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SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENCE OF THE ONE-DIMENSIONAL LANTHANUM(III) COORDINATION POLYMER WITH 2,6-BIS (3,5-DICARBOXYPHENOXY)PYRIDINE

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Abstract

By the interaction of 2,6-bis(3,5-dicarboxyphenoxy)pyridine (H4L) with lanthanum(III) nitrate in a 1:1 acetonitrile–water mixture a coordination polymer {[La(HL)(H4L)(H2O)4]·2H2O}n is synthesized. According to single crystal X-ray diffraction data, the compound is a linear coordination polymer whose chains are organized into a 3D supramolecular network by π–π stacking interactions and hydrogen bonds. The coordination polymer exhibits intraligand luminescence with the emission maximum at 392 nm.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (Projects Nos. 121031700321-3 and 121031700313-8).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    X. -L. Yu, D. I. Pavlov, A. A. Ryadun, A. S. Potapov & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    X. -L. Yu & V. P. Fedin

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  1. X. -L. Yu
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  2. D. I. Pavlov
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  3. A. A. Ryadun
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  4. A. S. Potapov
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  5. V. P. Fedin
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Corresponding author

Correspondence to A. S. Potapov.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 12, 103557.https://doi.org/10.26902/JSC_id103557

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Yu, X.L., Pavlov, D.I., Ryadun, A.A. et al. SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENCE OF THE ONE-DIMENSIONAL LANTHANUM(III) COORDINATION POLYMER WITH 2,6-BIS (3,5-DICARBOXYPHENOXY)PYRIDINE. J Struct Chem 63, 2028–2036 (2022). https://doi.org/10.1134/S0022476622120149

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