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Intramolecular Electronic Structural Rearrangements in Vanadium, Molybdenum, and Rhenium Oxo- and Thiometallates

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Abstract

Reaction pathways are found for electronic structural rearrangements in thiometallates [MS4]n– (M = V, n = 3; Mo, n = 2; Re, n = 1), which do not contradict the hypothesis about the possible electron transfer from sulfide ions S2– to metal centers with a corresponding decrease in metal atomic charges and the formation of disulfide ions of the (S2)2– type. The obtained results are compared with similar results for the same series of oxometallates [MO4]n–.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700321-3 and 121031700313-8).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. B. Artemkina, K. A. Brylev, M. N. Ivanova, S. G. Kozlova, M. R. Ryzhikov & V. E. Fedorov

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  1. S. B. Artemkina
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Correspondence to S. G. Kozlova.

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 8, 114992.https://doi.org/10.26902/JSC_id114992

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Artemkina, S.B., Brylev, K.A., Ivanova, M.N. et al. Intramolecular Electronic Structural Rearrangements in Vanadium, Molybdenum, and Rhenium Oxo- and Thiometallates. J Struct Chem 64, 1532–1541 (2023). https://doi.org/10.1134/S0022476623080176

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