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Properties of nitrogen-oxygen surface compounds on ZrO2 samples with different phase compositions according to in situ IR spectroscopy data

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Abstract

The zirconium dioxide surface has a wide variety of adsorption sites differing in their nature. The proportions of these sites can be changed by varying the oxide preparation and pretreatment conditions. This fact shows itself as a wide diversity of surface structures resulting from NO and O2 adsorption. Under conditions of the selective catalytic reduction of NO x , the most stable nitrogen oxide species are nitrates that result from the interaction between NO x and the ZrO2 surface. The concentrations of the other nitrogen-oxygen surface compounds are two orders of magnitude lower. The routes of NO −3 formation and decomposition on the ZrO2 surface are discussed. In these routes, monodentate nitrates (which show themselves at 1550–1555 cm−1) are considered as intermediates in the formation and decomposition of bidentate NO −3 .

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. A. Matyshak, A. N. Il’ichev, V. A. Sadykov, O. N. Sil’chenkova & V. N. Korchak

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  1. V. A. Matyshak
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  2. A. N. Il’ichev
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  3. V. A. Sadykov
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  4. O. N. Sil’chenkova
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  5. V. N. Korchak
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Correspondence to V. A. Matyshak.

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Original Russian Text © V.A. Matyshak, A.N. Il’ichev, V.A. Sadykov, O.N. Sil’chenkova, V.N. Korchak, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 2, pp. 228–239.

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Matyshak, V.A., Il’ichev, A.N., Sadykov, V.A. et al. Properties of nitrogen-oxygen surface compounds on ZrO2 samples with different phase compositions according to in situ IR spectroscopy data. Kinet Catal 56, 226–236 (2015). https://doi.org/10.1134/S0023158415010103

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  • DOI: https://doi.org/10.1134/S0023158415010103

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