Abstract
Crystalline 4- to 5-nm gold nanoparticles supported on graphite and oxidized silicon have been obtained by the impregnation method. Specific features of the adsorption and interaction of H2 and O2 on the Au surface have been investigated by scanning tunneling microscopy, Auger electron spectroscopy, and mass spectrometry. Hydrogen adsorbs dissociatively on separate Au nanoparticles. The Au-H bond energy is ∼1.7 eV. Oxygen adsorbs on the separate Au nanoparticles after hydrogen adsorption. The support nature has a significant effect on the reactivity of the H2 and O2 molecules adsorbed on the surface of the Au nanoparticles. A sufficient condition for water formation from oxygen and hydrogen on Au/SiO2/Si is that Au/SiO2/Si is exposed to H2 and then to O2. As distinct from what is observed for Au/SiO2/Si, water on the Au/graphite surface forms solely due to the successive adsorption of H2, O2, and H2.
Similar content being viewed by others
References
Bone, W.A. and Wheeler, R.V., Philos. Trans. R. Soc. London, Ser. A, 1906, vol. 206, p. 1.
Yolles, R.S., Wood, B.J., and Wise, H., J. Catal., 1971, vol. 21, p. 66.
Bond, G.C. and Sermon, P.A., Gold Bull., 1973, no. 6, p. 102.
Haruta, M., Kobayashi, T., Sano, H., and Yamada, N., Chem. Lett., 1987, vol. 16, p. 405.
Nikolaev, S.A., Smirnov, V.V., Vasil’kov, A.Yu., and Podshibikhin, V.L., Kinet. Catal., 2010, vol. 51, no. 3, p. 375.
Nikolaev, S.A., Permyakov, N.A., Smirnov, V.V., Vasil’kov, A.Yu., and Lanin, S.N., Kinet. Catal., 2010, vol. 51, no. 2, p. 288.
Simakova, I.L., Solkina, Yu.S., Moroz, B.L., Simakova, O.A., Reshetnikov, S.I., Prosvirin, I.P., Bukhtiyarov, V.I., Parmon, V.N., and Murzin, D.Yu., Appl. Catal., A, 2010, vol. 385, p. 136.
Smirnov, V.V., Nikolaev, S.A., Murav’eva, G.P., Tyurina, L.A., and Vasil’kov, A.Yu., Kinet. Catal., 2007, vol. 48, no. 2, p. 265.
Gómez-Quero, S., Cárdenas-Lizana, F., and Keane, M.A., J. Catal., 2013, vol. 303, p. 41.
Cárdenas-Lizana, F., Lamey, D., Perret, N., Gómez-Quero, S., Kiwi-Minsker, L., and Keane, M.A., Catal. Commun., 2012, no. 21, p. 46.
Ellert, O.G., Tsodikov, M.V., Nikolaev, S.A., and Novotortsev, V.M., Russ. Chem. Rev., 2014, no. 83, p. 718.
Lakshmanan, P., Upare, P.P., Le, N.-T., Hwang, Y.K., Hwang, D.W., Lee, U-H., Kim, H.R., and Chang, J.-S., Appl. Catal., A, 2013, vol. 468, p. 260.
Nikolaev, S.A., Chistyakov, A.V., Chudakova, M.V., Kriventsov, V.V., Yakimchuk, E.P., and Tsodikov, M.V., J. Catal., 2013, vol. 297, p. 296.
Takei, T., Akita, T., Nakamura, I., Fujitani, T., Okumura, M., Okazaki, K., Huang, J., Ishida, T., and Haruta, M., Adv. Catal., 2012, vol. 55, p. 1.
Chen, M. and Goodman, D.W., Chem. Soc. Rev., 2008, vol. 37, p. 1860.
Jiang, H.-L. and Xu, Q., J. Mater. Chem., 2011, vol. 21, p. 13705.
Singh, A.K. and Xu, Q., ChemCatChem, 2013, vol. 5, p. 652.
Bukhtiyarov, V.I., Russ. Chem. Rev., 2007, vol. 76, no. 6, p. 553.
Bukhtiyarov, V.I. and Slin’ko, M.G., Russ. Chem. Rev., 2001, vol. 70, no. 2, p. 147.
Miller, J.T., Kropf, A.J., Zha, Y., Regalbuto, J.R., Delannoy, L., Louis, C., Bus, E., and van Bokhoven, J.A., J. Catal., 2006, vol. 240, p. 222.
Janssens, T.V.W., Clausen, B.S., Hvolbæk, B., Falsig, H., Christensen, C.H., Bligaard, T., and Nørskov, J.K., Top. Catal., 2007, vol. 44, nos. 1–2, p. 15.
Campbell, C.T., Sharp, J.C., Yao, Y.X., Karp, E.M., and Silbaugh, T.L., Faraday Discuss., 2011, vol. 152, p. 227.
Bukhtiyarov, A.B., Nartova, A.B., and Kvon, R.I., Kinet. Catal., 2011, vol. 52, no. 5, p. 756.
Bukhtiyarov, A.V., Kvon, R.I., Nartova, A.V., and Bukhtiyarov, V.I., Russ. Chem. Bull., 2012, vol. 60, no. 10, p. 1977.
Demidov, D.V., Prosvirin, I.P., Sorokin, A.M., and Bukhtiyarov, V.I., Catal. Sci. Technol., 2011, vol. 1, p. 1432.
Baumer, M. and Freund, H.-J., Prog. Surf. Sci., 1999, vol. 61, p. 127.
Choudhary, T.V. and Goodman, D.W., Appl. Catal., A, 2005, vol. 291, p. 32.
Gatin, A.K., Grishin, M.V., Kirsankin, A.A., Trakhtenberg, L.I., and Shub, B.R., Nanotechnol. Russ., 2012, vol. 7, nos. 3–4, p. 122.
Gatin, A.K., Grishin, M.V., Kirsankin, A.A., Kharitonov, V.A., and Shub, B.R., Nanotechnol. Russ., 2013, vol. 8, nos. 1–2, p. 36.
Grishin, M.V., Gatin, A.K., Dokhlikova, N.V., Kirsankin, A.A., Kharitonov, V.A., and Shub, B.R., Russ. Chem. Bull., 2013, vol. 62, no. 7, p. 1525.
Gatin, A.K., Grishin, M.V., Gurevich, S.A., Dokhlikova, N.V., Kirsankin, A.A., Kozhevin, V.M., Kolchenko, N.N., Rostovshchikova, T.N., Kharitonov, V.A., Shub, B.R., and Yavsin, D.A., Russ. Chem. Bull., 2014, vol. 63, no. 8, p. 1696.
Gatin, A.K., Grishin, M.V., Kolchenko, N.N., Slutskii, V.G., Kharitonov, V.A., and Shub, B.R., Russ. Chem. Bull., 2014, vol. 63, no. 8, p. 1815.
Kozhevin, V.M., Yavsin, D.A., Kouznetsov, V.M., Busov, V.M., Mikushkin, V.M., Nikonov, S.Yu., Gurevich, S.A., and Kolobov, A., J. Vac. Sci. Technol., vol. 18, p. 1402.
Petkov, V., Peng, Y., Williams, G., Huang, B., Tomalia, D., and Ren, Y., Phys. Rev. B: Condens. Matter, 2005, vol. 72, p. 195402.
Scanning Tunneling Microscopy: I. General Principles and Applications to Clean and Adsorbate-Covered Surfaces, Güntherodt, H.-J. and Wiesendanger, R., Eds., Berlin: Springer, 1994.
Gatin, A.K., Grishin, M.V., Dalidchik, F.I., Kovalevskii, S.A., and Kolchenko, N.N., Khim. Fiz., 2006, vol. 25, no. 6, p. 17.
Kovalevskii, S., Dalidchik, F., Grishin, M., Kolchenko, N., and Shub, B., Appl. Phys. A, 1998, vol. 66, p. 125.
Grishin, M.V., Dalidchik, F.I., Kovalevskii, S.A., Shub, B.R., and Gatin, A.K., Russ. J. Phys. Chem. B, 2007, vol. 1, no. 5, p. 472.
Mironov, V.L., Osnovy skaniruyushchei zondovoi mikroskopii (Principles of Scanning Probe Microscopy), Nizhni Novgorod: Inst. Fiziki Mikrostruktur, 2004.
Binnig, G., Rohrer, H., Berber, C., and Weibel, E., Appl. Phys. Lett., 1981, vol. 40, no. 2, p. 178.
Meyer, E., Hug, H.J., and Bennewitz, R., Scanning Probe Microscopy, Berlin: Springer, 2004.
Hamers, R.J. and Wang, Y.J., Chem. Rev., 1996, vol. 96, no. 4, p. 1261.
Hamers, R.J., Tromp, R.M., and Demuth, J.E., Phys. Rev. Lett., 1986, vol. 56, no. 18, p. 1972.
Lian, L., Hackett, P.A., and Rayner, D.M., J. Chem. Phys., 1993, vol. 99, p. 2583.
Stromsnes, H., Jusul, S., Schimmelpfenning, B., Wahlgren, U., and Gropen, O., J. Mol. Struct., 2001, vol. 567–568, p. 137.
Ozaki, T., Phys. Rev. B: Condens. Matter, 2003, vol. 67, p. 155108.
Morrison, I., Bylander, D.M., and Kleinman, L., Phys. Rev. B: Condens. Matter, 1993, vol. 47, p. 6728.
Ozaki, T. and Kino, H., Phys. Rev. B: Condens. Matter, 2004, vol. 69, p. 195113.
Rhoderick, E.H., Metal-Semiconductor Contacts, Oxford: Clarendon, 1978.
Avtomatizatsiya proektirovaniya matrichnykh KMOP BIS (CMOS LSIC Arrays: Design Automation), Fomin, A.V., Ed., Moscow: Radio i Svyaz’, 1991.
Fizicheskie velichiny: Spravochnik (Physical Data: A Handbook), Grigorov, N.S. and Meilikhov, E.Z., Eds., Moscow: Energoatomizdat, 1991.
Suvorov, A.L., Bogdanovich, B.Yu., Zaluzhnyi, A.G., Grafutin, V.I., Kalugin, V.V., Nesterovich, A.V., Prokop’ev, E.P., Timoshenkov, S.P., and Chaplygin, Yu.A., Tekhnologii struktur kremnii na izolyatore (Silicon-on-Insulator Structure Technology), Moscow: Mosk. Inst. Elektronnoi Tekhniki, 2004.
Manzoli, M., Chiorino, A., Vindigni, F., and Boccuzzi, F., Catal. Today, 2012, vol. 181, p. 62.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.V. Grishin, A.K. Gatin, N.V. Dokhlikova, A.A. Kirsankin, A.I. Kulak, S.A. Nikolaev, B.R. Shub, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 4, pp. 539–546.
Rights and permissions
About this article
Cite this article
Grishin, M.V., Gatin, A.K., Dokhlikova, N.V. et al. Adsorption and interaction of hydrogen and oxygen on the surface of separate crystalline gold nanoparticles. Kinet Catal 56, 532–539 (2015). https://doi.org/10.1134/S0023158415040084
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158415040084