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Synthesis of Mg2+-, Al3+-, and Ga3+-containing layered hydroxides and supported platinum catalysts based thereon

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Abstract

The effect of the cationic composition of MgAl(Ga) layered double hydroxides on the structure, texture, and acid–base properties of related oxide supports for platinum catalysts has been investigated. As gallium is progressively substituted for aluminum in the mixed oxide, the properties of the support change only slightly, while the activity of the Ga–Pt catalysts in propane conversion increases, the propylene selectivity remains high (99%), and C–C bond hydrogenolysis is hampered.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    O. B. Belskaya, L. N. Stepanova, T. I. Gulyaeva, N. N. Leont’eva & V. A. Likholobov

  2. Omsk State Technical University, Omsk, 644050, Russia

    O. B. Belskaya & V. A. Likholobov

  3. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. I. Zaikovskii & A. N. Salanov

Authors
  1. O. B. Belskaya
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  2. L. N. Stepanova
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  3. T. I. Gulyaeva
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  4. N. N. Leont’eva
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  5. V. I. Zaikovskii
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  6. A. N. Salanov
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  7. V. A. Likholobov
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Correspondence to O. B. Belskaya.

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Original Russian Text © O.B. Belskaya, L.N. Stepanova, T.I. Gulyaeva, N.N. Leont’eva, V.I. Zaikovskii, A.N. Salanov, V.A. Likholobov, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 4, pp. 554–565.

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Belskaya, O.B., Stepanova, L.N., Gulyaeva, T.I. et al. Synthesis of Mg2+-, Al3+-, and Ga3+-containing layered hydroxides and supported platinum catalysts based thereon. Kinet Catal 57, 546–556 (2016). https://doi.org/10.1134/S0023158416040029

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