. Catal. Lett., 1987, vol. 33, no. 1, p. 223.

    Article  Google Scholar 

  71. Sokolovskii, V.D., Aliev, G.M., Buyevskaya, O.V., and Davydov, A.A., Catal. Today, 1989, vol. 4, nos. 3–4, p. 293.

    Article  CAS  Google Scholar 

  72. Choudhary, V.R. and Rane, V.H., J. Catal., 1991, vol. 130, no. 2, p. 411.

    Article  CAS  Google Scholar 

  73. Kwapien, K., Sierka, M., Döbler, J., and Sauer, J., ChemCatChem, 2010, vol. 2, no. 2, p. 819.

    Article  CAS  Google Scholar 

  74. Schwach, P., Hamilton, N., Eichelbaum, M., Thum, L., Lunkenbein, T., Schlögl, R., and Trunschke, A., J. Catal., 2015, vol. 329, p. 560.

    Article  CAS  Google Scholar 

  75. Schwach, P., Hamilton, N., Eichelbaum, M., Thum, L., Lunkenbein, T., Schlögl, R., and Trunschke, A., J. Catal., 2015, vol. 329, p. 574.

    Article  CAS  Google Scholar 

  76. Nelson, P.F., Lukey, C.A., and Cant, N.W., J. Phys. Chem., 1988, vol. 92, no. 2, p. 6176.

    Article  CAS  Google Scholar 

  77. Lapszewicz, J.A. and Jiand, X.-Z., Catal. Lett., 1992, vol. 13, nos 1-2, p. 103.

    Article  CAS  Google Scholar 

  78. Dissanayake, D., Lunsford, J.H., and Rosynek, M.P., J. Catal., 1994, vol. 146, no. 2, p. 613.

    Article  CAS  Google Scholar 

  79. Papa, F., Luminita, P., Osiceanu, P., Birjega, R., Akane, M., and Balint, I., J. Mol. Catal. A: Chem., 2011, vol. 346, nos. 1–2, p. 46.

    Article  CAS  Google Scholar 

  80. Sinev, M.Yu., Filkova, D.G., Bychkov, V.Yu., Ukharskii, A.A., and Krylov, O.V., Kinet. Catal., 1991, vol. 32, no. 1, p. 137.

    Google Scholar 

  81. Sinev, M.Yu., Margolis, L.Ya., Bychkov, V.Yu., and Korchak, V.N., Stud. Surf. Sci. Catal., 1997, vol. 110, p. 327.

    Article  CAS  Google Scholar 

  82. Sinev, M.Yu., Russ. J. Phys. Chem. B, 2007, vol. 1, no. 4, p. 329.

    Article  Google Scholar 

  83. Sohrabi, M., Dabir, B., Eskandari, A., and Golpasha, R., J. Chem. Technol. Biotechnol., 1996, vol. 67, no. 1, p. 15.

    Article  CAS  Google Scholar 

  84. Shahri, S.M.K. and Alavi, S.M., J. Nat. Gas. Chem., 2009, vol. 18, no. 1, p. 25.

    Article  CAS  Google Scholar 

  85. Peil, K., Goodwin, J.G., and Marcelin, J., J. Am. Chem. Soc., 1990, vol. 112, no. 16, p. 6129.

    Article  CAS  Google Scholar 

  86. Mirodatos, C., Holmen, A., Mariscal, R., and Martin, G.A., Catal. Today, 1990, vol. 6, no. 4, p. 601.

    Article  CAS  Google Scholar 

  87. Lacombe, S., Zanthoff, H., and Mirodatos, C., J. Catal., 1995, vol. 155, no. 1, p. 106.

    Article  CAS  Google Scholar 

  88. Jones, C.A., Leonard, J.J., and Sofranko, J.A., J. Catal., 1987, vol. 103, no. 2, p. 302.

    Article  Google Scholar 

  89. Aika, K.-I. and Lunsford, J.H., J. Phys. Chem., 1978, vol. 82, no. 16, p. 1794.

    Article  CAS  Google Scholar 

  90. Takita, Y. and Lunsford, J.H., J. Phys. Chem., 1979, vol. 83, no. 6, p. 683.

    Article  CAS  Google Scholar 

  91. Tong, Y., Rosynek, M.P., and Lunsford, J.H., J. Phys. Chem., 1989, vol. 93, no. 8, p. 2896.

    Article  CAS  Google Scholar 

  92. Zhang, H.S., Wang, J.-X., Driscoll, D.J., and Lunsford, J.H., J. Catal., 1988, vol. 112, no. 2, p. 366.

    Article  CAS  Google Scholar 

  93. Lin, C.-H., Wang, J.-X., and Lunsford, J.H., J. Catal., 1988, vol. 111, no. 2, p. 302.

    Article  CAS  Google Scholar 

  94. Wang, J.X. and Lunsford, J., H, J. Phys. Chem., 1986, vol. 90, no. 17, p. 3890.

    Article  CAS  Google Scholar 

  95. Wu, M.-C., Truong, C.M., Coulter, K., and Goodman, D.W., J. Catal., 1993, vol. 140, no. 2, p. 344.

    Article  CAS  Google Scholar 

  96. Rodríquez, J., Aray, Y., and Ruette, F., J. Mol. Struct.: THEOCHEM, 1990, vol. 210, p. 323.

    Article  Google Scholar 

  97. Borve, K.J. and Pettersson, L.G., J. Phys. Chem., 1991, vol. 95, no. 8, p. 3214.

    Article  Google Scholar 

  98. Xu, M., Shi, C., Yang, X., Rosynek, M.P., and Lunsford, J.H., J. Phys. Chem., 1992, vol. 96, no. 15, p. 6395.

    Article  CAS  Google Scholar 

  99. Sinev, M.Yu., Bychkov, V.Yu., Korchak, V.N., Aptekar’, E.L., and Krylov, O.V., Kinet. Catal., 1989, vol. 30, no.6.

    Google Scholar 

  100. Sinev, M.Yu., Bychkov, V.Yu., Korchak, V.N., Aptekar’, E.A., and Krylov, O.V., Kinet. Catal., 1989, vol. 30, no. 5, p. 989.

    Google Scholar 

  101. Sinev, M.Yu., Tyulenin, Yu.P., and Rozentuller, B.V., Kinet. Catal., 1991, vol. 32, no. 4, p. 807.

    Google Scholar 

  102. Sinev, M.Yu., Bychkov, V.Yu., Tulenin, Yu.P., Kalashnikova, O.V., Rozentuller, B.V., and Shiryaev, P.A., Catal. Today, 1992, vol. 13, no. 4, p. 585.

    Article  CAS  Google Scholar 

  103. Burrows, A., Kiely, Ch.J., Hutchings, G.J., Joyner, R.W., and Sinev, M.Yu., J. Catal., 1997, vol. 167, no. 1, p. 77.

    Article  CAS  Google Scholar 

  104. Burrows, A., Kiely, Ch.J., Hargreaves, J.S.J., Joyner, R.W., Hutchings, G.J., Sinev, M.Yu., and Tulenin, Yu.P., J. Catal., 1998, vol. 173, no. 2, p. 383.

    Article  CAS  Google Scholar 

  105. Filkova, D.G., Petrov, L.A., Sinev, M.Yu., and Tyulenin, Yu.P., Catal. Lett., 1992, vol. 13, p. 323.

    Article  CAS  Google Scholar 

  106. Sinev, M.Yu., Korchak, V.N., and Krylov, O.V., Kinet. Catal., 1986, vol. 27, no. 5, p. 1110.

    Google Scholar 

  107. Mestl, G., Knözinger, H., and Lunsford, J.H., Ber. Bunsen-Ges. Phys. Chem., 1993, vol. 97, no. 3, p. 319.

    Article  CAS  Google Scholar 

  108. Zhang, H.B., Lin, G.D., Wan, H.L., Liu, Y.D., Weng, W.Z., Cai, J.X., Shen, Y.F., and Tsai, K.R., Catal. Lett., 2001, vol. 73, nos. 2–4, p. 141.

    Article  CAS  Google Scholar 

  109. Wan, H.L., Zhou, X.P., Weng, W.Z., Long, R.Q., Chao, Z.S., Zhang, W.D., Chen, M.S., Luo, J.Z., and Zhou, S.Q., Catal. Today, 1999, vol. 51, no. 1, p. 161.

    Article  CAS  Google Scholar 

  110. Pacheco, J.G., Eon, J.G., and Schmal, M., Catal. Lett., 2000, vol. 68, nos 2-3, p. 197.

    Article  Google Scholar 

  111. Palmer, M.S., Neurock, M., and Olken, M.M., J. Phys. Chem. B, 2002, vol. 106, no. 25, p. 6543.

    Article  CAS  Google Scholar 

  112. Palmer, M.S., Neurock, M., and Olken, M.M., J. Am. Chem. Soc., 2002, vol. 124, no. 28, p. 8452.

    Article  CAS  Google Scholar 

  113. Kondratenko, E.V., Buyevskaya, O.V., Soick, M., and Baerns, M., Catal. Lett., 1999, vol. 63, nos 3-4, p. 153.

    Article  CAS  Google Scholar 

  114. Kondratenko, E.V., Wolf, D., and Baerns, M., Catal. Lett., 1999, vol. 58, no. 4, p. 217.

    Article  CAS  Google Scholar 

  115. Kondratenko, E.V., Buyevskaya, O.V., and Baerns, M., J. Mol. Catal. A: Chem., 2000, vol. 158, no. 1, p. 199.

    Article  CAS  Google Scholar 

  116. Iwamoto, M. and Lunsford, J.H., J. Phys. Chem., 1980, vol. 84, no. 23, p. 3079.

    Article  CAS  Google Scholar 

  117. Morrison, S.R, The Chemical Physics of Surfaces., New York: Plenum, 1977.

    Book  Google Scholar 

  118. Bielanski, A. and Haber, J., Oxygen in Catalysis., Boca Roton, Fla.: CRC, 1990.

    Google Scholar 

  119. Roguleva, V.G., Kondratenko, E.V., Maksimov, N.G., Selyutin, G.E., and Anshits, A.G., Catal. Lett., 1992, vol. 16, nos. 1–2, p. 165.

    Article  CAS  Google Scholar 

  120. Yamamoto, H.Y., Chu, H.Y., Xu, M., Shi, C., and Lunsford, J.H., J. Catal., 1993, vol. 142, no. 1, p. 325.

    Article  CAS  Google Scholar 

  121. Anshits, A.G., Roguleva, V.G., and Kondratenko, E.V., Stud. Surf. Sci. Catal., 1994, vol. 82, p. 337.

    Article  CAS  Google Scholar 

  122. Lo, M.-Y., Agarwal, S.K., Galy, L.G., and Marcelin, G., Catal. Today, 1988, vol. 3, nos. 2–3, p. 137.

    Article  CAS  Google Scholar 

  123. Shafranovskii, P.A., Sinev, M.Yu., Shub, B.R., Zhizhin, G.N., and Yakovlev, V.A., Kinet. Catal., 1989, vol. 30, no. 1, p. 173.

    Google Scholar 

  124. Simon, Y., Baronnet, F., and Marquaire, P.M., Ind. Eng. Chem. Res., 2007, vol. 46, p. 1914.

    Article  CAS  Google Scholar 

  125. Sun, J., Thybaut, J.W., and Marin, G.B., Catal. Today, 2008, vol. 137, nos. 1–2, p. 90.

    Article  CAS  Google Scholar 

  126. Lee, M.R., Park, M-J., Jeon, W., Choi, J-W., Suh, Y-W., and Suh, D.J., Fuel Process. Technol., 2012, vol. 96, p. 175.

    Article  CAS  Google Scholar 

  127. Sinev, M.Yu. and Bychkov, V.Yu., Kinet. Catal., 1999, vol. 40, no. 6, p. 819.

    CAS  Google Scholar 

  128. Sinev, M.Yu. and Bychkov, V.Yu., Kinet. Catal., 1993, vol. 34, no. 2, p. 272.

    Google Scholar 

  129. Sinev, M.Yu., Catal. Today, 1992, vol. 13, no. 4, p. 561.

    Article  CAS  Google Scholar 

  130. Trionfetti, C., Crapanzano, S., Babich, I.V., Seshan, K., and Lefferts, L., Catal. Today, 2009, vol. 145, nos. 1–2, p. 19.

    Article  CAS  Google Scholar 

  131. Anderson, L.C., Xu, M., Mooney, C.E., Rosynek, M.P., and Lunsford, J.H., J. Am. Chem. Soc., 1993, vol. 115, no. 13, p. 6322.

    Article  CAS  Google Scholar 

  132. Hewett, K.B., Rosynek, M.P., and Lunsford, J.H., Catal. Lett., 1997, vol. 45, nos 1-2, p. 125.

    Article  CAS  Google Scholar 

  133. Alexiadis, V.I., Thybaut, J.W., Kechagiopoulos, P.N., Chaar, M., van Veen, A.C., Muhler, M., and Marin, G.B., Appl. Catal., B, 2014, vols. 150–151, p. 496.

    Article  CAS  Google Scholar 

  134. Johnson, M.A., Stafanovich, E.V., and Truong, T.N., J. Phys. Chem., 1997, vol. 101, no. 16, p. 3196.

    Article  CAS  Google Scholar 

  135. Sinev, M.Yu., Korchak, V.N., and Krylov, O.V., Kinet. Catal., 1989, vol. 30, no. 4, p. 750.

    Google Scholar 

  136. Sinev, M.Yu., Korchak, V.N., and Krylov, O.V., Kinet. Catal., 1989, vol. 30, no. 4, p. 755.

    Google Scholar 

  137. Lomonosov, V.I., Gordienko, Yu.A., and Sinev, M.Yu., Kinet. Catal., 2013, vol. 54, no. 4, p. 451.

    Article  CAS  Google Scholar 

  138. Nelson, P.F., Lukey, C.A., and Cant, N.W., J. Catal., 1989, vol. 120, no. 1, p. 216.

    Article  CAS  Google Scholar 

  139. Lane, G.S. and Wolf, E.E., J. Catal., 1988, vol. 113, no. 1, p. 144.

    Article  CAS  Google Scholar 

  140. Mallens, E.P.J., Hoebink, J.H.B.J., and Marin, G.B., J. Catal., 1996, vol. 160, no. 2, p. 222.

    Article  CAS  Google Scholar 

  141. Martin, G.A. and Mirodatos, C., J. Chem. Soc., Chem. Commun., 1987, vol. 14, p. 1393.

    Article  Google Scholar 

  142. Kondrat'ev, V.N., Konstanty skorosti gazofaznykh reaktsii (Rate Constants of Gas-Phase Reactiona), Moscow: Nauka, 1971.

    Google Scholar 

  143. Warnatz, J., in Combustion Chemistry, Gardiner, W.C., Jr., Ed., New York: Springer, 1984, ch.5.

  144. Morales, E. and Lunsford, J.H., J. Catal., 1989, vol. 118, no. 1, p. 255.

    Article  CAS  Google Scholar 

  145. Conway, S.J. and Lunsford, J.H., J. Catal., 1991, vol. 131, no. 2, p. 513.

    Article  CAS  Google Scholar 

  146. Consay, S.J., Wang, D.J., and Lunsford, J.H., Appl. Catal., A, 1991, vol. 79, no. 1, p. L1.

    Article  Google Scholar 

  147. Aika, K.-I. and Lunsford, J.H., J. Phys. Chem., 1977, vol. 81, no. 14, p. 1393.

    Article  CAS  Google Scholar 

  148. Couwenberg, P.M., Chen, Q., and Marin, G.B., Ind. Eng. Chem. Res., 1996, vol. 35, no. 2, p. 415.

    Article  CAS  Google Scholar 

  149. Mims, C.A., Mauti, R., Dean, A.M., and Rose, K.D., J. Phys. Chem., 1994, vol. 98, no. 50, p. 13357.

    Article  CAS  Google Scholar 

  150. Shi, C., Hatano, M., and Lunsford, J.H., Catal. Today, 1992, vol. 13, nos. 2–3, p. 191.

    Article  CAS  Google Scholar 

  151. Sinev, M.Yu., Korchak, V.N., and Krylov, O.V., Kinet. Catal., 1987, vol. 28, no. 6, p. 1188.

    Google Scholar 

  152. Aparicio, L.M., Rossini, S.A., Sanfilippo, D.G., Rekoske, J.E., Trevino, A.A., and Dumesic, J.A., Ind. Eng. Chem. Res., 1991, vol. 30, no. 10, p. 2114.

    Article  CAS  Google Scholar 

  153. Tong, Y. and Lunsford, J.H., J. Am. Chem. Soc., 1991, vol. 113, no. 13, p. 4741.

    Article  CAS  Google Scholar 

  154. Nibbelke, R.H., Scheerova, J., Croon, M.H.J.M., and Marin, G.B., J. Catal., 1995, vol. 156, no. 1, p. 106.

    Article  CAS  Google Scholar 

  155. Sinev, M.Yu., Setiadi, S., and Otsuka, K., Mendeleev Commun., 1993, vol. 3, no. 1, p. 10.

    Article  Google Scholar 

  156. Nelson, P.F. and Cant, N.W., J. Phys. Chem., 1990, vol. 94, no. 9, p. 3756.

    Article  CAS  Google Scholar 

  157. Ekstrom, A., Lapszewicz, J.A., and Campbell, I., Appl. Catal., 1989, vol. 56, no. 1, p. Ð. L29.

    Google Scholar 

  158. Rosynek, M.P. and Lunsford, J.H., J. Phys. Chem., 1994, vol. 98, no. 34, p. 8371.

    Article  Google Scholar 

  159. Mleczko, L., Andorf, R., and Baerns, M., Chem. Eng. Technol., 1991, vol. 14, no. 5, p. 325.

    Article  CAS  Google Scholar 

  160. Geerts, J.W.M.H., van Kasteren, J.M.N., and van der Wiele, K., Catal. Today, 1989, vol. 4, nos. 3–4, p. 453.

    Article  CAS  Google Scholar 

  161. Santamaria, J.M., Miro, E.E., and Wolf, E.E., Ind. Eng. Chem. Res., 1991, vol. 30, no. 6, p. 1157.

    Article  CAS  Google Scholar 

  162. Otsuka, K., Jinno, K., and Morikawa, A., J. Catal., 1986, vol. 100, no. 2, p. 353.

    Article  CAS  Google Scholar 

  163. Lehmann, L. and Baerns, M., Catal. Today, 1992, vol. 13, nos. 2–3, p. 265.

    Article  CAS  Google Scholar 

  164. Dedov, A.G., Makhlin, V.A., Podlesnaya, M.V., Zyskin, A.G., Loktev, A.S., Tyunyaev, A.A., Nipan, G.D., Kol’tsova, T.N., Ketsko, V.A., Kartasheva, M.N., and Moiseev, I.I., Theor. Found. Chem. Eng., 2010, vol. 44, no. 1, p. 1.

    Article  CAS  Google Scholar 

  165. Yaghobi, N. and Ghoreishy, M.H.R., J. Nat. Gas Chem., 2008, vol. 17, no. 1, p. 8.

    Article  CAS  Google Scholar 

  166. Lacombe, S., Durjanova, Z., Mleczko, L., and Mirodatos, C., Chem. Eng. Technol., 1995, vol. 18, no. 3, p. 216.

    Article  CAS  Google Scholar 

  167. Bartsch, S. and Hofmann, H., Catal. Today, 1990, vol. 6, no. 4, p. 527.

    Article  CAS  Google Scholar 

  168. Tung, W.-Y. and Lobban, L.L., Ind. Eng. Chem. Res., 1992, vol. 31, no. 7, p. 1621.

    Article  CAS  Google Scholar 

  169. Stansch, Z., Mleczko, L., and Baerns, M., Ind. Eng. Chem. Res., 1997, vol. 36, no. 7, p. 2568.

    Article  CAS  Google Scholar 

  170. Wada, S., and Imai, H., Appl. Catal., 1989, vol. 47, no. 2, p. 277.

    Article  CAS  Google Scholar 

  171. Ding, X., Yu, Z., Wang, X., and Shen, S., Stud. Surf. Sci. Catal., 1991, vol. 61, p. 65.

    Article  CAS  Google Scholar 

  172. Tye, C.T., Mohamed, A.R., and Bhatia, S., Chem. Eng. J., 2002, vol. 87, no. 1, p. 49.

    Article  CAS  Google Scholar 

  173. Nouralishahi, A., Pahlevanzadeh, H., and Tofighi, J., Fuel Process. Technol., 2008, vol. 89, no. 7, p. 667.

    Article  CAS  Google Scholar 

  174. Yaghobi, N. and Ghoreishy, M.H.R., J. Gas Chem., 2009, vol. 18, no. 1, p. 39.

    Article  CAS  Google Scholar 

  175. Daneshpayeh, M., Khodadadi, K., Mostoufi, N., Mortazavi, Y., and Talebizadeh, A., Fuel Process. Technol., 2009, vol. 90, no. 3, p. 403.

    Article  CAS  Google Scholar 

  176. Makhlin, V.A., Magomedova, M.V., Zyskin, A.G., Loktev, A.S., Dedov, A.G., and Moiseev, I.I., Kinet. Catal., 2011, vol. 52, no. 6, p. 914.

    Article  CAS  Google Scholar 

  177. Magomedova, M.V., Cand. Sci. (Eng.) Dissertation., Moscow: Karpov Inst. of Physical Chemistry,2011.

    Google Scholar 

  178. Sinev, M.Y., Korchak, V.N., and Krylov, O.V., Proc. 6th Int. Symp. on Heterogeneous Catalysis, Sofia, 1987, vol. 1, p. 450.

    Google Scholar 

  179. Mars, P. and van Krevelen, D.W., Chem. Eng. Sci., 1954, vol. 3, p. 41.

    Article  CAS  Google Scholar 

  180. Iwamatsu, E. and Aika, K.-I., J. Catal., 1989, vol. 117, no. 2, p. 416.

    Article  CAS  Google Scholar 

  181. Ahari, J.S., Ahmadi, R., Mikami, H., Inazu, K., Zarrinpashne, S., Suzuki, S., and Aika, K.-I., Catal. Today, 2009, vol. 145, nos. 1–2, p. 45.

    Article  CAS  Google Scholar 

  182. Otsuka, K. and Jinno, K., Inorg. Chim. Acta, 1986, vol. 121, no. 2, p. 237.

    Article  CAS  Google Scholar 

  183. Hargreaves, J.S.J., Hutchings, G.J., and Joyner, R.W., Nature, 1990, vol. 348, p. 428.

    Article  CAS  Google Scholar 

  184. Zanthoff, H. and Baerns, M., Ind. Eng. Chem. Res., 1990, vol. 29, no. 1, p. 2.

    Article  CAS  Google Scholar 

  185. Tjatjopoulos, G.T. and Vasalos, I.A., Appl. Catal., A, 1992, vol. 88, no. 2, p. 213.

    Article  CAS  Google Scholar 

  186. Vedeneev, V.I., Arutyunov, V.S., and Basevich, V.Ya., Khim. Fiz., 1997, vol. 16, no. 1, p. 76.

    CAS  Google Scholar 

  187. McCarty, J.G., McEwen, A.B., and Quinlan, M.A., Stud. Surf. Sci. Catal., 1990, vol. 55, p. 405.

    Article  CAS  Google Scholar 

  188. Tjatjopoulos, G.J. and Vasalos, I.A., Catal. Today, 1992, vol. 13, nos. 2–3, p. 361.

    Article  CAS  Google Scholar 

  189. Bistolfi, M., Fornasari, G., Molinari, M., Palmery, S., Dente, M., and Ranzi, E., Chem. Eng. Sci., 1992, vol. 47, nos. 9–11, p. 2647.

    Article  CAS  Google Scholar 

  190. Reyes, S.C., Iglesia, E., and Kelkar, C.P., Chem. Eng. Sci., 1993, vol. 48, no. 14, p. 2643.

    Article  CAS  Google Scholar 

  191. Sinev, M.Yu., Catal. Today, 1995, vol. 24, no. 3, p. 389.

    Article  CAS  Google Scholar 

  192. Thybaut, J.W., Sun, J., Olivier, L., van Veen, A.C., Mirodatos, C., and Marin, G.B., Catal. Today, 2011, vol. 159, no. 1, p. 29.

    Article  CAS  Google Scholar 

  193. Kechagiopoulos, P., Thybaut, J.W., and Marin, G.B., Ind. Eng. Chem. Res., 2014, vol. 53, no. 5, p. 1825.

    Article  CAS  Google Scholar 

  194. Chen, Q., Hoebink, J.H.B.J., and Marin, G.B., Ind. Eng. Chem. Res., 1991, vol. 30, no. 9, p. 2088.

    Article  CAS  Google Scholar 

  195. Batiot, C. and Hodnett, B.K., Appl. Catal., A, 1996, vol. 163, p. 117.

    Google Scholar 

  196. Cassidy, F.E. and Hodnett, B.K., CATTECH, 1998, vol. 2, p. 173.

    CAS  Google Scholar 

  197. Hodnett, B.K., Heterogeneous Catalytic Oxidation: Fundamental and Technological Aspects of the Selective and Total Oxidation of Organic Compounds., New York: Wiley, 2000.

    Google Scholar 

  198. Hodnett, B.K., in Supported Catalysts and Their Applications, Sherrington, D.C. and Kybett, A.P., Eds., Cambridge, UK: R. Soc. Chem., 2001, p. 1.

  199. Magomedov, R.N., Proshina, A.Yu., Peshnev, B.V., and Arutyunov, V.S., Kinet. Catal., 2013, vol. 54, no. 4, p. 383.

    Article  CAS  Google Scholar 

  200. Mackie, J.C., Smith, J.G., Nelson, P.F., and Tyler, R.J., Energy Fuels, 1990, vol. 4, no. 3, p. 285.

    Article  CAS  Google Scholar 

  201. Pogosyan, N.M. and Pogosyan, M.Dzh., Khim. Zh. Arm., 2009, vol. 67, nos. 3–4, p. 316.

    Google Scholar 

  202. Mimoun, H., Robine, A., Bonnaudet, S., and Cameron, C.J., Appl. Catal., 1990, vol. 58, no. 1, p. 269.

    Article  CAS  Google Scholar 

  203. Chen, Q., Couwenberg, P.M., and Marin, G.B., Catal. Today, 1994, vol. 21, nos. 2–3, p. 309.

    Article  CAS  Google Scholar 

  204. Machocki, A. and Denis, A., Chem. Eng. J., 2002, vol. 90, nos. 2–3, p. 165.

    Article  CAS  Google Scholar 

  205. Takanabe, K. and Iglesia, E., J. Phys.Chem. A, 2009, vol. 113, no. 37, p. 10131.

    CAS  Google Scholar 

  206. Peng, X.D. and Stair, P.C., J. Catal., 1991, vol. 128, no. 1, p. 264.

    Article  CAS  Google Scholar 

  207. Aika, K.-I. and Aono, K., J. Chem. So., Faraday Trans., 1991, vol. 87, no. 8, p. 1273.

    Article  CAS  Google Scholar 

  208. Suzuki, T., Wada, K., and Watanabe, Y., Appl. Catal., 1990, vol. 59, no. 1, p. 213.

    Article  CAS  Google Scholar 

  209. Wang, D., Xu, M., Shi, C., and Lunsford, J.H., Catal. Lett., 1993, vol. 8, no. 4, p. 323.

    Article  Google Scholar 

  210. Peil, K., Goodwin, J.G., Jr., and Marcelin, G., Stud. Surf. Sci. Catal., 1991, vol. 61, no. 1, p. 73.

    Article  CAS  Google Scholar 

  211. Korf, S.J., Roos, J.A., de Brujin, M.A., Ommen, J.G., and Ross, J.R.H., J. Chem. Soc., Chem. Commun., 1987, vol. 19, p. 1433.

    Article  Google Scholar 

  212. Al-Zahrani, S.M.S., Song, Q., and Lobban, L.L., Ind. Eng. Chem. Res., 1994, vol. 33, no. 2, p. 251.

    Article  CAS  Google Scholar 

  213. Gasiev, R.G., Ukharsky, A.A., Fattakhova, Z.T., Berman, A.D., Yanovsky, M.I., and Krylov, O.V., Proc. 6th Int. Symp. on Heterogeneous Catalysis, Sofia, 1987, vol. 2, p. 228.

    Google Scholar 

  214. Galuszka, J., Catal. Today, 1994, vol. 21, nos. 2–3, p. 321.

    Article  CAS  Google Scholar 

  215. Korf, S.J., Roos, J.A., de Bruijn, N.A., Van Ommen, J.G., and Ross, J.R.H., Appl. Catal., 1990, vol. 58, no. 1, p. 131.

    Article  CAS  Google Scholar 

  216. Lomonosov, V.I., Gordienko, Yu.A., and Sinev, M.Yu., 10th Natural Gas Conversion Symp., Doha, Qatar, 2013, p. 10.

    Google Scholar 

  217. Shi, J., Yao, L., and Hu, C., J. Energy Chem., 2015, vol. 24, no. 4, p. 324.

    Article  Google Scholar 

  218. Shi, J., Xiao, T., Li, S., Chou, L., Zhang, B., Xu, C., Hou, R., York, A., and Green, M., J. Catal., 2003, vol. 220, no. 1, p. 47.

    Article  CAS  Google Scholar 

  219. Aika, K.-I. and Nishiyama, T., J. Chem. Soc., Chem. Commun., 1988, vol. 1, p. 70.

    Article  Google Scholar 

  220. Zhang, Z. and Baerns, M., Appl. Catal., 1991, vol. 75, no. 1, p. 239.

    Article  Google Scholar 

  221. Pereira, P., Lee, S.H., Somorjai, G.A., and Heinemann, H., Catal. Lett., 1990, vol. 6, no. 3, p. 255.

    Article  CAS  Google Scholar 

  222. Rasco, J., Pereira, P., Somorjai, G.A., and Heinemann, H., Catal. Lett., 1991, vol. 9, nos. 5–6, p. 395.

    Article  Google Scholar 

  223. Matsukata, M., Okanari, E., and Komori, K., Proc. Symp. on Methane Activation., Int. Congr. of Pacific Basin Soc.., Honolulu, 1989, p. 52.

    Google Scholar 

  224. Kimble, J.B. and Kolts, J.H., Energy Prog., 1986, vol. 6, no. 4, p. 226.

    CAS  Google Scholar 

  225. Al-Zahrani, S.M.S. and Lobban, L.L., Ind. Eng. Chem. Res., 1995, vol. 34, no. 4, p. 1060.

    Article  CAS  Google Scholar 

  226. Karasuda, T., Nagaoka, K., and Aika, K.-I., Stud. Surf. Sci. Catal., 1998, vol. 119, p. 283.

    Article  CAS  Google Scholar 

  227. Buyevskaya, O.V., Vanina, M.P., Saputina, N.F., and Sokolovskii, V.D., Catal. Today, 1992, vol. 13, no. 4, p. 589.

    Article  Google Scholar 

  228. Zhang, B., Wang, J., Chou, L., Song, H., Zhao, J., Yang, J., and Li, S., Stud. Surf. Sci. Catal., 2007, vol. 167, p. 237.

    Article  CAS  Google Scholar 

  229. Takanabe, K. and Iglesia, E., Angew. Chem., Int. Ed. Engl., 2008, vol. 47, no. 40, p. 7689.

    Article  CAS  Google Scholar 

  230. Lomonosov, V., Gordienko, Yu., and Sinev, M., Top. Catal., 2013, vol. 56, no. 18, p. 1858.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. I. Lomonosov & M. Yu. Sinev

Authors
  1. V. I. Lomonosov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Yu. Sinev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Yu. Sinev.

Additional information

Original Russian Text © V.I. Lomonosov, M.Yu. Sinev, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 5, pp. 652–684.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lomonosov, V.I., Sinev, M.Y. Oxidative coupling of methane: Mechanism and kinetics. Kinet Catal 57, 647–676 (2016). https://doi.org/10.1134/S0023158416050128

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158416050128

Keywords

Search

Navigation